Enantioselective synthesis of epoxides having a tetrasubstituted trifluoromethylated carbon center: Methylhydrazine-induced aerobic epoxidation of β,β-disubstituted enones

Angewandte Chemie - International Edition

Volumn 52, Issue 8, 2013, Pages 2221-2225

  Kawai, Hiroyuki ^a   Okusu, Satoshi ^a   Yuan, Zhe ^a   Tokunaga, Etsuko ^a   Yamano, Akihito ^b   Shiro, Motoo ^b   Shibata, Norio ^a  

^a NAGOYA INSTITUTE OF TECHNOLOGY   (Japan)

^b RIGAKU CORPORATION   (Japan)

Author keywords

epoxidation; organocatalyst; oxygen; reaction mechanisms; synthetic methodology

Indexed keywords

AEROBIC EPOXIDATION; ENANTIOSELECTIVE SYNTHESIS; METHYL TERT BUTYL ETHER; METHYLHYDRAZINE; ORGANOCATALYSTS; REACTION MECHANISM; SYNTHETIC METHODOLOGY;

CARBON; CATALYSTS; ENANTIOSELECTIVITY; EPOXIDATION; OXYGEN;

SELECTIVE CATALYTIC REDUCTION;

ALKENE; AMINE OXIDE; CARBON; EPOXIDE; FLUORINE; METHYLHYDRAZINE; OXYGEN; TEMPO;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALKENES; CARBON; CYCLIC N-OXIDES; EPOXY COMPOUNDS; FLUORINE; MOLECULAR STRUCTURE; MONOMETHYLHYDRAZINE; OXYGEN; STEREOISOMERISM;

EID: 84873887526     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201209355     Document Type: Article

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