Active site and reaction mechanism for the epoxidation of propylene by oxygen over CuOx/SiO2 catalysts with and without Cs + modification

Journal of Catalysis

Volumn 299, Issue , 2013, Pages 53-66

  He, Jieli ^a   Zhai, Qingge ^a   Zhang, Qinghong ^a   Deng, Weiping ^a   Wang, Ye ^a  

^a XIAMEN UNIVERSITY   (China)

Author keywords

Allylic oxidation; Cesium; Copper oxide catalyst; CuI active site; Epoxidation; Molecular oxygen; Propylene; Selectivity control

Indexed keywords

ACTIVE SITE; ALLYL ALCOHOLS; ALLYLIC OXIDATION; COPPER OXIDE CATALYSTS; EPOXIDATION OF PROPYLENE; FOURIER TRANSFORM INFRA REDS; KINETIC STUDY; LATTICE OXYGEN; PRIMARY PRODUCTS; PROPYLENE OXIDE; REACTION MECHANISM; SELECTIVE FORMATION; SELECTIVITY CONTROL; SITU X-RAY DIFFRACTION;

ALDEHYDES; CATALYSTS; CESIUM; EPOXIDATION; HERBICIDES; ISOMERIZATION; ISOMERS; MOLECULAR OXYGEN; OXIDATION; OXYGEN; X RAY DIFFRACTION;

PROPYLENE;

EID: 84873637248     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2012.11.032     Document Type: Article

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