D2O solvent isotope effects suggest uniform energy barriers in ribulose-1,5-bisphosphate carboxylase/oxygenase catalysis

Biochemistry

Volumn 52, Issue 5, 2013, Pages 869-877

  Tcherkez, Guillaume G B ^a,b   Bathellier, Camille ^a,c   Stuart Williams, Hilary ^c   Whitney, Spencer ^c   Gout, Elisabeth ^d   Bligny, Richard ^d   Badger, Murray ^c   Farquhar, Graham D ^c  

^a INSTITUTE OF PLANT SCIENCES PARIS SACLAY IPS2   (France)

^b INSTITUT UNIVERSITAIRE DE FRANCE   (France)

^c AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

^d CEA GRENOBLE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

5-BISPHOSPHATE; AMINO ACID RESIDUES; ATMOSPHERIC CO; CATALYTIC RATES; CATALYTIC TURNOVER; DEUTERATIONS; ENERGY PROFILE; ENOLIZATION; H/D EXCHANGE; ISOTOPE EFFECT; MICHAELIS CONSTANTS; PROTON EXCHANGE; RATE LIMITING; REACTION MECHANISM; REPROTONATION; RUBISCO; SOLVENT ISOTOPE EFFECTS;

AMINO ACIDS; CARBOXYLATION; CARRIER MOBILITY; CATALYSIS; DEUTERIUM; ENERGY BARRIERS; PROTONS; SOLVENTS;

CARBON DIOXIDE;

3 PHOSPHO DEXTRO GLYCERATE; CARBON DIOXIDE; CARBOXYKETONE; DEUTERIUM OXIDE; GLYCERIC ACID; HYDROGEN; KETONE; PROTON; RIBULOSEBISPHOSPHATE CARBOXYLASE; UNCLASSIFIED DRUG; WATER; RIBULOSE 1,5 DIPHOSPHATE; RIBULOSE PHOSPHATE; RIBULOSE-1,5 DIPHOSPHATE;

ARTICLE; CARBOXYLATION; CATALYSIS; ENZYME STRUCTURE; HYDROLYSIS; MICHAELIS CONSTANT; OXYGENATION; PRIORITY JOURNAL; PROTON TRANSPORT; ENZYMOLOGY; KINETICS; METABOLISM; PLANT LEAF; SPINACH; THERMODYNAMICS;

CARBON DIOXIDE; DEUTERIUM OXIDE; KINETICS; PLANT LEAVES; RIBULOSE-BISPHOSPHATE CARBOXYLASE; RIBULOSEPHOSPHATES; SPINACIA OLERACEA; THERMODYNAMICS;

MLCS; MLOWN;

EID: 84873387185     PISSN: 00062960     EISSN: 15204995     Source Type: Journal    
DOI: 10.1021/bi300933u     Document Type: Article

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