Transformation of various kinds of goethite into magnetite: Effect of chemical and surface properties

Geoderma

Volumn 197-198, Issue , 2013, Pages 9-16

  Usman, M ^a,b   Abdelmoula, M ^b   Faure, P ^b   Ruby, C ^b   Hanna, K ^b,c  

^a UNIVERSITY OF AGRICULTURE   (Pakistan)

^b UNIVERSITÉ DE LORRAINE   (France)

^c UNIV RENNES   (France)

Author keywords

Dissolution; Goethite; Magnetite; Sorption; Transformation

Indexed keywords

ADSORPTION SITE; CHELATING LIGANDS; CRYSTAL FACE; CRYSTAL HABITS; EFFECT OF CHEMICALS; ELECTRON TRANSFER; FIRST-ORDER RATE CONSTANTS; GOETHITE; INNER SPHERE COMPLEXES; INTRINSIC REACTIVITY; KINETIC RATE CONSTANTS; LANGMUIR SORPTION; MAGNETITE FORMATION; MICROSCOPIC LEVELS; MINERALOGICAL TRANSFORMATIONS; REDUCTIVE DISSOLUTION; SITE DENSITY; SOLID STATE TRANSFORMATIONS; SPECIFIC CRYSTAL FACES; SPECTROSCOPIC INVESTIGATIONS; SURFACE SITE DENSITY; TRANSFORMATION; TRANSFORMATION PROCESS;

ADSORPTION; COORDINATION REACTIONS; DISSOLUTION; ELECTRON TRANSITIONS; IRON OXIDES; RATE CONSTANTS; SOLID STATE REACTIONS; SORPTION; SURFACE PROPERTIES;

MAGNETITE;

ADSORPTION; CHEMICAL PROPERTY; CRYSTAL STRUCTURE; CRYSTALLIZATION; DISSOLUTION; GOETHITE; LIGAND; MAGNETITE; PHOSPHATE; REACTION KINETICS; REACTION RATE; SORPTION; TRANSFORMATION;

EID: 84872813317     PISSN: 00167061     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.geoderma.2012.12.015     Document Type: Article

References (35)

1. Ardizzone S., Formaro L. Temperature induced phase transformation of metastable Fe(OH)3 in the presence of ferrous ions. Materials Chemistry and Physics 1983, 8:125-133.
2. Barrón V., Galvez N., Hochella M.F., Torrent J. Epitaxial overgrowth of goethite on hematite synthesized in phosphate media; a scanning force and transmission electron microscopy study. American Mineralogist 1997, 82:1091-1100.
3. Benali O., Abdelmoula M., Refait P., Génin J.-M.R. Effect of orthophosphate on the oxidation products of Fe(II)-Fe(III) hydroxycarbonate, the transformation of green rust to ferrihydrite. Geochimica et Cosmochimica Acta 2001, 65:1715-1726.
4. Boily J.-F., Nilsson N., Persson P., Sjöberg S. Benzenecarboxylate surface complexation at the goethite (α-FeOOH)/water interface: I. A mechanistic description of pyromellitate surface complexes from the combined evidence of infrared spectroscopy, potentiometry, adsorption data, and surface complexation modeling. Langmuir 2000, 16:5719-5729.
5. Borch T., Masue Y., Kukkadapu R.K., Fendorf S. Phosphate imposed limitations on biological reduction and alteration of ferrihydrite. Environmental Science and Technology 2006, 41:166-172.
6. Cornell R.M., Schwertmann U. The Iron Oxides: Structure, Properties, Reactions, Occurrence and Uses 2003, Wiley-VCH.
7. Cutting R.S., Coker V.S., Fellowes J.W., Lloyd J.R., Vaughan D.J. Mineralogical and morphological constraints on the reduction of Fe(III) minerals by Geobacter sulfurreducens. Geochimica et Cosmochimica Acta 2009, 73:4004-4022.
8. Dixit S., Hering J.G. Sorption of Fe(II) and As(III) on goethite in single- and dual-sorbate systems. Chemical Geology 2006, 228:6-15.
9. Fredrickson J.K., Zachara J.M., Kennedy D.W., Dong H., Onstott T.C., Hinman N.W., Li S.-m. Biogenic iron mineralization accompanying the dissimilatory reduction of hydrous ferric oxide by a groundwater bacterium. Geochimica et Cosmochimica Acta 1998, 62:3239-3257.
10. Gaboriaud F., Ehrhardt J.-J. Effects of different crystal faces on the surface charge of colloidal goethite ([alpha]-FeOOH) particles: an experimental and modeling study. Geochimica et Cosmochimica Acta 2003, 67:967-983.
11. Hansel C.M., Benner S.G., Nico P., Fendorf S. Structural constraints of ferric (hydr)oxides on dissimilatory iron reduction and the fate of Fe(II). Geochimica et Cosmochimica Acta 2004, 68:3217-3229.
12. Hansel C.M., Benner S.G., Fendorf S. Competing Fe(II)-induced mineralization pathways of ferrihydrite. Environmental Science and Technology 2005, 39:7147-7153.
13. Hartridge A., Bhattacharya A.K., Sengupta M., Majumdar C.K., Das D., Chintalapudi S.N. Crystallite size dependence on the magnetic properties of nanocrystalline magnetite powders. Journal of Magnetism and Magnetic Materials 1997, 176:89-92.
14. Hiemstra T., Van Riemsdijk W.H. A surface structural approach to ion adsorption: the charge distribution (CD) model. Journal of Colloid and Interface Science 1996, 179:488-508.
15. Jeon B.-H., Dempsey B.A., Burgos W.D. Kinetics and mechanisms for reactions of Fe(II) with iron(III) oxides. Environmental Science and Technology 2003, 37:3309-3315.
16. Klingelhöfer G., Fegley B., Morris R.V., Kankeleit E., Held P., Evlanov E., Priloutskii O. Mineralogical analysis of Martian soil and rock by a miniaturized backscattering Mössbauer spectrometer. Planetary and Space Science 1996, 44(11 SPEC. ISS.):1277-1288.
17. Larese-Casanova P., Scherer M.M. Fe(II) sorption on hematite: new insights based on spectroscopic measurements. Environmental Science and Technology 2006, 41:471-477.
18. Larsen O., Postma D. Kinetics of reductive bulk dissolution of lepidocrocite, ferrihydrite, and goethite. Geochimica et Cosmochimica Acta 2001, 65:1367-1379.
19. Liger E., Charlet L., Van Cappellen P. Surface catalysis of uranium(VI) reduction by iron(II). Geochimica et Cosmochimica Acta 1999, 63:2939-2955.
20. Liu C., Kota S., Zachara J.M., Fredrickson J.K., Brinkman C.K. Kinetic analysis of the bacterial reduction of goethite. Environmental Science and Technology 2001, 35:2482-2490.
21. Liu H., Guo H., Li P., Wei Y. The transformation of ferrihydrite in the presence of trace Fe(II): the effect of the anionic media. Journal of Solid State Chemistry 2008, 181:2666-2671.
22. Manceau A., Nagy K.L., Spadini L., Ragnarsdottir K.V. Influence of anionic layer structure of Fe-oxyhydroxides on the structure of Cd surface complexes. Journal of Colloid and Interface Science 2000, 228:306-316.
23. Pedersen H.D., Postma D., Jakobsen R., Larsen O. Fast transformation of iron oxyhydroxides by the catalytic action of aqueous Fe(II). Geochimica et Cosmochimica Acta 2005, 69:3967-3977.
24. Prélot B., Villiéras F., Pelletier M., Gérard G., Gaboriaud F., Ehrhardt J.-J., Perrone J., Fedoroff M., Jeanjean J., Lefèvre G., Mazerolles L., Pastol J.-L., Rouchaud J.-C., Lindecker C. Morphology and surface heterogeneities in synthetic goethites. Journal of Colloid and Interface Science 2003, 261:244-254.
25. Rancourt D.G., Ping J.Y. Voigt-based methods for arbitrary-shape static hyperfine parameter distributions in Mössbauer spectroscopy. Nuclear Instruments and Methods in Physical Research Section B 1991, 58:85-97.
26. Schwertmann U., Cornell R.M. Iron oxides in the laboratory: preparation and characterization 2000, Wiley-VCH, New York, (121-134 pp.).
27. Schwertmann U., Taylor R.M. Iron oxides, minerals in soil environments. SSSA Book Serie, 1 1989, Soil Science Society of America, Madison, WI, (379-438 pp.).
28. Spadini L., Schindler P.W., Charlet L., Manceau A., Vala Ragnarsdottir K. Hydrous ferric oxide: evaluation of Cd-HFO surface complexation models combining CdK EXAFS data, potentiometric titration results, and surface site structures identified from mineralogical knowledge. Journal of Colloid and Interface Science 2003, 266:1-18.
29. Torrent J., Barron V., Schwertmann U. Phosphate adsorption and desorption by goethites differing in crystal morphology. Soil Science Society of America Journal 1990, 54:1007-1012.
30. Tronc E., Belleville P., Jolivet J.P., Livage J. Transformation of ferric hydroxide into spinel by FeII adsorption. Langmuir 1992, 8:313-319.
31. Usman M., Abdelmoula M., Hanna K., Grégoire B., Faure P., Ruby C. FeII induced mineralogical transformations of ferric oxyhydroxides into magnetite of variable stoichiometry and morphology. Journal of Solid State Chemistry 2012, 194:328-335.
32. Usman M., Hanna K., Abdelmoula M., Zegeye A., Faure P., Ruby C. Formation of green rust via mineralogical transformation of ferric oxides (ferrihydrite, goethite and hematite). Applied Clay Science 2012, 64:38-43.
33. Williams A.G.B., Scherer M.M. Spectroscopic evidence for Fe(II)-Fe(III) electron transfer at the iron oxide-water interface. Environmental Science and Technology 2004, 38:4782-4790.
34. Yang L., Steefel C.I., Marcus M.A., Bargar J.R. Kinetics of Fe(II)-catalyzed transformation of 6-line ferrihydrite under anaerobic flow conditions. Environmental Science and Technology 2010, 44:5469-5475.
35. Zegeye A., Abdelmoula M., Usman M., Hanna K., Ruby C. In situ monitoring of lepidocrocite bioreduction and magnetite formation by reflection Mossbauer spectroscopy. American Mineralogist 2011, 96:1410-1413.