Stereochemistry of LinB-catalyzed biotransformation of δ-HBCD to 1R,2R,5S,6R,9R,10S-pentabromocyclododecanol

Chemosphere

Volumn 90, Issue 6, 2013, Pages 1911-1919

  Heeb, Norbert V ^a   Zindel, Daniel ^a,b   Graf, Heidi ^a,b   Azara, Valeria ^a   Bernd Schweizer, W ^c   Geueke, Birgit ^d   Kohler, Hans Peter E ^d   Lienemann, Peter ^b  

^a SWISS FEDERAL LABORATORIES FOR MATERIALS SCIENCE AND TECHNOLOGY   (Switzerland)

^b ZURICH UNIVERSITY OF APPLIED SCIENCES   (Switzerland)

^c ETH ZURICH   (Switzerland)

^d SWISS FEDERAL INSTITUTE OF AQUATIC SCIENCE AND TECHNOLOGY   (Switzerland)

Author keywords

Brominated flame retardants; Crystal structure; HBCD transformation; HCH converting enzymes

Indexed keywords

CATALYSIS; FLAME RETARDANTS; METABOLITES; METADATA; STEREOCHEMISTRY; STEREOSELECTIVITY; SUBSTITUTION REACTIONS;

BIOTRANSFORMATION PRODUCT; BROMINATED FLAME RETARDANTS; CONFORMATIONAL ANALYSIS; CONVERTING ENZYME; ENZYMATIC TRANSFORMATION; HBCD TRANSFORMATION; HEXABROMOCYCLODODECANES; HEXACHLOROCYCLOHEXANES;

CRYSTAL STRUCTURE;

ALCOHOL; ALKANE DERIVATIVE; ALPHA2 PENTABROMOCYCLODODECANOL; BACTERIAL ENZYME; BETA HEXACHLOROCYCLOHEXANE; BROMINE; DEHALOGENASE LINB; DELTA HEXABROMOCYCLODODECANE; GAMMA HEXABROMOCYCLODODECANE; HEXABROMOCYCLODODECANE; LAURYL ALCOHOL; PENTABROMOCYCLODODECANOL DERIVATIVE; TETRABROMOCYCLODODECADIOL DERIVATIVE; UNCLASSIFIED DRUG;

ALCOHOL; BACTERIUM; BIOTRANSFORMATION; ENZYME ACTIVITY;

ARTICLE; BACTERIUM; BIOTRANSFORMATION; CONFORMATIONAL TRANSITION; CRYSTAL STRUCTURE; HYDROXYLATION; NONHUMAN; NUCLEOPHILICITY; POLLUTION; SPHINGOBIUM INDICUM; STEREOCHEMISTRY; STEREOISOMERISM; SUBSTITUTION REACTION; X RAY DIFFRACTION;

BACTERIA (MICROORGANISMS); SPHINGOBIUM INDICUM;

EID: 84872686357     PISSN: 00456535     EISSN: 18791298     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2012.10.019     Document Type: Article

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