Methane reacts with heteropolyacids chemisorbed on silica to produce acetic acid under soft conditions

Journal of the American Chemical Society

Volumn 135, Issue 2, 2013, Pages 804-810

  Sun, Miao ^a   Abou Hamad, Edy ^a   Rossini, Aaron J ^b   Zhang, Jizhe ^a   Lesage, Anne ^b   Zhu, Haibo ^a   Pelletier, Jeremie ^a   Emsley, Lyndon ^b   Caps, Valerie ^a,c   Basset, Jean Marie ^a  

^a KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Saudi Arabia)

^b UNIVERSITÉ LYON 1   (France)

^c UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

C-H ACTIVATION; C-H BOND; HETEROPOLY ACIDS; MODERATE TEMPERATURE; ROOM TEMPERATURE; SELECTIVE FUNCTIONALIZATION; SINGLE-STEP; SOLID-STATE NMR SPECTROSCOPY; SURFACE CHARACTERIZATION; WATER FORMATION;

ACETIC ACID; ACTIVATION ANALYSIS; ATMOSPHERIC PRESSURE; CHEMISORPTION; CYCLIC VOLTAMMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PH; PHOTOELECTRONS; SILICA; X RAY PHOTOELECTRON SPECTROSCOPY;

METHANE;

ACETIC ACID; ACID; CARBON; HETEROPOLYACID; HYDROGEN; METHANE; PALLADIUM; PROTON; SILICON DIOXIDE; UNCLASSIFIED DRUG;

ABSORPTION; ACIDITY; ARTICLE; ATMOSPHERIC PRESSURE; CHEMICAL REACTION; CHEMICAL STRUCTURE; GAS; HYDRATION; HYDROGEN BOND; ROOM TEMPERATURE; SOLID; SURFACE PROPERTY;

EID: 84872580901     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja309966j     Document Type: Article

References (52)

1. NaturalGas.org. Overview of Natural Gas. http://www.naturalgas.org/ overview/background.asp (accessed Oct, 5, 2012.
2. Hashiguchi, B. G.; Bischof, S. M.; Konnick, M. M.; Periana, R. A. Acc. Chem. Res. 2012, 45, 885
3. Crabtree, R. H. Chem. Rev. 1995, 95, 987
4. Olah, G. A.; Schlosberg, R. H. J. Am. Chem. Soc. 1968, 90, 2726
5. Olah, G. A.; Klopman, G.; Schlosberg, R. H. J. Am. Chem. Soc. 1969, 91, 3261
6. Goldberg, K. I.; Goldman, A. S. 223rd American Chemical Society Meeting, Orlando, FL, 2002.
7. Shilov, A. E. Activation of Saturated Hydrocarbons by Transition Metal Complexes; Reidel, Dordrecht, The Netherlands, 1984.
8. Periana, R. A.; Taube, D. J.; Evitt, E. R.; Loffler, D. G.; Wentrcek, P. R.; Voss, G.; Masuda, T. Science 1993, 259, 340
9. Periana, R. A.; Taube, D. J.; Gamble, S.; Taube, H.; Satoh, T.; Fujii, H. Science 1998, 280, 560
10. Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. Angew. Chem., Int. Ed. 1998, 37, 2181
11. Levchenko, L. A.; Sadkov, A. P.; Lariontseva, N. V.; Koldasheva, E. M.; Shilova, A. K.; Shilov, A. E. Dokl. Biochem. Biophys. 2001, 377, 123
12. Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507
13. Jones, C. J.; Taube, D.; Ziatdinov, V. R.; Periana, R. A.; Nielsen, R. J.; Oxgaard, J.; Goddard, W. A. Angew. Chem., Int. Ed. 2004, 43, 4626
14. Lersch, M.; Tilset, M. Chem. Rev. 2005, 105, 2471
15. Levchenko, L. A.; Lobanova, N. G.; Martynenko, V. M.; Sadkov, A. P.; Shestakov, A. F.; Shilova, A. K.; Shilov, A. E. Dokl. Chem. 2010, 430, 50
16. Periana, R. A.; Mironov, O.; Taube, D.; Bhalla, G.; Jones, C. J. Science 2003, 301, 814
17. Conley, B. L.; Tenn, W. J.; Young, K. J. H.; Ganesh, S. K.; Meier, S. K.; Ziatdinov, V. R.; Mironov, O.; Oxgaard, J.; Gonzales, J.; Goddard, W. A.; Periana, R. A. J. Mol. Catal. A: Chem. 2006, 251, 8
18. Xu, Z. T.; Oxgaard, J.; Goddard, W. A. Organometallics 2008, 27, 3770
19. Ahlquist, M.; Periana, R. A.; Goddard, W. A. Chem. Commun. 2009, 2373
20. Bagno, A.; Bukala, J.; Olah, G. A. J. Org. Chem. 1990, 55, 4284
21. Hogeveen, H.; Lukas, J.; Roobeek, C. F. J. Chem. Soc. D: Chem. Commun. 1969, 920
22. de Rege, P. J. E.; Gladysz, J. A.; Horvath, I. T. Adv. Synth. Catal. 2002, 344, 1059
23. Palkovits, R.; Antonietti, M.; Kuhn, P.; Thomas, A.; Schuth, F. Angew. Chem., Int. Ed. 2009, 48, 6909
24. Palkovits, R.; von Malotki, C.; Baumgarten, M.; Mullen, K.; Baltes, C.; Antonietti, M.; Kuhn, P.; Weber, J.; Thomas, A.; Schuth, F. ChemSusChem 2010, 3, 277
25. Forde, M. M.; Grazia, B. C.; Armstrong, R.; Jenkins, R. L.; Ab Rahim, M. H.; Carley, A. F.; Dimitratos, N.; Lopez-Sanchez, J. A.; Taylor, S. H.; McKeown, N. B.; Hutchings, G. J. J. Catal. 2012, 290, 177
26. Dobson, I. D. Green Chem. 2003, 5, G78
27. Fang, K. G.; Wang, X. P.; Zhang, J. L.; Cai, T. X. Chin. Chem. Lett. 2001, 12, 125
28. Sopa, A.; Waclaw-Held, A.; Grossy, M.; Pijanka, J.; Nowinska, K. Appl. Catal., A 2005, 285, 119
29. Luzgin, M. V.; Rogov, V. A.; Kotsarenko, N. S.; Shmachkova, V. P.; Stepanov, A. G. J. Phys. Chem. C 2007, 111, 10624
30. Wang, X.; Qi, G.; Xu, J.; Li, B.; Wang, C.; Deng, F. Angew. Chem., Int. Ed. 2012, 51, 3850
31. Fulmer, G. R.; Miller, A. J. M.; Sherden, N. H.; Gottlieb, H. E.; Nudelman, A.; Stoltz, B. M.; Bercaw, J. E.; Goldberg, K. I. Organometallics 2010, 29, 2176
32. Legrand, A. P.; Hommel, H.; de la Caillerie, J. B. D. Colloid. Surf. A 1999, 158, 157
33. Grinenval, E.; Rozanska, X.; Baudouin, A.; Berrier, E.; Delbecq, F.; Sautet, P.; Basset, J. M.; Lefebvre, F. J. Phys. Chem. C 2010, 114, 19024
34. Kozhevnikov, I. V.; Sinnema, A.; Vanbekkum, H. Catal. Lett. 1995, 34, 213
35. Geen, H.; Titman, J. J.; Gottwald, J.; Spiess, H. W. Chem. Phys. Lett. 1994, 227, 79
36. Rataboul, F.; Baudouin, A.; Thieuleux, C.; Veyre, L.; Coperet, C.; Thivolle-Cazat, J.; Basset, J. M.; Lesage, A.; Emsley, L. J. Am. Chem. Soc. 2004, 126, 12541
37. Avenier, P.; Taoufik, M.; Lesage, A.; Solans-Monfort, X.; Baudouin, A.; de Mallmann, A.; Veyre, L.; Basset, J. M.; Eisenstein, O.; Emsley, L.; Quadrelli, E. A. Science 2007, 317, 1056
38. Trebosc, J.; Wiench, J. W.; Huh, S.; Lin, V. S. Y.; Pruski, M. J. Am. Chem. Soc. 2005, 127, 3057
39. Ratcliffe, C. I.; Ripmeester, J. A.; Tse, J. S. Chem. Phys. Lett. 1985, 120, 427
40. Brown, G. M.; Noespirlet, M. R.; Busing, W. R.; Levy, H. A. Acta Crystallogr., Sect. B 1977, 33, 1038
41. Bielanski, A.; Datka, J.; Gil, B.; Malecka-Lubanska, A.; Micek-Ilnicka, A. Catal. Lett. 1999, 57, 61
42. Micek-Ilnicka, A. J. Mol. Catal. A: Chem. 2009, 308, 1
43. Izumi, Y.; Matsuo, K.; Urabe, K. J. Mol. Catal. 1983, 18, 299
44. Kulesza, P. J.; Faulkner, L. R.; Chen, J.; Klemperer, W. G. J. Am. Chem. Soc. 1991, 113, 379
45. Karwowska, B.; Kulesza, P. J. Electroanalysis 1995, 7, 1005
46. Berry, F. J.; Derrick, G. R.; Marco, J. F.; Mortimer, M. Mater. Chem. Phys. 2009, 114, 1000
47. Xie, F. Y.; Gong, L.; Liu, X.; Tao, Y. T.; Zhang, W. H.; Chen, S. H.; Meng, H.; Chen, J. J. Electron Spectrosc. Relat. Phenom. 2012, 185, 112
48. Vasireddy, S.; Ganguly, S.; Sauer, J.; Cook, W.; Spivey, J. J. Chem Commun 2011, 47, 785
49. Tungatarova, S. A. http://www.scientificfund.kz/index.php?option=com- content&view=article&id=22:structural.
50. Marion, D.; Wuthrich, K. Biochem. Biophys. Res. Commun. 1983, 113, 967
51. Rataboul, F.; Baudouin, A.; Thieuleux, C.; Veyre, L.; Coperet, C.; Thivolle-Cazat, J.; Basset, J. M.; Lesage, A.; Emsley, L. J. Am. Chem. Soc. 2004, 126, 12541
52. Schnell, I.; Spiess, H. W. J. Magn. Reson. 2001, 151, 153