Porosity of pillared clays studied by hyperpolarized 129Xe NMR spectroscopy and Xe adsorption isotherms

Langmuir

Volumn 29, Issue 2, 2013, Pages 643-652

  Keenan, Caroline D ^a   Herling, Markus M ^a   Siegel, Renée ^a   Petzold, Nikolaus ^a   Bowers, Clifford R ^b   Rössler, Ernst A ^a   Breu, Josef ^a   Senker, Jürgen ^a  

^a UNIVERSITY OF BAYREUTH   (Germany)

^b University of Florida   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBATE-ADSORBATE INTERACTION; ADSORPTION ENTHALPIES; BIMODAL DISTRIBUTION; CHARGE REDUCTION; DATA FITS; DEFECT CONCENTRATIONS; DICATIONS; HIGH RESOLUTION; HIGH-PRESSURE LIMITS; HYPERPOLARIZED; INTERLAYER SPACES; LAYER CHARGE; MAS NMR; MEAN DIAMETER; NMR MEASUREMENTS; PILLARED CLAY; PILLARED INTER-LAYERED CLAYS; PORE DIAMETERS; PORE DIMENSIONS; PORE SYSTEM; PORE VOLUME; SILICATE LAYERS; SOLID-STATE NMR SPECTROSCOPY; TEMPERATURE DEPENDENT;

ADSORBATES; DEFECTS; MICROSTRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHYSISORPTION; SILICATES;

XENON;

EID: 84872530507     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la304502r     Document Type: Article

References (56)

1. Cheetham, A. K.; Ferey, G.; Loiseau, T. Open-framework inorganic materials Angew. Chem., Int. Ed. 1999, 38, 3268-3292
2. Schoonheydt, R. A.; Pinnavaia, T.; Lagaly, G.; Gangas, N. Pillared clays and pillared layered solids Pure Appl. Chem. 1999, 71 (2) 2367-2371
3. Tsapatsis, M.; Maheshwari, S. Pores by pillaring: Not always a maze Angew. Chem., Int. Ed. 2008, 47, 4262-4263
4. Baumgartner, A.; Sattler, K.; Thun, J.; Breu, J. A route to microporous materials through oxidative pillaring of micas Angew. Chem., Int. Ed. 2008, 47, 1640-1644
5. Stöcker, M.; Seidl, W.; Seyfarth, L.; Senker, J.; Breu, J. Realisation of truly microporous pillared clays Chem. Commun. (Cambridge, U. K.) 2008, 5, 629-631
6. Stöcker, M.; Seyfarth, L.; Hirsemann, D.; Senker, J.; Breu, J. Microporous PILCs-Synthesis, pillaring mechanism and selective cation exchange Appl. Clay Sci. 2010, 48, 146-153
7. Baumgartner, A.; Wagner, F. E.; Herling, M.; Breu, J. Towards a tunable pore size utilizing oxidative pillaring of the mica ferrous tainiolite Microporous Mesoporous Mater. 2009, 123, 253-259
8. Nijs, H.; De Bock, M.; Maes, N.; Vansant, E. F. Theoretical evaluation of the microporosity of pillared layered double hydroxides J. Porous Mater. 1999, 6 (4) 307-321
9. Gomez-Romero, P.; Sanchez, C. In Functional Hybrid Materials; Gomez-Romero, P. S. C., Ed.; Wiley-VCH: Weinheim, 2004.
10. Yamagishi, A. In Dynamic Processes on Solid Surfaces; Tamaru, K., Ed.; Plenum Press: New York, 1993; p 307.
11. Breu, J.; Seidl, W.; Stoll, A. J.; Lange, K. G.; Probst, T. U. Charge homogeneity in synthetic fluorohectorite Chem. Mater. 2001, 13, 4213-4220
12. Breu, J.; Seidl, W.; Stoll, A. Fehlordnung bei smectiten in abhängigkeit vom zwischenschichtkation Z. Anorg. Allg. Chem. 2003, 629, 503-515
13. Möller, M. W.; Hirsemann, D.; Haarmann, F.; Senker, J.; Breu, J. Facile scalable synthesis of rectorites Chem. Mater. 2010, 22, 186-196
14. Mariychuk, R.; Baumgartner, A.; Wagner, F. E.; Lerf, A.; Dubbe, A.; Moos, R.; Breu, J. Synthesis, structure, and electric conductivity of ferrous tainiolite and its oxidative conversion into coarse-grained swellable smectite Chem. Mater. 2007, 19, 5377-5387
15. Kalo, H.; Möller, M. W.; Ziadeh, M.; Dolejs, D.; Breu, J. Large scale melt synthesis in an open crucible of Na-fluorohectorite with superb charge homogeneity and particle size Appl. Clay Sci. 2010, 48 (1-2) 39-45
16. Kalo, H.; Möller, M. W.; Kunz, D. A.; Breu, J. How to maximize the aspect ratio of clay nanoplatelets Nanoscale. 2012, 4 (18) 5633-5639
17. Hofmann, U.; Klemen, R. Verlust der austauschfaehigkeit von Lithiumionen an bentonit durch erhitzung Z. Anorg. Allg. Chem. 1950, 262, 95-99
18. Jaynes, W. F.; Traina, S. J.; Bigham, J. M.; Johnston, C. T. Preparation and characterization of reduced-charge hectorites Clays Clay Miner. 1992, 40, 397-404
19. Herling, M. M.; Kalo, H.; Seibt, S.; Schobert, R.; Breu, J. Tailoring the pore sizes of microporous pillared interlayered clays through layer charge reduction Langmuir 2012, 28 (41) 14713-14719
20. 129Xe-NMR of physisorbed xenon used as a probe for the study of microporous solids Appl. Magn. Reson. 1995, 8 (3-4) 427-456
21. 129Xe NMR for studying surface heterogeneity: well-known facts and new findings Langmuir 1997, 13 (5) 1229-1236
22. 129Xe NMR study of carbonaceous materials: effects of surface chemistry and nanotexture Carbon 1999, 37 (4) 591-600
23. 129Xe NMR spectroscopy J. Am. Chem. Soc. 2010, 132 (15) 5387-5393
24. 2(dabco) (DUT-8(Ni) J. Am. Chem. Soc. 2011, 133 (22) 8681-8690
25. 129Xe NMR J. Phys. Chem. C 2011, 116 (1) 22-29
26. Comotti, A.; Bracco, S.; Sozzani, P.; Horike, S.; Matsuda, R.; Chen, J.; Takata, M.; Kubota, Y.; Kitagawa, S. Nanochannels of two distinct cross-sections in a porous Al-based coordination polymer J. Am. Chem. Soc. 2008, 130 (41) 13664-13672
27. Shiratori, N.; Lee, K. J.; Miyawaki, J.; Hong, S.-H.; Mochida, I.; An, B.; Yokogawa, K.; Jang, J.; Yoon, S.-H. Pore structure analysis of activated carbon fiber by microdomain-based model Langmuir 2009, 25 (13) 7631-7637
28. Pawsey, S.; Kalebaila, K. K.; Moudrakovski, I.; Ripmeester, J. A.; Brock, S. L. Pore structure and interconnectivity of CdS aerogels and xerogels by hyperpolarized Xenon NMR J. Phys. Chem. C 2010, 114 (31) 13187-13195
29. 129Xe NMR Chem. Mater. 2012, 24 (20) 3952-3963
30. 129Xe NMR investigation of multifunctional organic/inorganic hybrid mesoporous silica materials Phys. Chem. Chem. Phys. 2005, 7 (16) 3080-3087
31. Walker, T. G.; Happer, W. Spin-exchange optical pumping of noble-gas nuclei Rev. Mod. Phys. 1997, 69 (2) 629-642
32. Goodson, B. M. Nuclear magnetic resonance of laser-polarized noble gases in molecules, materials, and organisms J. Magn. Reson. 2002, 155 (2) 157-216
33. Zook, A. L.; Adhyaru, B. B.; Bowers, C. R. High capacity production of > 65% spin polarized xenon-129 for NMR spectroscopy and imaging J. Magn. Reson. 2002, 159 (2) 175-182
34. Moudrakovski, I. L.; Lang, S.; Ratcliffe, C. I.; Simard, B.; Santyr, G.; Ripmeester, J. A. Chemical shift imaging with continuously flowing hyperpolarized xenon for the characterization of materials J. Magn. Reson. 2000, 144 (2) 372-377
35. 129Xe). In Studies in Surface Science and Catalysis; Grobet, P. J.; Mortier, W. J.; Vansant, E. F.; Schulz-Ekloff, G., Eds.; Elsevier: Amsterdam, 1988; Vol. 37, pp 183-189.
36. Thommes, M. Nanoporous Materials: Science and Engineering; Imperial College Press: London, 2004.
37. Fung, B. M.; Khitrin, A. K.; Ermolaev, K. An improved broadband decoupling sequence for liquid crystals and solids J. Magn. Reson. 2000, 142 (1) 97-101
38. Zhao, X.; Hoffbauer, W.; Schmedt auf der Günne, J.; Levitt, M. H. Heteronuclear polarization transfer by symmetry-based recoupling sequences in solid-state NMR Solid State Nucl. Magn. Reson. 2004, 26 (2) 57-64
39. 129Xe-MAS NMR studies of microporous materials Phys. Chem. Chem. Phys. 2003, 5 (20) 4479-4483
40. 19F MAS-NMR study of structural fluorine in some natural and synthetic 2:1 layer silicates Clays Clay Miner. 1992, 40 (2) 186-191
41. 19F nuclear magnetic resonance study of natural clays Clays Clay Miner. 1995, 43 (6) 697-704
42. 2+ sites in 2:1 layered silicates: an assessment of edge attack and gallery access mechanisms Clays Clay Miner. 1994, 42 (6) 717-723
43. Breu, J.; Seidl, W.; Senker, J. Synthese von dreidimensional geordneten einlagerungsverbindungen des hectorits Z. Anorg. Allg. Chem. 2004, 630 (1) 80-90
44. Kirkpatrick, R. J.; Smith, K. A.; Schramm, S.; Turner, G.; Yang, W.-H. Solid-state nuclear magnetic resonance spectroscopy of minerals Annu. Rev. Earth Planet. Sci 1985, 13, 29-47
45. 29Si NMR spectroscopy of 2:1 layer silicates; correlations among chemical shift, structural distortions, and chemical variations Carbon 1987, 72 (9-10) 935-942
46. Kinsey, R. A. K.; James, R.; Hower, J.; Smith, K.; Oldfield, E. High resolution aluminum-27 and silicon-29 nuclear magnetic resonance spectroscopic study of layer silicates, including clay minerals Am. Mineral. 1985, 70, 537-548
47. Gertsmans, A.; Urbanczyk, L.; Jéroîme, R.; Robert, J.-L.; Grandjean, J. XRD and NMR characterization of synthetic hectorites and the corresponding surfactant-exchanged clays Clay Miner. 2008, 43 (2) 205-212
48. 29Si MAS-NMR spectra of sepiolite and aliminated sepiolite Clay Miner. 1994, 29, 313-318
49. Cattaneo, A. S.; Bracco, S.; Comotti, A.; Galimberti, M.; Sozzani, P.; Eckert, H. Structural characterization of pristine and modified fluoromica using multinuclear solid-state NMR J. Phys. Chem. C 2011, 115 (25) 12517-12529
50. Jameson, C. J.; de Dios, A. C. Xe nuclear magnetic resonance line shapes in nanochannels J. Chem. Phys. 2002, 116 (9) 3805-3821
51. 129Xe NMR spectroscopy J. Phys. Chem. A 2000, 104 (50) 11665-11670
52. Comotti, A.; Bracco, S.; Ferretti, L.; Mauri, M.; Simonutti, R.; Sozzani, P. A single-crystal imprints macroscopic orientation on xenon atoms Chem. Commun. 2007, 4, 350-352
53. 129Xe NMR of xenon adsorbed on zeolites. Relationship between the chemical shift and the void space Chem. Phys. Lett. 1987, 136, 314-318
54. Massiot, D.; Fayon, F.; Capron, M.; King, I.; Le Calvé, S.; Alonso, B.; Durand, J. O.; Bujoli, B.; Gan, Z.; Hoatson, G. Modelling one and two-dimensional solid-state NMR spectra Magn. Reson. Chem. 2002, 40 (1) 70-76
55. Anedda, R.; Soldatov, D. V.; Moudrakovski, I. L.; Casu, M.; Ripmeester, J. A. A new approach to characterizing sorption in materials with flexible micropores Chem. Mater. 2008, 20 (9) 2908-2920
56. 2 nanotubes Bull. Korean Chem. Soc. 2012, 33 (2) 512-514