Shape memory behaviour of functionalised poly(ε-caprolactone) crosslinked by hexamethylene-diisocyanate

Current Organic Chemistry

Volumn 16, Issue 22, 2012, Pages 2708-2716

  Gomez d'Ayala, Giovanna ^a   Laurienzo, Paola ^a   Malinconico, Mario ^a   Nobile, Maria Rossella ^b   Pantalena, Diletta ^b   Russo, Roberto ^a  

^a CNR   (Italy)

^b UNIVERSITY OF SALERNO   (Italy)

Author keywords

Crosslinking; Poly(e caprolactone); Shape memory effect

Indexed keywords

ACRYLIC MONOMERS; CROSSLINKING; CYCLOHEXANE; SHAPE OPTIMIZATION;

CROSS-LINKING DEGREE; CROSSLINKED; FUNCTIONALIZED; GLYCIDYL METHACRYLATE; HEXAMETHYLENE DIISOCYANATE; POLY(E-CAPROLACTONE); POLY(Ε CAPROLACTONE); SHAPE MEMORY BEHAVIOR; SHAPE-MEMORY EFFECT;

SHAPE MEMORY EFFECT;

EID: 84872511662     PISSN: 13852728     EISSN: None     Source Type: Journal    
DOI: 10.2174/138527212804004535     Document Type: Article

References (40)

1. Lendlein, A.; Kelch, S. Shape-memory polymers. Angew. Chem., Int. Ed., 2002, 41, 2034-2057.
2. M. Irie. In: Shape Memory Materials; K. Otsuka, C.M. Wayman, Eds.; Cambridge University press: Cambridge, 1998.
3. Wei, Z.G.; Sandstrom, R.; Miyazaky, S. Shape-memorymaterials and hybrid composites for smart systems: Part I Shape-memory materials. J. Mater. Sci., 1998, 33, 3743-3762.
4. Beloshenko, V.A.; Varyukhin, V.N.; Voznyak, Y.V. The shape memory effect in polymers Russ. Chem. Rev., 2005, 74, 265-283.
5. Behl, M.; Lendlein, A. Shape-memory polymers. Mater. Today, 2007, 10(4), 20-28.
6. Liu, C.; Qin, H.; Mather, P.T. Review of progress in shape-memory polymers. J. Mater. Chem. 2007, 17, 1543-1558.
7. Rousseau, I.A. Challanges of shape memory polymers: a review of the progress toward overcoming SMP's limitations. Polym. Eng. Sci. 2008, 48, 2075-2089.
8. Charlesby, A. Atomic radiation and polymers. Pergamon Press, Oxford 1960, pp. 198-257
9. Li, F.; Zhu, W.; Zhang, X.; Zhao, C.; Xu, M. Shape memory effect of ethylene-vinyl acetate copolymers J. Appl. Polym. Sci. 1999, 71, 1063-1070.
10. Li, F.; Chen, Y.; Zhu, W.; Zhang, X.; Xu, M. Shape memory effect of polyethylene/nylon 6 graft copolymers. Polymer 1998, 39, 6929-6934.
11. Lee, B.S.; Chun, C.; Chung, Y.C.; Sul, K.I.; Cho, J.W. Structure and thermomechanical properties of polyurethane block copolymers with shape memory effect. Macromolecules 2001, 34, 6431-6437.
12. Zhu, G.M.; Xu, Q.Y.; Liang, G.Z.; Zhou, H.F. Shape-memory behaviors of sensitizing radiation-crosslinked polycaprolactone with polyfunctional poly(ester-acrylate). J. Appl. Polym. Sci. 2005, 95, 634-639.
13. Ping, P.; Wang, W.; Chen, X.; Jing, X. Poly(ε-polycaprolactone) polyurethane and its shape-memory property. Biomacromolecules 2005, 6, 587-592.
14. Lin, J. R.; Chen, L.W. Study on shape-memory behavior of polyether based polyurethanes. I. Influence of hard segment content. J. Appl. Polym. Sci. 1998, 69, 1563-1574.
15. Cao, F.; Jana, S.C. Nanoclay-tethered shape memory polyurethane nanocomposites. Polymer 2007, 48, 3790-3800
16. Yang, B.; Huang, W.W.; Li, C.; Li, L. Effects of moisture on the thermomechanical properties of a polyurethane shape memory polymer. Polymer 2006, 47, 1348-1356.
17. Jeong, H.M.; Lee, S.Y.; Kim, B.K. Shape memory polyurethane containing amorphous reversible phase. J. Mater. Sci. 2000, 35, 1579-1583.
18. Tobushi, H.; Hara, H.; Yamada, E.; Hayashi, S. Thermomechanical properties in a thin film of shape memory polymer of polyurethane series Smart Mater. Struct. 1996, 5, 483-491.
19. Small, W. IV; Singhal, P.; Wilson, T.S.; Maitland, D.J. J. Biomedical applications of thermally activated shape memory polymers. Mater. Chem 2010, 20, 3356-3366.
20. Lendlein, A.; Langer, R. Biodegradable, elastic shape-memory polymers for potential biomedical applications. Science 2002, 296, 1673-1679.
21. Zheng, X.; Zhou, S.; Li, X.; Weng, J. Shape memory properties of poly(D, Llactide)/ hydroxyapatite composites. Biomaterials 2006, 27, 4288-4295.
22. Metcalfe, A.; Desfaits, A.C.; Salazkin, I.; Yahia, L.; Sokolowski, W.M.; Raimond, J. Cold hibernated elastic memory foamsfor endovascular interventions. Biomaterials 2003, 24, 491-497.
23. Yakacky, CM.; Shandas, R.; Lanning, C.; Rech, B.; Eckstein, A.; Gall, K. Unconstrained recovery characterization of shape-memory polymer networks for cardiovascular applications. Biomaterials 2007, 28, 2255-2263.
24. Nagata, M.; Sato, Y. Synthesis and Properties of Photocurable Biodegradable Multiblock Copolymers Based on Poly(ε-caprolactone)and Poly(L-lactide) Segments. J. Polym. Sci. Part A, Polym. Chem. 2005, 43, 2426-2439.
25. Laurienzo, P.; Malinconico, M.; Mattia, G.; Romano, G. Synthesis and Characterization of Functionalized Crosslinkable Poly(ε-caprolactone). Macromol. Chem. Phys. 2006, 207, 1861-1869.
26. Mangiacapra, P.; Raimondo, M.; Tammaro, L.; Vittoria, V.; Malinconico, M.; Laurienzo, P. Nanometric dispersion of a Mg/Al layered double hydroxide into a chemically modified polycaprolactone. Biomacromolecules 2007, 8, 773-779.
27. Xie, X-M.; Chen, N.-H.; Guo, B.-H.; Li, S. Study of multi-monomer meltgrafting onto a polypropylene in an extruder. Polym. Int. 2000, 46, 1677-1683.
28. Yu, Z.-Z.; Yang, M.-S.; Dai, S.-C.; Mai, Y.-W. Toughening of recycled poly(ethylene terephthalate) with a maleic anhydride grafted SEBS triblock copolymer. J. Appl. Polym. Sci. 2004, 93 (4), 1462-1472.
29. Fushimi, A.; Okude, Y.; Ishikura, S. A new curing system for automotive topcoat. Progr. Org. Coat. 2001, 42, 159-166.
30. Gurtler, C.; Danielmeier, K. A catalytic system for the reaction of carboxylic acids with aliphatic isocyanates. Tetrahedron Lett. 2004, 45, 2515-2521.
31. Khanna, Y.P. Rheological Mechanism and overview of nucleated crystallization kinetics. Macromolecules 1993, 26, 3639-3643.
32. Bove, L.; Nobile, M.R. Shear-induced crystallization of isotactic poly(1-butene). Macromol. Symposia 2002, 185, 135-147.
33. Iervolino, R.; Somma, E.; Nobile, M.R.; Chen, X.; Hsiao, B.S. The role of multi-walled carbon nanotubes in shear enhanced crystallization of isotactic poly(1-butene). J. Therm. Anal. Calorim. 2009, 98, 611-622.
34. Kelarakis, A.; Mai, S.M.; Booth, C.; Ryan, A.J. Can rheometry measure crystallization kinetics? A comparative study using block copolymers. Polymer 2005, 46, 2739-2747.
35. Bove, L.; Nobile, M.R. Shear flow effects on polymer melts crystallization: Kinetic features Macromol. Symp. 2002, 180, 169-180.
36. Gomez d'Ayala, G.; Di Pace, E.; Laurienzo, P.; Pantalena, D.; Somma, E.; Nobile, M.R. Poly(ε-caprolactone) modified by functional groups: preparation and chemical-physical investigation. Eur. Polym. J. 2009, 45, 3217-3229.
37. Peterlin, A. Crystallization from a strained melt or solution. Polym. Eng. Sci. 1976, 16, 126-137.
38. Hobbs, J.K. In situ atomic force microscopy of the melting of meltcrystallized polyethylene. Polymer 2006, 47, 5566-5573.
39. Kimata, S.; Sakurai, T.; Nozue, Y.; Kasahara, T.; Yamaguchi, N.; Karino, T.; Shibayama, M.; Kornfield, J.A. Molecular basis of the shish-kebab morphology in polymer crystallization. Science 2007, 316, 1014-1017.
40. Wang, M.; Zhang, L. Recovery as a measure of oriented crystalline structure in poly(ether-ester)s based on poly(ethylene oxide) and poly(ethylene terephthalate) used as shape memory polymers. J. Polym. Sci. B, Polym. Phys. 1999, 37, 101-112.