Surface-mediated synthesis of dimeric rhodium catalysts on MgO: Tracking changes in the nuclearity and ligand environment of the catalytically active sites by x-ray absorption and infrared spectroscopies

Chemistry - A European Journal

Volumn 19, Issue 4, 2013, Pages 1235-1245

  Yardimci, Dicle ^a   Serna, Pedro ^a   Gates, Bruce C ^a  

^a University of California Davis   (United States)

Author keywords

catalysis; cluster compounds; dimerization; hydrogenation; rhodium; supported catalysts

Indexed keywords

ACTIVE SITE; CATALYTIC PERFORMANCE; CLUSTER COMPOUNDS; DINUCLEAR; ETHYLENE HYDROGENATION; IR SPECTRUM; METAL-SUPPORT INTERACTIONS; MGO; MOLECULAR SURFACES; NUCLEARITY; RHODIUM CATALYSTS; RHODIUM CLUSTER; SURFACE MEDIATED REACTION; SYNTHETIC ROUTES;

CATALYSIS; CATALYST ACTIVITY; CATALYST SUPPORTS; DIMERIZATION; DIMERS; ETHYLENE; HYDROGENATION; LIGANDS; SURFACE REACTIONS; X RAY ABSORPTION;

RHODIUM;

EID: 84872443198     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201202514     Document Type: Article

References (56)

1. F. A. Cotton, G. Wilkinson, C. A. Murillo, M. Bochmann, Advanced Inorganic Chemistry, 6 th ed., Wiley, New York, 1999.
2. K. K. Bando, K. Asakura, H. Arakawa, K. Isobe, Y. Iwasawa, J. Phys. Chem. 1996, 100, 13636-13645.
3. R. Whyman, Chem. Commun. 1970, 1194-1195.
4. L. A. Hanlan, G. A. Ozin, J. Am. Chem. Soc. 1974, 96, 6324-6329.
5. M. D. Fryzuk, W. E. Piers, Can. J. Chem. 1989, 67, 883-896.
6. C. Grazia Arena, F. Faraone, M. Lanfranchi, E. Rotondo, A. Tiripicchio, Inorg. Chem. 1992, 31, 4797-4802.
7. K. Isobe, D. G. Andrews, B. E. Mann, P. M. J. Maitlis, J. Chem. Soc. Chem. Commun. 1981, 809-810.
8. K. Asakura, K. Kitamura-Bando, K. Isobe, H. Arakawa, Y. Iwasawa, J. Am. Chem. Soc. 1990, 112, 3242-3244
9. K. Asakura, K. Kitamura-Bando, Y. Iwasawa, H. Arakawa, K. Isobe, J. Am. Chem. Soc. 1990, 112, 9096-9104.
10. K. Kitamura-Bando, K. Asakura, H. Arakawa, Y. Sugi, K. Isobe, Y. Iwasawa, J. Chem. Soc. Chem. Commun. 1990, 253-255
11. M. Tada, Y. Iwasawa, Coord. Chem. Rev. 2007, 251, 2702-2716.
12. A. Berkõ, G. Menesi, F. Solymosi, J. Phys. Chem. 1996, 100, 17732-17734.
13. A. Suzuki, Y. Inada, A. Yamaguchi, T. Chihara, M. Yuasa, M. Nomura, Y. Iwasawa, Angew. Chem. 2003, 115, 4943-4979.
14. A. Berkõ, F. Solymosi, J. Catal. 1999, 183, 91-101.
15. T. T. T. Wong, A. Y. Stakheev, W. M. H. Sachtler, J. Phys. Chem. 1992, 96, 7733-7740.
16. V. A. Bhirud, J. O. Ehresmann, P. W. Kletnieks, J. F. Haw, B. C. Gates, Langmuir 2006, 22, 490-496.
17. A. J. Liang, R. Craciun, M. Chen, T. G. Kelly, P. W. Kletnieks, J. F. Haw, D. A. Dixon, B. C. Gates, J. Am. Chem. Soc. 2009, 131, 8460-8473.
18. D. C. Koningsberger, B. L. Mojet, G. E. van Dorssen, D. E. Ramaker, Top. Catal. 2000, 10, 143-155.
19. A. Uzun, V. Ortalan, N. D. Browning, B. C. Gates, J. Catal. 2010, 269, 318-328.
20. K. Chhor, J. F. Bocquet, C. Pommier, Mater. Chem. Phys. 1995, 40, 63-68.
21. A. Uzun, B. C. Gates, Angew. Chem. 2008, 120, 9385-9388
22. Angew. Chem. Int. Ed. 2008, 47, 9245-9248.
23. A. J. Liang, B. C. Gates, J. Phys. Chem. C 2008, 112, 18039-18049.
24. Q. Wang, J. C. Hanson, A. I. Frenkel, J. Chem. Phys. 2008, 129, 234502-234507.
25. A. Kohl, S. Labich, E. Taglauer, H. Knözinger, Surf. Sci. 2000, 454-456, 974-978.
26. F. W. Lytle, D. E. Sayers, E. A. Stern, Physica B 1989, 158, 701-722.
27. P. Serna, B. C. Gates, J. Am. Chem. Soc. 2011, 133, 4714-4717.
28. L. F. Rao, A. Fukuoka, N. Kosugi, H. Kuroda, M. Ichikawa, J.Phys. Chem. 1990, 94, 5317-5327.
29. A. D. Allian, Y. Wang, M. Saeys, G. M. Kuramshina, M. Garland, Vib. Spectrosc. 2006, 41, 101-111.
30. S. Kawi, Z. Xu, B. C. Gates, Inorg. Chem. 1994, 33, 503-509.
31. E. Cariati, C. Dragonetti, D. Roberto, R. Ugo, E. Lucenti, Inorg. Chim. Acta 2003, 349, 189-194.
32. J. H. B. Chenier, M. Histed, J. A. Howard, H. A. Joly, H. Morris, B. Mile, Inorg. Chem. 1989, 28, 4114-4119.
33. X. Feng, C. Xie, Z. Liu, Y. Xie, R. B. King, H. F. Schaefer III, Dalton Trans. 2009, 2599-2608.
34. J. Rasko, E. Novak, F. Solymosi, Catal. Today 1996, 27, 115-121.
35. J. F. Goellner, B. C. Gates, G. N. Vayssilov, N. Rösch, J. Am. Chem. Soc. 2000, 122, 8056-8066.
36. J. Lu, P. Serna, C. Aydin, N. D. Browning, B. C. Gates, J. Am. Chem. Soc. 2011, 133, 16186-16195.
37. J. Lu, P. Serna, B. C. Gates, ACS Catal. 2011, 1, 1549-1561.
38. G. Parkin, Struct. Bonding (Berlin) 2010, 136, 113-146.
39. F. Shafiq, R. Eisenberg, Inorg. Chem. 1993, 32, 3287-3294.
40. M. D. Fryzuk, W. E. Piers, S. J. Rettig, F. W. B. Einstein, T. Jones, T. A. Albright, J. Am. Chem. Soc. 1989, 111, 5709-5721.
41. G. Bor, Pure Appl. Chem. 1986, 58, 543-552.
42. A. S. Al-Ammar, G. Webb, J. Chem. Soc. Faraday Trans. 1 1979, 75, 1900-1911.
43. J. Grunes, J. Zhu, M. Yang, G. A. Somorjai, Catal. Lett. 2003, 86, 157-161.
44. S. Alayoglu, A. U. Nilekar, M. Mavrikakis, B. Eichhorn, Nat. Mater. 2008, 7, 333-338.
45. P. Serna, B. C. Gates, Angew. Chem. 2011, 123, 5642-5645
46. Angew. Chem. Int. Ed. 2011, 50, 5528-5531.
47. Homogeneous Catalysis by Coordination Compounds:, J. Halpern, in Homogeneous Catalysis, Industrial Applications and Implications (Ed.:, B. J. Luberoff,), American Chemical Society, Washington D. C., 1974, Chapter 1, pp. 1-24.
48. J. F. Young, J. A. Osborn, F. A. Jardine, G. J. Wilkinson, J. Chem. Soc., Chem. Commun. 1965, 7, 131-132.
49. C.-K. Tsung, J. N. Kuhn, W. Huang, C. Aliaga, L.-I. Hung, G. A. Somorjai, P. Yang, J. Am. Chem. Soc. 2009, 131, 5816-5822.
50. M. Newville, B. Ravel, D. Haskel, J. J. Rehr, E. A. Stern, Y. Yacoby, Physica B 1995, 208/209, 154-156.
51. M. J. Newville, J. Synchrotron Radiat. 2001, 8, 96-100.
52. S. I. Zabinsky, J. J. Rehr, A. Ankudinov, R. C. Albers, M. J. Eller, Phys. Rev. B 1995, 52, 2995-3009.
53. P. Villars, L. D. Calvert, W. B. Pearson, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, American Society for Metals, Metals Park, 1985, pp. 3090-3091.
54. M. Bühl, M. Hakansson, A. H. Mahmoudkhani, L. Ohrstrom, Organometallics 2000, 19, 5589-5596.
55. P. S. Kirlin, F. B. M. van Zon, D. C. Koningsberger, B. C. Gates, J. Phys. Chem. 1990, 94, 8439-8450.
56. J. B. A. D. van Zon, D. C. Koningsberger, H. F. J. van′t Blik, D. E. Sayers, J. Chem. Phys. 1985, 82, 5742-5754.