Zeolite- and MgO-supported molecular iridium complexes: Support and ligand effects in catalysis of ethene hydrogenation and H-D exchange in the conversion of H2 + D2

ACS Catalysis

Volumn 1, Issue 11, 2011, Pages 1549-1561

  Lu, Jing ^a   Serna, Pedro ^a   Gates, Bruce C ^a  

^a University of California   (United States)

Author keywords

ethene hydrogenation; EXAFS spectroscopy; IR spectroscopy; MgO; supported iridium complex catalyst; zeolite

Indexed keywords

ACETYLACETONATES; AS-LIGANDS; CO LIGANDS; ELECTRON-DEFICIENT; ETHENE HYDROGENATION; EXCHANGE REACTION; EXTENDED X-RAY ABSORPTION FINE STRUCTURES; H-D EXCHANGE; IRIDIUM COMPLEX; LIGAND EFFECT; METAL OXIDES; MGO; SUPPORTED IRIDIUM COMPLEX CATALYST; X-RAY ABSORPTION NEAR-EDGE STRUCTURE; ZEOLITE SUPPORT;

ABSORPTION; ABSORPTION SPECTRA; ABSORPTION SPECTROSCOPY; CATALYST ACTIVITY; ETHYLENE; EXTENDED X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY; HELIUM; HYDROGENATION; IRIDIUM; LIGANDS; METAL COMPLEXES; X RAY ABSORPTION;

IRIDIUM COMPOUNDS;

EID: 80655142280     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs200397r     Document Type: Article

References (43)

1. Coq, B.; Figueras, F. Cood. Chem. Rev. 1998, 178-180, 1753
2. Kawi, S.; Gates, B. C. In Clusters and Colloids: From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; p 299 -365.
3. Goellner, J. F.; Gates, B. C.; Vayssilov, G. N.; Rösch, N. J. Am. Chem. Soc. 2000, 122, 8056-8066
4. Uzun, A.; Bhirud, V. A.; Kletnieks, P. W.; Haw, J. F.; Gates, B. C. J. Phys. Chem. C 2007, 111, 15064-15073
5. Uzun, A.; Ortalan, V.; Browning, N. D.; Gates, B. C. Chem. Commun. 2009, 31, 4657-4659
6. Bhirud, V. A.; Uzun, A.; Kletnieks, P. W.; Craciun, R.; Haw, J. M.; Dixon, D. A.; Olmstead, M. M.; Gates, B. C. J. Organomet. Chem. 2007, 692, 2107-2113
7. Niu, H.; Yang, Q.; Tang, K.; Xie, Y. Microporous Mesoporous Mater. 2006, 96, 428-433
8. Uzun, A.; Ortalan, V.; Browning, N. D.; Gates, B. C. J. Catal. 2010, 269, 318-328
9. Burkhardt, I.; Gutschick, D.; Landsmesser, H.; Miessner, H. In Zeolite Chemistry and Catalysis; Jacobs, P.A., Ed.; Elsevier: Amsterdam, 1991; p 215-222.
10. Solymosi, F.; Novak, E.; Molnar, A. J. Phys. Chem. 1990, 94, 7250-7255
11. Mihaylov, M.; Ivanova, E.; Thibault-Starzyk, F.; Daturi, M.; Dimitrov, L.; Hadjiivanov, K. I. J. Phys. Chem. B 2006, 110, 10383-10389
12. Liang, A. J.; Bhirud, V. A.; Ehresmann, J. O.; Kletnieks, P. W.; Haw, J. F.; Gates, B. C. J. Phys. Chem. B 2005, 109, 24236-24243
13. Liang, A. J.; Craciun, R.; Chen, M.; Kelly, T. G.; Kletnieks, P. W.; Haw, J. F.; Dixon, D. A.; Gates, B. C. J. Am. Chem. Soc. 2009, 131, 8460-8473
14. Ogino, I.; Gates, B. C. J. Phys. Chem. C 2010, 114, 8405-8413
15. Miessner, H.; Burkhardt, I.; Gutschick, D.; Zecchina, A.; Morterra, C.; Spoto, G. J. Chem. Soc., Faraday Trans 1989, 85, 2113-2126
16. ethene contributions (in terms of both the atomic weights and bonding distances), we chose for simplicity to lump these two contributions. For details of EXAFS analysis of supported metal complexes, see: Alexeev, O.; Gates, B. C. Top. Catal. 2000, 10, 273-293
17. Serna, P.; Gates, B. C. J. Am. Chem. Soc. 2011, 133, 4714-4717
18. Beaumont, R; Barthomeuf, D. J. Catal. 1972, 26, 218-225
19. Beaumont, R; Barthomeuf, D. J. Catal. 1972, 27, 45-51
20. Miessner, H.; Kosslick, H.; Lohse, U.; Parlitz, B.; Tuan, V.-A. J. Phys. Chem. 1993, 97, 974-9748
21. Samant, M. G.; Boudart, M. J. Phys. Chem. 1991, 95, 4070-4074
22. Grunes, J.; Zhu, J.; Yang, M.; Somorjai, G. A. Catal. Lett. 2003, 86, 15-161
23. Hadjiivanov, K. I.; Vayssilov, G. N. Adv. Catal. 2002, 47, 308-511
24. Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry; Wiley-Interscience, New York, 1967.
25. Kondo, J. N.; Domen, K.; Hirose, C. J. Phys. Chem. 1995, 99, 10573-10580
26. Knodo, J. N.; Nishitani, R.; Yoda, E.; Yokoi, T.; Tatsumi, T.; Domen, K. Phys. Chem. Chem. Phys. 2010, 12, 11576-11586
27. Li, F.; Gates, B. C. J. Phys. Chem. B 2004, 108, 11259-11264
28. Astruc, D. Organometallic Chemistry and Catalysis; Springer: Berlin, Heidelberg, New York, 2007.
29. Wang, Q.; Hanson, J. C.; Frenkel, A. I. J. Chem. Phys. 2008, 129, 234502-234507
30. Senior, W. A.; Verrall, R. E. J. Phys. Chem. 1969, 73, 4242-4249
31. Lu, J.; Serna, P.; Aydin, C.; Browning, N. D.; Gates, B. C. J. Am. Chem. Soc. 2011, 133; DOI: 10.1021/ja206486j.
32. Odzak, J. F.; Argo, A. M.; Lai, F. S.; Gates, B. C. Rev. Sci. Instrum. 2001, 72, 3943-3945
33. Newville, M.; Ravel, B.; Haskel, D.; Rehr, J. J.; Stern, E. A.; Yacoby, Y. Physica B 1995, 208/209, 154-156
34. Newville, M. J. Synchrotron Radiat. 2001, 8, 96-100
35. Vaarkamp, M.; Linders, J. C.; Koningsberger, D. C. Physica B 1995, 209, 159-160
36. Koningsberger, D. C.; Mojet, B. L.; van Dorssen, G. E.; Ramaker, D. E. Top. Catal. 2000, 10, 143-155
37. Zabinsky, S. E.; Rehr, J. J.; Ankudinov, A.; Albers, R. C.; Eller, M. J. Phys. Rev. B. 1995, 52, 2995-3009
38. Carney, G. O., Jr. Ph.D. Thesis, University of North Carolina at Chapel Hill, 1942.
39. van Zon, F. B. M.; Kirlin, P. S.; Gates, B. C.; Koningsberger, D. C. J. Phys. Chem. 1989, 93, 2218-2222
40. Duivenvoorden, F. B. M.; Koningsberger, D. C.; Uh, Y. S.; Gates, B. C. J. Am. Chem. Soc. 1986, 108, 6254-6262
41. Pearson, W. B.; Calvert, L. D.; Villars, P. Pearson?s Handbook of Crystallographic Data for Intermetallic Phases; American Society for Metals: Metals Park, OH, 1985.
42. Ogino, I.; Gates, B. C. J. Am. Chem. Soc. 2008, 130, 13338-13346
43. Lytle, F. W.; Sayers, D. E.; Stern, E. A. Physica B 1989, 158, 701-722