Concertedness in proton-coupled electron transfer cleavages of carbon-metal bonds illustrated by the reduction of an alkyl cobalt porphyrin

Chemical Science

Volumn 4, Issue 2, 2013, Pages 819-823

  Costentin, Cyrille ^a   Passard, Guillaume ^a   Robert, Marc ^a   Savéant, Jean Michel ^a  

^a UNIVERSITÉ PARIS DESCARTES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL HALIDES; BOND-BREAKING; CARBON-METAL BONDS; CATALYTIC CURRENT; COBALT PORPHYRINS; COBALT-CARBON BOND; ELECTRON TRANSFER; PROTON-COUPLED ELECTRON TRANSFER; REDUCTIVE CLEAVAGE; SMALL MOLECULES; TETRAPHENYL PORPHYRINS; VITAMIN B; VOLTAMMETRIC ANALYSIS;

COBALT; ELECTRON TRANSITIONS; METAL COMPLEXES; PORPHYRINS; PROTON TRANSFER; TRANSITION METAL COMPOUNDS;

REDUCTION;

EID: 84872086440     PISSN: 20416520     EISSN: 20416539     Source Type: Journal    
DOI: 10.1039/c2sc21788k     Document Type: Article

References (37)

1. J. Stubbe D. G. Nocera C. S. Yee M. C. Y. Chang Chem. Rev. 2003 103 2167 2202
2. S. Y. Reece J. M. Hodgkiss J. Stubbe D. G. Nocera Philos. Trans. R. Soc. London, Ser. B 2006 361 1351 1364
3. J. L. Dempsey J. R. Winkler H. B. Gray Chem. Rev. 2010 110 7024 7039
4. S. Hammes-Schiffer A. A. Stuchebrukhov Chem. Rev. 2010 110 6939 6960
5. J. J. Warren T. A. Tronic J. M. Mayer Chem. Rev. 2010 110 6961 7001
6. C. Costentin M. Robert J.-M. Saveant Chem. Rev. 2010 110 PR1 PR40
7. J. Rosenthal D. G. Nocera Acc. Chem. Res. 2007 40 543 553
8. C. Costentin V. Hajj M. Robert J.-M. Saveant C. Tard Proc. Natl. Acad. Sci. U. S. A. 2011 108 8559 8564
9. L. Smith L. Mervyn P. W. Muggleton A. W. Johnson N. Shaw Ann. N.Y. Acad. Sci. 1964 112 564 574
10. G. N. Schrauzer E. Deutsch R. L. Windgassen J. Am. Chem. Soc. 1968 90 2441 2442
11. M. Momenteau M. Fournier M. Rougée J. Chim. Phys. 1970 67 926 931
12. M. Momenteau D. Lexa Biochem. Biophys. Res. Commun. 1974 58 940 944
13. M. Perrée-Fauvet A. Gaudemer P. Boucly J. Devinck J. Organomet. Chem. 1976 120 439 451
14. D. Lexa J.-M. Savéant J. P. Soufflet J. Electroanal. Chem. 1979 100 159 172
15. L. Nadjo J.-M. Savéant J. Electroanal. Chem. 1973 48 113 145
16. J.-M. Savéant, Elements of molecular and biomolecular electrochemistry: an electrochemical approach to electron transfer chemistry, John Wiley & Sons, Hoboken, NJ, 2006, Ch. 2, pp. 80-84
17. 12, Academic Press, New York, 1972
18. ed., D. Dolphin, B12, John Wiley, New York, 1982, vol. I and II
19. D. Lexa J.-M. Savéant J. Am. Chem. Soc. 1978 100 3220 3222
20. D. Lexa J.-M. Savéant Acc. Chem. Res. 1983 16 235 243
21. J. M. Pratt, in Chemistry and Biochemistry of B12, ed., R. Banerjee, John Wiley & Sons, New York, 1999
22. R. L. Birke Q. Huang T. Spataru D. K. Gosser J. Am. Chem. Soc. 2006 128 1922 1936
23. T. Spataru R. L. Birke J. Phys. Chem. A 2006 110 8599 8604
24. T. Spataru R. L. Birke J. Electroanal. Chem. 2006 593 74 86
25. O. Tinembart L. Walder R. Scheffold Ber. Bunsen-Ges. 1988 92 1225 1231
26. D. L. Zhou O. Tinembart R. Scheffold L. Walder Helv. Chim. Acta 1990 73 2225 2241
27. D. L. Zhou P. Walder R. Scheffold L. Walder Helv. Chim. Acta 1992 75 995 1011
28. M. D. Vlasie R. Banerjee J. Am. Chem. Soc. 2003 125 5431 5435
29. J. E. Arguello C. Costentin S. Griveau J.-M. Savéant J. Am. Chem. Soc. 2005 127 5049 5055
30. J.-M. Savéant and E. Vianello, in Advances in Polarography, ed., I. S. Longmuir, Pergamon Press, Cambridge, UK, 1st edn, 1959, vol. 1, p 367
31. M. Rudolph J. Electroanal. Chem. 2003 543 23 39
32. A. Cardinale A. A. Isse A. Gennaro M. Robert J.-M. Savéant J. Am. Chem. Soc. 2002 124 13533 13539
33. C. Costentin C. Louault M. Robert J.-M. Savéant Proc. Natl. Acad. Sci. U. S. A. 2009 106 18143 18148
34. C. P. Andrieux J. Gamby P. Hapiot J.-M. Savéant J. Am. Chem. Soc. 2003 125 10119 10124
35. J. Gamby, Thèse Université Paris-Diderot-Paris VII, 2003
36. N. Bortolamei A. A. Isse A. Gennaro Electrochim. Acta 2010 55 8312 8318
37. K. Izutsu, Acid-Base Dissociation Constants in Dipolar Aprotic Solvents, Blackwell, 1990, pp. 17-35