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84871739247
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Experimental procedure for synthesis of 2,6-bis{[(R)-2-(diphenylmethoxy)- 1,1-binaphthyl-2-yloxy]methyl}pyridine: To a round bottom flask containing a solution of (R)-2-(diphenylmethoxy)-1,1-binaphthyl-2-ol (4.4mmol) in THF (18 mL) a solution of sodium hydroxide (10mmol) in water (0.5 mL) was added
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Experimental procedure for synthesis of 2,6-bis{[(R)-2-(diphenylmethoxy)- 1,1-binaphthyl-2-yloxy]methyl}pyridine: To a round bottom flask containing a solution of (R)-2-(diphenylmethoxy)-1,1-binaphthyl-2-ol (4.4mmol) in THF (18 mL) a solution of sodium hydroxide (10mmol) in water (0.5 mL) was added.
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84871729393
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General procedure for the synthesis of bis-BINOL triflate derivative ether, 2a2c: In a dry Schlenk, equipped with magnetic stirrer, containing 2,2-bis-BINOLate desired (2.3mmol) was sequentially added, under inert atmosphere (N2) at a temperature of 0 °C, dry dichloromethane (20 mL), dry pyridine (0.56 mL, 6.9mmol) and finally triflic anhydride (1.6 g, 5.4mmol). After adding all components of the reaction mixture, the reaction was left at room temperature for 4 h
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General procedure for the synthesis of bis-BINOL triflate derivative ether, 2a2c: In a dry Schlenk, equipped with magnetic stirrer, containing 2,2-bis-BINOLate desired (2.3mmol) was sequentially added, under inert atmosphere (N2) at a temperature of 0 °C, dry dichloromethane (20 mL), dry pyridine (0.56 mL, 6.9mmol) and finally triflic anhydride (1.6 g, 5.4mmol). After adding all components of the reaction mixture, the reaction was left at room temperature for 4 h.
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0000513598
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A. E. S. Gelpke, H. Kooijman, A. L. Spek, H. Hiemstra, Chem.®Eur. J. 1999, 5, 2472.
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Gelpke, A.E.S.1
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0034602421
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F. Y. Kwong, A. S. C. Chan, K. S. Chan, Tetrahedron 2000, 56, 8893.
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W. Hu, C.-C. Chen, G. Xue, A. S. C. Chan, Tetrahedron: Asymmetry 1998, 9, 4183.
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84871752143
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General procedure for the synthesis of bisphosphine ether: To a dried Schlenk, equipped with magnetic stirrer, containing [NiCl2(dppe)] (1.1 g, 2mmol) under inert atmosphere (N2), was added dry DMF (2 mL), followed by diphenylphosphine (2mmol) at room temperature
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General procedure for the synthesis of bisphosphine ether: To a dried Schlenk, equipped with magnetic stirrer, containing [NiCl2(dppe)] (1.1 g, 2mmol) under inert atmosphere (N2), was added dry DMF (2 mL), followed by diphenylphosphine (2mmol) at room temperature.
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B. A. Prakasam, K. Ramalingam, G. Bocelli, A. Cantoni, Bull. Chem. Soc. Jpn. 2006, 79, 113.
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Prakasam, B.A.1
Ramalingam, K.2
Bocelli, G.3
Cantoni, A.4
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84871802461
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Supporting Information is available electronically on the CSJ-Journal Web site
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Supporting Information is available electronically on the CSJ-Journal Web site, http://www.csj.jp/journals/chem-lett/index.html.
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