In situ reaction monitoring reveals a diastereoselective ligand exchange reaction between the intrinsically chiral Au38(SR)24 and chiral thiols

Journal of the American Chemical Society

Volumn 134, Issue 50, 2012, Pages 20302-20305

  Knoppe, Stefan ^a   Azoulay, Raymond ^a   Dass, Amala ^b   Bürgi, Thomas ^a  

^a UNIVERSITY OF GENEVA   (Switzerland)

^b UNIVERSITY OF MISSISSIPPI   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHIRAL THIOLS; DIASTEREOSELECTIVE; DITHIOLS; ELECTRONIC EFFECTS; ENANTIOPURE; GOLD CLUSTERS; IN-SITU REACTIONS; LIGAND EXCHANGE REACTIONS; PRODUCT MIXTURE; TAILORED PROPERTIES;

CHEMICAL REACTIONS; CHIRALITY; ENANTIOMERS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY;

GOLD COMPOUNDS;

1,1' BINAPHTHYL 2,2' DITHIOL; 2 PHENYLETHYLTHIOLATE; GOLD; THIOL; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CIRCULAR DICHROISM; COMPLEX FORMATION; CRYSTAL STRUCTURE; DIASTEREOISOMER; ENANTIOMER; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; LIGAND BINDING; MATRIX ASSISTED LASER DESORPTION IONIZATION TIME OF FLIGHT MASS SPECTROMETRY; RACEMIZATION; STEREOCHEMISTRY; SUBSTITUTION REACTION; ULTRAVIOLET SPECTROSCOPY;

EID: 84871393976     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja310330m     Document Type: Article

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