Racemization of a chiral nanoparticle evidences the flexibility of the gold-thiolate interface

Journal of the American Chemical Society

Volumn 134, Issue 31, 2012, Pages 13114-13120

  Knoppe, Stefan ^a   Dolamic, Igor ^a   Bürgi, Thomas ^a  

^a UNIVERSITY OF GENEVA   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PARAMETER; BOND-BREAKING; CHEMICAL FUNCTIONALITY; FUTURE APPLICATIONS; GOLD NANOCLUSTER; GOLD NANOPARTICLES; LIGAND SHELLS; PLACE EXCHANGE; THIOLATES;

ACTIVATION ENERGY; GOLD; PRECISION ENGINEERING; SULFUR;

STEREOCHEMISTRY;

GOLD NANOPARTICLE; THIOL;

ACCURACY; ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHIRALITY; DECOMPOSITION; ENERGY; MOLECULAR INTERACTION; RACEMIZATION; REACTION ANALYSIS; TEMPERATURE DEPENDENCE;

CHROMATOGRAPHY, HIGH PRESSURE LIQUID; CIRCULAR DICHROISM; GOLD; ISOMERISM; METAL NANOPARTICLES; SPECTROPHOTOMETRY, ULTRAVIOLET; SULFHYDRYL COMPOUNDS;

EID: 84864717607     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3053865     Document Type: Article

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