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Volumn 31, Issue 23, 2012, Pages 8388-8406

Activation and deactivation of neutral palladium(II) phosphinesulfonato polymerization catalysts

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SPECIES; ALKYL COMPLEXES; CATALYST PRECURSORS; CHAIN GROWTH; DFT CALCULATION; DIFFRACTION ANALYSIS; ETHYLENE POLYMERIZATION; FREE LIGANDS; HYDRIDE COMPLEXES; HYDRIDE ELIMINATION; ISOLATION AND CHARACTERIZATION; NMR AND X-RAY; NMR TUBES; OXIDATIVE ADDITIONS; PALLADIUM COMPLEXES; PALLADIUM HYDRIDE; PHOSPHINE OXIDE; PHOSPHONIUM SALTS; POLYMER CHAINS; POLYMERIZATION CATALYSTS; POLYMERIZATION CONDITIONS; POLYMERIZATION TIME; PRESSURE REACTORS; RATE-LIMITING STEPS; REACTION COORDINATES; REACTION SEQUENCES; REDUCTIVE ELIMINATION; TRANSITION-STATE;

EID: 84870911631     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om300969d     Document Type: Article
Times cited : (59)

References (75)
  • 19
    • 84861609159 scopus 로고    scopus 로고
    • A broad scope of polar monomers can be incorporated in ethylene copolymers with cationic phosphine-phosphineoxide Pd(II) complexes: Carrow, B. P.; Nozaki, K. J. Am. Chem. Soc. 2012, 134, 8802-8805
    • (2012) J. Am. Chem. Soc. , vol.134 , pp. 8802-8805
    • Carrow, B.P.1    Nozaki, K.2
  • 31
    • 84870949758 scopus 로고    scopus 로고
    • Ref 19b
    • Ref 19b.
  • 34
    • 84870898786 scopus 로고    scopus 로고
    • Ref 24b
    • Ref 24b.
  • 37
    • 0035250085 scopus 로고    scopus 로고
    • An unidentified chain coupling reaction of palladium carbyl complexes has been proposed to account for the increased polydispersity due to a bimodal distribution in living ethylene polymerization by palladium diimine complexes. Cleavage of palladium polymeryl species by triethylsilane after polymerization yields fully saturated polymer chains and avoids bimodal molecular weight distribution, thus narrowing polydispersities: Gottfried, A. C.; Brookhart, M. Macromolecules 2001, 34, 1140-1142
    • (2001) Macromolecules , vol.34 , pp. 1140-1142
    • Gottfried, A.C.1    Brookhart, M.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.