Stereodivergence in amine-catalyzed regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles

Journal of the American Chemical Society

Volumn 134, Issue 48, 2012, Pages 19942-19947

  Feng, Xin ^a   Zhou, Zhi ^a   Zhou, Rong ^a   Zhou, Qing Qing ^a   Dong, Lin ^a   Chen, Ying Chun ^a,b  

^a SICHUAN UNIVERSITY   (China)

^b CHONGQING MEDICAL UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

[4 + 2] CYCLOADDITION; CATALYTIC SYSTEM; CYCLOADDITIONS; CYCLOADDUCTS; DIASTEREO- AND ENANTIOSELECTIVITY; DIELS-ALDER CYCLOADDITIONS; HYDROGEN BONDING INTERACTIONS; MALONONITRILES; MICHAEL ADDITIONS; PRIMARY AMINES; REACTION PATTERNS; REGIO-SELECTIVE; SALICYLIC ACIDS; SWITCHABLE;

ADDITION REACTIONS; CATALYSIS; CYCLOADDITION; HYDROGEN BONDS; REACTION INTERMEDIATES; REGIOSELECTIVITY;

ORGANIC COMPOUNDS;

6' HYDROXY 9 AMINO 9 DEOXYEPIQUINIDINE; 9 AMINO 9 DEOXYEPIQUINIDINE; AMINE; BICYCLO[2.2.2]OCTANE DERIVATIVE; CYCLIC ENONE DERIVATIVE; KETONE DERIVATIVE; MALONONITRILE; QUINIDINE; QUININE; SALICYLIC ACID; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CYCLOADDITION; DIELS ALDER REACTION; HYDROGEN BOND; MICHAEL ADDITION; STEREOCHEMISTRY;

AMINES; CATALYSIS; CYCLIZATION; MOLECULAR STRUCTURE; NITRILES; STEREOISOMERISM;

EID: 84870678367     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3106219     Document Type: Article

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