A comparison of the chemical sinks of atmospheric organics in the gas and aqueous phase

Atmospheric Chemistry and Physics

Volumn 12, Issue 17, 2012, Pages 8205-8222

  Epstein, S A ^a   Nizkorodov, S A ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; COMPARATIVE STUDY; HYDROXYL RADICAL; PARTITIONING; PHOTOCHEMISTRY; PHOTOLYSIS; REACTION KINETICS; SOURCE-SINK DYNAMICS; VOLATILE ORGANIC COMPOUND;

EID: 84869059005     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-12-8205-2012     Document Type: Article

References (75)

1. Albinet, A., Minero, C., and Vione, D.: Phototransformation processes of 2,4-dinitrophenol, relevant to atmospheric water droplets, Chemosphere, 80, 753-758, 2010.
2. Andreae, M. O. and Crutzen, P. J.: Atmospheric Aerosols: Biogeochemical Sources and Role in Atmospheric Chemistry, Science, 276, 1052-1058, doi:10.1126/science.276.5315.1052, 1997. (Pubitemid 27218103)
3. Atkinson, R.: A structure-activity relationship for the estimation of rate constants for the gas-phase reactions of OH radicals with organic compounds, Int. J. Chem. Kinet., 19, 799-828, doi:10.1002/kin.550190903, 1987.
4. Atkinson, R.: Estimation of gas-phase hydroxyl radical rate constants for organic chemicals, Environ. Toxicol. Chem., 7, 435-442, doi:10.1002/etc. 5620070604, 1988.
5. Atkinson, R.: Gas-phase tropospheric chemistry of organic compounds: A review, Atmos. Environ. A-Gen., 24, 1-41, 1990. (Pubitemid 20149112)
6. 3 Radical with Organic Compounds, J. Phys. Chem. Ref. Data, 20, 459-507, 1991.
7. Atkinson, R. and Arey, J.: Atmospheric Degradation of Volatile Organic Compounds, Chem. Rev., 103, 4605-4638, doi:10.1021/cr0206420, 2003.
8. Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II-gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625-4055, doi:10.5194/acp-6-3625-2006, 2006. (Pubitemid 44369557)
9. Audiffren, N., Renard, M., Buisson, E., and Chaumerliac, N.: Deviations from the Henry's law equilibrium during cloud events: a numerical approach of the mass transfer between phases and its specific numerical effects, Atmos. Res., 49, 139-161, 1998. (Pubitemid 29020641)
10. Bailey, P. S.: Organic chemistry, vol. 39, pt. 1: Ozonation in organic chemistry, vol. 1: Olefinic compounds; Academic Press, 1978.
11. Bateman, A. P., Nizkorodov, S. A., Laskin, J., and Laskin, A.: Photolytic processing of secondary organic aerosols dissolved in cloud droplets, PCCP, 13, 12199-12212, 2011.
12. Bell, R. P. and Gold, V.: The Reversible Hydration of Carbonyl Compounds, in: Adv. Phys. Org. Chem., Academic Press, 1-29, 1966.
13. Bell, R. P. and McDougall, A. O.: Hydration equilibria of some aldehydes and ketones, Trans. Faraday Soc., 56, 1281-1285, 1960.
14. Buxton, G. V., Greenstock, C. L., Helman, W. P., and Ross, A. B.: Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals in aqueous Solution, J. Phys. Chem. Ref. Data, 17, 513-886, 1988.
15. Calvert, J. G. and Pitts, J. N.: Photochemistry, Wiley, 1966.
16. Chaumerliac, N., Leriche, M., and Audiffren, N.: Modeling of scavenging processes in clouds: some remaining questions about the partitioning of gases among gas and liquid phases, Atmos. Res., 53, 29-43, 2000.
17. Chebbi, A. and Carlier, P.: Carboxylic acids in the troposphere, occurrence, sources, and sinks: A review, Atmos. Environ., 30, 4233-4249, 1996.
18. Chu, L. and Anastasio, C.: Formation of Hydroxyl Radical from the Photolysis of Frozen Hydrogen Peroxide, J. Phys. Chem. A, 109, 6264-6271, doi:10.1021/jp051415f, 2005. (Pubitemid 41083909)
19. Czaplicka, M.: Photo-degradation of chlorophenols in the aqueous solution, J. Hazard. Mater., 134, 45-59, 2006. (Pubitemid 44255708)
20. De Bruyn, W. J., Swartz, E., Hu, J. H., Shorter, J. A., Davidovits, P., Worsnop, D. R., Zahniser, M. S., and Kolb, C. E.: Henry's law solubilities and Setchenow coefficients for biogenic reduced sulfur species obtained from gas-liquid uptake measurements, J. Geophys. Res., 100, 7245-7251, doi:10.1029/95jd00217, 1995.
21. Donahue, N. M., Robinson, A. L., and Pandis, S. N.: Atmospheric organic particulate matter: from smoke to secondary organic aerosol, Atmos. Environ., 43, 94-106, 2009.
22. Dong, S. and Dasgupta, P. K.: Solubility of gaseous formaldehyde in liquid water and generation of trace standard gaseous formaldehyde, Environ. Sci. Technol., 20, 637-640, doi:10.1021/es00148a016, 1986. (Pubitemid 16040668)
23. Epstein, S. A., Shemesh, D., Tran, V. T., Nizkorodov, S. A., and Gerber, R. B.: Absorption spectra and photolysis of methyl peroxide in liquid and frozen water, J. Phys. Chem. A, 24, 6068-6077, 2012.
24. Ervens, B. and Volkamer, R.: Glyoxal processing by aerosol multiphase chemistry: towards a kinetic modeling framework of secondary organic aerosol formation in aqueous particles, Atmos. Chem. Phys., 10, 8219-8244, doi:10.5194/acp-10-8219-2010, 2010.
25. Ervens, B., George, C., Williams, J. E., Buxton, G. V., Salmon, G. A., Bydder, M., Wilkinson, F., Dentener, F., Mirabel, P., Wolke, R., and Herrmann, H.: CAPRAM 2.4 (MODAC mechanism): An extended and condensed tropospheric aqueous phase mechanism and its application, J. Geophys. Res., 108, 4426, doi:10.1029/2002jd002202, 2003a.
26. Ervens, B., Gligorovski, S., and Herrmann, H.: Temperaturedependent rate constants for hydroxyl radical reactions with organic compounds in aqueous solutions, PCCP, 5, 1811-1824, 2003b.
27. Ervens, B., Turpin, B. J., and Weber, R. J.: Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies, Atmos. Chem. Phys., 11, 11069-11102, doi:10.5194/acp-11-11069-2011, 2011.
28. Farkas, L. and Hirshberg, Y.: The Photochemical Decomposition of Aliphatic Alcohols in Aqueous Solution, J. Am. Chem. Soc., 59, 2450-2453, doi:10.1021/ja01290a104, 1937.
29. Faust, B. C.: Photochemistry of clouds, fogs, and aerosols, Environ. Sci. Technol., 28, 216A-222A, doi:10.1021/es00054a712, 1994.
30. Faust, B. C. and Allen, J. M.: Aqueous-phase photochemical formation of hydroxyl radical in authentic cloudwaters and fogwaters, Environ. Sci. Technol., 27, 1221-1224, doi:10.1021/es00043a024, 1993. (Pubitemid 23178645)
31. Faust, B. C., Powell, K., Rao, C. J., and Anastasio, C.: Aqueousphase photolysis of biacetyl (An alpha-dicarbonyl compound): A sink for biacetyl, and a source of acetic acid, peroxyacetic acid, hydrogen peroxide, and the highly oxidizing acetylperoxyl radical in aqueous aerosols, fogs, and clouds, Atmos. Environ., 31, 497-510, 1997.
32. Finlayson-Pitts, B. J. and Pitts, J. N.: Chemistry of the Upper and Lower Atmosphere, Academic Press, San Diego, 2000.
33. Gelencśer and Varga: Evaluation of the atmospheric significance of multiphase reactions in atmospheric secondary organic aerosol formation, Atmos. Chem. Phys., 5, 2823-2831, doi:10.5194/acp-5-2823-2005, 2005.
34. Goldstein, A. H. and Galbally, I. E.: Known and Unexplored Organic Constituents in the Earth's Atmosphere, Environ. Sci. Technol., 41, 1514-1521, doi:10.1021/es072476p, 2007. (Pubitemid 46362448)
35. 2: quantum yield and applications for polychromatic UV actinometry in photoreactors, Environ. Sci. Technol., 41, 7486-7490, doi:10.1021/es071379t, 2007. (Pubitemid 350080350)
36. Graedel, T. E. and Goldberg, K. I.: Kinetic Studies of Raindrop Chemistry 1. Inorganic and Organic Processes, J. Geophys. Res., 88, 10865-10882, doi:10.1029/JC088iC15p10865, 1983. (Pubitemid 14561446)
37. Graedel, T. E. and Weschler, C. J.: Chemistry within aqueous atmospheric aerosols and raindrops, Rev. Geophys., 19, 505-539, doi:10.1029/RG019i004p00505, 1981. (Pubitemid 12504493)
38. Guzḿan, M. I., Colussi, A. J., and Hoffmann, M. R.: Photoinduced oligomerization of aqueous pyruvic acid, J. Phys. Chem. A, 110, 3619-3626, doi:10.1021/jp056097z, 2006.
39. 2 ice core record anomalies, J. Geophys. Res., 112, D10123, doi:10.1029/2006jd007886, 2007. (Pubitemid 47193625)
40. Haag, W. R. and Yao, C. C. D.: Rate constants for reaction of hydroxyl radicals with several drinking water contaminants, Environ. Sci. Technol., 26, 1005-1013, doi:10.1021/es00029a021, 1992.
41. Hirshberg, Y. and Farkas, L.: On the Photochemical Decomposition of Aliphatic Aldehydes in Aqueous Solutions, J. Am. Chem. Soc., 59, 2453-2457, doi:10.1021/ja01290a105, 1937.
42. Hobbs, P. V.: Aerosol-Cloud-Climate Interactions, Academic Press, 1993.
43. Hummel, J. R. and Reck, R. A.: A Global Surface Albedo Model, J. Appl. Meteorol., 18, 239-253, 1979.
44. Kolb, C. E., Jayne, J. T., Worsnop, D. R., and Davidovits, P.: Solubility data requirements and new experimental methods in atmospheric aerosol research, Pure and applied chemistry, Research Triangle Park, NC, ETATS-UNIS, 10 pp., 1997.
45. Kwok, E. S. C. and Atkinson, R.: Estimation of hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: An update, Atmos. Environ., 29, 1685-1695, 1995. (Pubitemid 26436793)
46. Larsen, M. C. and Vaida, V.: Near Infrared Photochemistry of Pyruvic Acid in Aqueous Solution, J. Phys. Chem. A, 116, 5840-5846, doi:10.1021/jp2087972, 2012.
47. Le Botlan, D. J., Mechin, B. G., and Martin, G. J.: Proton and carbon-13 nuclear magnetic resonance spectrometry of formaldehyde in water, Anal. Chem., 55, 587-591, doi:10.1021/ac00254a041, 1983.
48. Ledger, M. B. and Porter, G.: Primary photochemical processes in aromatic molecules. Part 15.-The photochemistry of aromatic carbonyl compounds in aqueous solution, J. Chem. Soc. Faraday T., 68, 539-553, 1972.
49. Lee, M., Heikes, B. G., and O'Sullivan, D. W.: Hydrogen peroxide and organic hydroperoxide in the troposphere: a review, Atmos. Environ., 34, 3475-3494, 2000. (Pubitemid 30330742)
50. Leermakers, P. A. and Vesley, G. F.: The Photochemistry of alpha-Keto Acids and alpha-Keto Esters. I. Photolysis of Pyruvic Acid and Benzoylformic Acid, J. Am. Chem. Soc., 85, 3776-3779, doi:10.1021/ja00906a013, 1963.
51. Leriche, M., Voisin, D., Chaumerliac, N., Monod, A., and Aumont, B.: A model for tropospheric multiphase chemistry: application to one cloudy event during the CIME experiment, Atmos. Environ., 34, 5015-5036, 2000.
52. Limbeck, A. and Puxbaum, H.: Dependence of in-cloud scavenging of polar organic aerosol compounds on the water solubility, J. Geophys. Res., 105, 19857-19867, doi:10.1029/2000jd900123, 2000.
53. Madronich, S.: Photodissociation in the Atmosphere 1. Actinic Flux and the Effects of Ground Reflections and Clouds, J. Geophys. Res., 92, 9740-9752, doi:10.1029/JD092iD08p09740, 1987.
54. Marini, A., Munoz-Losa, A., Biancardi, A., and Mennucci, B.: What is Solvatochromism?, J. Phys. Chem. B, 114, 17128-17135, doi:10.1021/jp1097487, 2010.
55. Mayer, B. and Madronich, S.: Actinic flux and photolysis in water droplets: Mie calculations and geometrical optics limit, Atmos. Chem. Phys., 4, 2241-2250, doi:10.5194/acp-4-2241-2004, 2004. (Pubitemid 40008493)
56. Monod, A., Poulain, L., Grubert, S., Voisin, D., and Wortham, H.: Kinetics of OH-initiated oxidation of oxygenated organic compounds in the aqueous phase: new rate constants, structure activity relationships and atmospheric implications, Atmos. Environ., 39, 7667-7688, 2005.
57. Monod, A., Chevallier, E., Durand Jolibois, R., Doussin, J. F., Picquet-Varrault, B., and Carlier, P.: Photooxidation of methylhydroperoxide and ethylhydroperoxide in the aqueous phase under simulated cloud droplet conditions, Atmos. Environ., 41, 2412-2426, 2007. (Pubitemid 46275503)
58. Moortgat, G. K.: Important photochemical processes in the atmosphere, Pure Appl. Chem., 73, 487-490, 2001.
59. Nguyen, T. B., Laskin, A., Laskin, J., and Nizkorodov, S. A.: Direct aqueous photochemistry of isoprene high-nox secondary organic aerosol, PCCP, 14, 9702-9714, 2012.
60. Pankow, J. F. and Asher, W. E.: SIMPOL.1: a simple group contribution method for predicting vapor pressures and enthalpies of vaporization of multifunctional organic compounds, Atmos. Chem. Phys., 8, 2773-2796, doi:10.5194/acp-8-2773-2008, 2008.
61. Rohrer, F. and Berresheim, H.: Strong correlation between levels of tropospheric hydroxyl radicals and solar ultraviolet radiation, Nature, 442, 184-187, 2006. (Pubitemid 44086562)
62. Ruggaber, A., Dlugi, R., Bott, A., Forkel, R., Herrmann, H., and Jacobi, H. W.: Modelling of radiation quantities and photolysis frequencies in the aqueous phase in the troposphere, Atmos. Environ., 31, 3137-3150, 1997. (Pubitemid 27361814)
63. Sander, R.: Compilation of Henry's Law constants for inorganic and organic species of potential importance in environmental chemistry (Version 3), available at: http://www.henrys-law.org, 1999.
64. Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., andWine, P. H.: Chemical kinetics and photochemical data for use in atmospheric studies: Evaluation number 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, available at: http://jpldataeval.jpl.nasa.gov, 2011.
65. Saxena, P. and Hildemann, L. M.: Water-soluble organics in atmospheric particles: A critical review of the literature and application of thermodynamics to identify candidate compounds, J. Atmos. Chem., 24, 57-109, 1996.
66. Schwarzenbach, R. P., Gschwend, P. M., and Imboden, D. M.: Frontmatter, in: Environmental Organic Chemistry, John Wiley & Sons, Inc., i-xiii, 2005.
67. Seinfeld, J. and Pandis, S.: Atmospheric Chemistry and Physics, John Wiley and Sons, Inc., New York, 1998.
68. Vaitilingom, M., Amato, P., Sancelme, M., Laj, P., Leriche, M., and Delort, A. M.: Contribution of microbial activity to carbon chemistry in clouds, Appl. Environ. Microbiol., 76, 23-29, 2010.
69. Vione, D., Maurino, V., Minero, C., Pelizzetti, E., Harrison, M. A. J., Olariu, R.-I., and Arsene, C.: Photochemical reactions in the tropospheric aqueous phase and on particulate matter, Chem. Soc. Rev., 35, 441-453, 2006. (Pubitemid 44004948)
70. Wallace, J. M. and Hobbs, P. V.: Atmospheric Science: An Introductory Survey, in: International Geophysics Series, edited by: Dmowska, R., Hartmann, D., and Rossby, H. T., Academic Press, 2006.
71. Wan, H. B.,Wong, M. K., and Mok, C. Y.: Comparative study on the quantum yields of direct photolysis of organophosphorus pesticides in aqueous solution, J. Agric. Food. Chem., 42, 2625-2630, doi:10.1021/jf00047a046, 1994.
72. Winiwarter, W., Fierlinger, H., Puxbaum, H., Facchini, M. C., Arends, B. G., Fuzzi, S., Schell, D., Kaminski, U., Pahl, S., Schneider, T., Berner, A., Solly, I., and Kruisz, C.: Henry's law and the behavior of weak acids and bases in fog and cloud, J. Atmos. Chem., 19, 173-188, doi:10.1007/bf00696588, 1994.
73. Xu, H., Wentworth, P. J., Howell, N. W., and Joens, J. A.: Temperature dependent near-UV molar absorptivities of aliphatic aldehydes and ketones in aqueous solution, Spectrochim. Acta A, 49, 1171-1178, 1993.
74. 2 at 308 and 351 nm in the temperature range 278-353 K, J. Atmos. Chem., 10, 411-425, doi:10.1007/bf00115783, 1990. (Pubitemid 20355865)
75. Zimmerman, H. E. and Sandel, V. R.: Mechanistic organic photochemistry. II.1,2 Solvolytic photochemical reactions, J. Am. Chem. Soc., 85, 915-922, doi:10.1021/ja00890a019, 1963.