메뉴 건너뛰기




Volumn 41, Issue 21, 2007, Pages 7486-7490

Photolysis of aqueous H2O2: Quantum yield and applications for polychromatic UV actinometry in photoreactors

Author keywords

[No Author keywords available]

Indexed keywords

METHANOL; PHOTOLYSIS; QUANTUM YIELD; SOLUTIONS; ULTRAVIOLET RADIATION;

EID: 36048953100     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es071379t     Document Type: Article
Times cited : (206)

References (41)
  • 2
    • 0023365880 scopus 로고
    • Potassium ferrioxalate as chemical actinometer in ultraviolet reactors
    • Harris, G. D.; Adams, V. D.; Moore, W. M.; Sorensen, D. L. Potassium ferrioxalate as chemical actinometer in ultraviolet reactors. J. Environ. Eng. 1987, 113, 612-627.
    • (1987) J. Environ. Eng , vol.113 , pp. 612-627
    • Harris, G.D.1    Adams, V.D.2    Moore, W.M.3    Sorensen, D.L.4
  • 3
    • 0001723737 scopus 로고
    • The photolysis of potassium peroxodisulphate in aqueous solution in the presence of tert-butanol: A simple actinometer for 254 nm radiation
    • Mark, G.; Schuchmann, M. N.; Schuchmann, H. P.; von Sonntag, C. The photolysis of potassium peroxodisulphate in aqueous solution in the presence of tert-butanol: a simple actinometer for 254 nm radiation. J. Photochem. Photobiol., A 1990, 55, 157-168.
    • (1990) J. Photochem. Photobiol., A , vol.55 , pp. 157-168
    • Mark, G.1    Schuchmann, M.N.2    Schuchmann, H.P.3    von Sonntag, C.4
  • 4
    • 33646232005 scopus 로고    scopus 로고
    • The iodide/iodate actinometer in UV disinfection: Determination of the fluence rate distribution in UV reactors
    • Rahn, R. O.; Bolton, J.; Stefan, M. I. The iodide/iodate actinometer in UV disinfection: Determination of the fluence rate distribution in UV reactors. Photochem. Photobiol. 2006, 82, 611-615.
    • (2006) Photochem. Photobiol , vol.82 , pp. 611-615
    • Rahn, R.O.1    Bolton, J.2    Stefan, M.I.3
  • 5
    • 0010821416 scopus 로고    scopus 로고
    • Estimating effective germicidal dose from medium pressure UV lamps
    • Linden, K. G.; Darby, J. L. Estimating effective germicidal dose from medium pressure UV lamps. J. Environ. Eng. 1997, 123, 1142-1149.
    • (1997) J. Environ. Eng , vol.123 , pp. 1142-1149
    • Linden, K.G.1    Darby, J.L.2
  • 6
    • 33746173278 scopus 로고    scopus 로고
    • Polychromatic UV fluence measurement using chemical actinometry, biodosimetry, and mathematical techniques
    • Jin, S.; Mofidi, A. A.; Linden, K. G. Polychromatic UV fluence measurement using chemical actinometry, biodosimetry, and mathematical techniques. J. Environ. Eng. 2006, 132, 831-841.
    • (2006) J. Environ. Eng , vol.132 , pp. 831-841
    • Jin, S.1    Mofidi, A.A.2    Linden, K.G.3
  • 7
    • 18944402116 scopus 로고    scopus 로고
    • Shen, C.; Fang, S.; Bergstrom, D. E.; Blatchley, E. R. (E)-5-[2-(Methoxycarbonyl)ethenyl]cytidine as a chemical actinometer for germicidal UV radiation. Environ. Sci. Technol. 2005, 39, 3826-3832.
    • Shen, C.; Fang, S.; Bergstrom, D. E.; Blatchley, E. R. (E)-5-[2-(Methoxycarbonyl)ethenyl]cytidine as a chemical actinometer for germicidal UV radiation. Environ. Sci. Technol. 2005, 39, 3826-3832.
  • 8
    • 36048980232 scopus 로고    scopus 로고
    • Hatchard, C. G.; Parker, C. A. A new sensitive chemical actinometer. II. Potasium ferrioxalate as a standard chemical actinometer. Proc. Roy. Soc., Ser. A 1956, 235, 518-536.
    • Hatchard, C. G.; Parker, C. A. A new sensitive chemical actinometer. II. Potasium ferrioxalate as a standard chemical actinometer. Proc. Roy. Soc., Ser. A 1956, 235, 518-536.
  • 9
    • 0001692803 scopus 로고
    • Determination of the quantum yield of the ferrioxalate actinometer with electrically calibrated radiometers
    • Demas, J. N.; Bowman, W. D.; Zalewskl, E. F.; Velapoldl, R. A. Determination of the quantum yield of the ferrioxalate actinometer with electrically calibrated radiometers. J. Phys. Chem. 1981, 85, 2766-2771.
    • (1981) J. Phys. Chem , vol.85 , pp. 2766-2771
    • Demas, J.N.1    Bowman, W.D.2    Zalewskl, E.F.3    Velapoldl, R.A.4
  • 10
    • 0242365543 scopus 로고    scopus 로고
    • Quantum yield of the iodide-iodate chemical actinometer: Dependence on wavelength and concentration
    • Rahn, R. O.; Stefany, M. I.; Bolton, J. R.; Goren, E.; Shaw, P.-S.; Lykke, K. R. Quantum yield of the iodide-iodate chemical actinometer: Dependence on wavelength and concentration. Photochem. Photobiol. 2003, 78, 146-152.
    • (2003) Photochem. Photobiol , vol.78 , pp. 146-152
    • Rahn, R.O.1    Stefany, M.I.2    Bolton, J.R.3    Goren, E.4    Shaw, P.-S.5    Lykke, K.R.6
  • 12
    • 0001569233 scopus 로고
    • The photochemical decomposition of hydrogen peroxide. Quantum yields, tracer and fractionation effects
    • Hunt, J. P.; Taube, H. The photochemical decomposition of hydrogen peroxide. Quantum yields, tracer and fractionation effects. J. Am. Chem. Soc. 1952, 74, 5999-6002.
    • (1952) J. Am. Chem. Soc , vol.74 , pp. 5999-6002
    • Hunt, J.P.1    Taube, H.2
  • 13
    • 0000860088 scopus 로고
    • The primary quantum yield of hydrogen peroxide decomposition
    • Weeks, J. L.; Matheson, M. S. The primary quantum yield of hydrogen peroxide decomposition. J. Am. Chem. Soc. 1956, 78, 1273.
    • (1956) J. Am. Chem. Soc , vol.78 , pp. 1273
    • Weeks, J.L.1    Matheson, M.S.2
  • 14
    • 0000860090 scopus 로고
    • The primary quantum yield in the photolysis of hydrogen peroxide at 3130 Å and the primary radical yield in the X- and γ-radiolysis of water
    • Dainton, F. S. The primary quantum yield in the photolysis of hydrogen peroxide at 3130 Å and the primary radical yield in the X- and γ-radiolysis of water. J. Am. Chem. Soc. 1956, 78, 1278-1279.
    • (1956) J. Am. Chem. Soc , vol.78 , pp. 1278-1279
    • Dainton, F.S.1
  • 15
    • 0000876156 scopus 로고
    • The photochemical decomposition of hydrogen peroxide in aqueous solutions of allyl alcohol at 2537 Å
    • Volman, D. H.; Chen, J. C. The photochemical decomposition of hydrogen peroxide in aqueous solutions of allyl alcohol at 2537 Å J. Am. Chem. Soc. 1959, 81, 4141-4144.
    • (1959) J. Am. Chem. Soc , vol.81 , pp. 4141-4144
    • Volman, D.H.1    Chen, J.C.2
  • 16
    • 0013176759 scopus 로고
    • Radiolysis and photolysis of the hydrogen peroxide-p-nitrosodimethylaniline-oxygen system
    • Hatada, M.; Kraljic, I.; El Samahy, A.; Trumbore, C. N. Radiolysis and photolysis of the hydrogen peroxide-p-nitrosodimethylaniline-oxygen system. J. Phys. Chem. 1974, 78, 888-891.
    • (1974) J. Phys. Chem , vol.78 , pp. 888-891
    • Hatada, M.1    Kraljic, I.2    El Samahy, A.3    Trumbore, C.N.4
  • 17
    • 0000428023 scopus 로고
    • Ultraviolet molar absorptivities of aqueous hydrogen peroxide and hydroperoxyl ion
    • Morgan, M. S.; Van Trieste, P. F.; Garlick, S. M.; Mahon, M. J.; Smith, A. L. Ultraviolet molar absorptivities of aqueous hydrogen peroxide and hydroperoxyl ion. Anal. Chim. Acta 1988, 215, 325-329.
    • (1988) Anal. Chim. Acta , vol.215 , pp. 325-329
    • Morgan, M.S.1    Van Trieste, P.F.2    Garlick, S.M.3    Mahon, M.J.4    Smith, A.L.5
  • 18
    • 0025092549 scopus 로고
    • 2 at 308 and 351 nm in the temperature range 278-353 K
    • 2 at 308 and 351 nm in the temperature range 278-353 K. J. Atmos. Chem. 1990, 10, 411-425.
    • (1990) J. Atmos. Chem , vol.10 , pp. 411-425
    • Zellner, R.1    Exner, M.2    Herrmann, M.3
  • 19
    • 0037422392 scopus 로고    scopus 로고
    • Hydrogen peroxide photolysis in acidic aqueous solutions containing chloride ions. I. Chemical mechanism
    • Yu, X.-Y.; Barker, J. R. Hydrogen peroxide photolysis in acidic aqueous solutions containing chloride ions. I. Chemical mechanism. J. Phys. Chem. A 2003, 107, 1313-1324.
    • (2003) J. Phys. Chem. A , vol.107 , pp. 1313-1324
    • Yu, X.-Y.1    Barker, J.R.2
  • 20
    • 23144461593 scopus 로고    scopus 로고
    • Formation of hydroxyl radical from the photolysis of frozen hydrogen peroxide
    • Chu, L.; Anastasio, C. Formation of hydroxyl radical from the photolysis of frozen hydrogen peroxide. J. Phys. Chem. A 2005, 109, 6264-6271.
    • (2005) J. Phys. Chem. A , vol.109 , pp. 6264-6271
    • Chu, L.1    Anastasio, C.2
  • 21
    • 77049138167 scopus 로고
    • The colorimetric estimation of formaldehyde by means of the Hantzsch reaction
    • Nash, T. The colorimetric estimation of formaldehyde by means of the Hantzsch reaction. Biochem. J. 1953, 55, 416-421.
    • (1953) Biochem. J , vol.55 , pp. 416-421
    • Nash, T.1
  • 22
    • 36049052522 scopus 로고    scopus 로고
    • In ref 21, both 7700 and 8000 M-1 cm-1 are reported. We observed in independent experiments that the lower value is more appropriate
    • -1 are reported. We observed in independent experiments that the lower value is more appropriate.
  • 23
    • 36049006142 scopus 로고    scopus 로고
    • The ferrioxalate and iodide-iodate actinometers in the UV region
    • in press
    • Goldstein, S.; Rabani, J. The ferrioxalate and iodide-iodate actinometers in the UV region. J. Photochem. Photobiol., A 2007, in press.
    • (2007) J. Photochem. Photobiol., A
    • Goldstein, S.1    Rabani, J.2
  • 24
    • 0000450518 scopus 로고
    • Pulse radiolytic study of the site of hydroxyl radical attack on aliphatic alcohols in aqueous solution
    • Asmus, K. D.; Moeckel, H.; Henglein, A. Pulse radiolytic study of the site of hydroxyl radical attack on aliphatic alcohols in aqueous solution. J. Phys. Chem. 1973, 77, 1218-1221.
    • (1973) J. Phys. Chem , vol.77 , pp. 1218-1221
    • Asmus, K.D.1    Moeckel, H.2    Henglein, A.3
  • 26
    • 33947298622 scopus 로고
    • 2 in aqueous solutions by pulse radiolysis
    • 2 in aqueous solutions by pulse radiolysis. J. Phys. Chem. 1969, 73, 3736-3744.
    • (1969) J. Phys. Chem , vol.73 , pp. 3736-3744
    • Rabani, J.1    Nielsen, S.O.2
  • 27
    • 33947294218 scopus 로고
    • Acid dissociation constant and decay kinetics of the perhydroxyl radical
    • Behar, D.; Czapski, G.; Rabani, J.; Dorfman, L. M.; Schwarz, H. A. Acid dissociation constant and decay kinetics of the perhydroxyl radical. J. Phys. Chem. 1970, 74, 3209-3213.
    • (1970) J. Phys. Chem , vol.74 , pp. 3209-3213
    • Behar, D.1    Czapski, G.2    Rabani, J.3    Dorfman, L.M.4    Schwarz, H.A.5
  • 29
    • 0348174853 scopus 로고
    • Pulse radiolysis of alkaline solution
    • Rabani, J. Pulse radiolysis of alkaline solution. Adv. Chem. Ser. 1968, 81, 131-152.
    • (1968) Adv. Chem. Ser , vol.81 , pp. 131-152
    • Rabani, J.1
  • 30
    • 0000003171 scopus 로고
    • The pulse radiolysis of deaerated aqueous carbonate solutions. I. Transient optical spectrum and mechanism. 11. pK for OH radicals
    • Weeks, J. L.; Rabani, J. The pulse radiolysis of deaerated aqueous carbonate solutions. I. Transient optical spectrum and mechanism. 11. pK for OH radicals. J. Phys. Chem. 1966, 70, 2100-2106.
    • (1966) J. Phys. Chem , vol.70 , pp. 2100-2106
    • Weeks, J.L.1    Rabani, J.2
  • 31
    • 33947488599 scopus 로고
    • Pulse radiolytic determination of pK for hydroxyl ionic dissociation in water
    • Rabani, J.; Matheson, M. S. Pulse radiolytic determination of pK for hydroxyl ionic dissociation in water. J. Am. Chem. Soc. 1964, 86, 3175.
    • (1964) J. Am. Chem. Soc , vol.86 , pp. 3175
    • Rabani, J.1    Matheson, M.S.2
  • 32
    • 33947333303 scopus 로고
    • Pulse radiolysis of aqueous solutions of potassium ferrocyanide
    • Rabani, J.; Matheson, M.S. Pulse radiolysis of aqueous solutions of potassium ferrocyanide. J. Phys. Chem. 1966, 70, 761-769.
    • (1966) J. Phys. Chem , vol.70 , pp. 761-769
    • Rabani, J.1    Matheson, M.S.2
  • 33
    • 84943702002 scopus 로고
    • The bimolecular decay of the alfa-hydroxymethylperoxyl radicals in aqueous solutions
    • Bothe, E.; Schulte-Frohlinde, D. The bimolecular decay of the alfa-hydroxymethylperoxyl radicals in aqueous solutions. Z. Naturforsch. 1978, 33b, 786-788.
    • (1978) Z. Naturforsch , vol.33 b , pp. 786-788
    • Bothe, E.1    Schulte-Frohlinde, D.2
  • 34
    • 0000526002 scopus 로고
    • Aqueous solubility and reaction kinetics of hydroxymethyl hydroperoxide
    • Zhou, X.; Lee, Y.-N. Aqueous solubility and reaction kinetics of hydroxymethyl hydroperoxide. J. Phys. Chem. 1992, 96, 265-272.
    • (1992) J. Phys. Chem , vol.96 , pp. 265-272
    • Zhou, X.1    Lee, Y.-N.2
  • 35
    • 0347753693 scopus 로고    scopus 로고
    • Geminate recombination of hydroxyl radicals generated in 200 nm photodissociation of aqueous hydrogen peroxide
    • Crowell, R. A.; Lian, R.; Sauer, M. C., Jr.; Oulianov, D. A.; Shkrob, I. A. Geminate recombination of hydroxyl radicals generated in 200 nm photodissociation of aqueous hydrogen peroxide. Chem. Phys. Lett. 2004, 383, 481-485.
    • (2004) Chem. Phys. Lett , vol.383 , pp. 481-485
    • Crowell, R.A.1    Lian, R.2    Sauer Jr., M.C.3    Oulianov, D.A.4    Shkrob, I.A.5
  • 36
    • 0347334744 scopus 로고    scopus 로고
    • The ultraviolet photolysis of aqueous solutions of 1,1,1-trichloroethane and hydrogen peroxide at 222 nm
    • Loraine, G. A.; Glaze, W. H. The ultraviolet photolysis of aqueous solutions of 1,1,1-trichloroethane and hydrogen peroxide at 222 nm. J. Adv. Oxid. Technol. 1999, 4, 424-433.
    • (1999) J. Adv. Oxid. Technol , vol.4 , pp. 424-433
    • Loraine, G.A.1    Glaze, W.H.2
  • 38
    • 0025388369 scopus 로고
    • Use of UV radiation in water treatment: Measurements of photonic flux by hydrogen peroxide actinometry
    • Nicole, I.; De Laat, J.; Dore, M.; Duguet, J. P.; Bonnel, C. Use of UV radiation in water treatment: Measurements of photonic flux by hydrogen peroxide actinometry. Water Res. 1990, 24, 157-168.
    • (1990) Water Res , vol.24 , pp. 157-168
    • Nicole, I.1    De Laat, J.2    Dore, M.3    Duguet, J.P.4    Bonnel, C.5
  • 39
    • 0000044238 scopus 로고    scopus 로고
    • Vacuum-UV (172 nm) actinometry. The quantum yield of the photolysis of water
    • Heit, G.; Neuner, A.; Saugy, P.-Y.; Braun, A. M. Vacuum-UV (172 nm) actinometry. The quantum yield of the photolysis of water. J. Phys. Chem. A 1998, 102, 5551-5561.
    • (1998) J. Phys. Chem. A , vol.102 , pp. 5551-5561
    • Heit, G.1    Neuner, A.2    Saugy, P.-Y.3    Braun, A.M.4
  • 40
    • 19744368682 scopus 로고    scopus 로고
    • 2O-VUV) with a xenon excimer flow-through lamp at 172 nm: Use of methanol as actinometer for VUV intensity measurements and as reference compound for OH-radical competition kinetics in aqueous systems
    • 2O-VUV) with a xenon excimer flow-through lamp at 172 nm: Use of methanol as actinometer for VUV intensity measurements and as reference compound for OH-radical competition kinetics in aqueous systems. J. Adv. Oxid. Technol. 2002, 5, 155-163.
    • (2002) J. Adv. Oxid. Technol , vol.5 , pp. 155-163
    • Oppenlander, T.1    Schwarzwalder, R.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.