Mechanical and thermal properties of polyurethane elastomers synthesized with toluene diisocyanate trimer

Journal of Macromolecular Science, Part B: Physics

Volumn 52, Issue 1, 2013, Pages 138-154

  Yang, Qin ^a   Ye, Lin ^a  

^a SICHUAN UNIVERSITY   (China)

Author keywords

mechanical property; polyurethane elastomer (PUE); TDI trimer; thermal stability

Indexed keywords

DUCTILE FAILURES; ELONGATION AT BREAK; FREQUENCY FACTORS; HIGH-TENSILE STRENGTH; IN-SITU POLYMERIZATION; ISOCYANURATE; MECHANICAL AND THERMAL PROPERTIES; PEAK HEIGHT; POLYURETHANE ELASTOMERS; PRE-POLYMER PROCESS; SOFT SEGMENTS; TDI TRIMER; TOLUENE DIISOCYANATES;

ACTIVATION ENERGY; BRITTLE FRACTURE; ELASTOMERS; MECHANICAL PROPERTIES; PLASTICS; POLYURETHANES; STRESS-STRAIN CURVES; THERMODYNAMIC STABILITY; TOLUENE;

OLIGOMERS;

EID: 84868580402     PISSN: 00222348     EISSN: 1525609X     Source Type: Journal    
DOI: 10.1080/00222348.2012.695631     Document Type: Article

References (17)

1. Chen, K.-S., Chen, Y.-S., Yu, T. L., and, Tsai, C.-L. 2002. Physical properties of tri-isocyanate crosslinked polyurethane. J. Polym. Res, 9: 119
2. Savelyev, Yu.V., Akhranovich, E. R., Grekov, A. P., Privalko, E. G., Korskanov, V. V., Shtompel, V. I., Privalko, V. P., Pissis, P., and, Kanapitsas, A. 1998. Influence of chain extenders and chain end groups on properties of segmented polyurethanes, I. Phase morphology. Polymer, 39: 3425
3. Pichon, P. G., David, L., Mechin, F., and, Sautereau, H. 2010. Morphologies of cross-linked segmented polyurethanes. Evolution during maturation and consequences on elastic properties and thermal compressive fatigue. Macromolecules, 43: 1888
4. Zia, K. M., Bhatti, I. A., Barikani, M., Zuber, M., and, Bhatti, H. N. 2009. XRD studies of polyurethane elastomers based on chitin/1,4-butane diol blends. Carbohyd. Polym, 76: 183
5. Mallakpour, S., and, Rafiemanzelat, F. 2006. Study of the Miscibility of Hard and Soft Segments of Optically Active Poly (amide-imide-ether-urethane) copolymers based-L-Leucine with different soft segments. Polym. Bull, 56: 9
6. Ni, H., Aaserud, D. J., Simonsiek, Jr. W.J., and, Soucek, M. D. 2000. Preparation and characterization of alkoxysilane functionalized isocyanurates. Polymer, 41: 57
7. Kiyotsugu, A., Shin-Ichi, I., and, Hiroshi, O. 2000. Preparation and properties of imide-containing elastic polymers from elastic polyureas and pyromellitic dianhydride. J. Polym. Sci., Part A: Polym. Chem, 38: 715
8. Radhaakrishnan Nair, P., Reghynadhan Nair, C. P., and, Francis, D. J. 1998. Imide-Modified polyurethanes, syntheses, thermal, and mechanical characteristics. J. Appl. Polym. Sci, 70: 1483
9. Ho, T.-H., and, Wang, C.-S. 1996. Modification of epoxy resins with polysiloxane thermoplastic polyurethane for electronic encapsulation: 1. Polymer, 37: 2733
10. Yeganeh, H., Jamshidi, S., and, Talemi, P. H. 2006. Synthesis, characterization and properties of novel thermally stable poly(urethane- oxazolidone) elastomers. Eur. Polym. J, 42: 1743
11. He, X.-Z., and, Wang, Z.-J. 1996. Synthesis of TDI trimer and its application in the two-component polyurethane coatings. Plastic Industry, 26: 19
12. Sun, J., Hao, J. S., Wang, S. J., and, Li, Z. F. 2008. Synthesis of TDI terpolymer and preparation of polyurethane-urea elastomers. Polyurethane Industry, 23: 22
13. Wang, J.-J., and, Shi, T.-J. 2001. Synthesis of thermally stable polyurethane elastomers. China Synthetic Rubber Industry, 24: 347
14. Xia, W.-H., Wang, G.-B., Ha, C.-Y., and, Shen, M.-M. 2002. Synthesis of TDI Trimer. Guangzhou Chemistry, 27: 1
15. Satheesh Kumar, M. N., and, Siddaramaiah. 2007. Thermogravimetric analysis and morphological behavior of castor oil based polyurethane-polyester nonwoven fabric composites. J. Appl. Polym. Sci, 106: 3521
16. Sbirrazzuoli, N., Brunel, D., and, Elegant, L. 1992. Different kinetic equations analysis. J. Thermal Anal, 38: 1509
17. Coats, A. W., and, Redfern, J. P. 1964. Kinetic parameters from thermogravimetric data. Nature, 68: 201