Finite-rate surface chemistry model, I: Formulation and reaction system examples

42nd AIAA Thermophysics Conference

Volumn , Issue , 2011, Pages

  Marschall, Jochen ^a   MaClean, Matthew ^b  

^a SRI INTERNATIONAL   (United States)

^b CUBRC   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION/DESORPTION; ARRHENIUS-FUNCTION; COMPUTATIONAL FLUID DYNAMICS CODES; EQUILIBRIUM THERMODYNAMICS; LANGMUIR-HINSHELWOOD; NUMERICAL IMPLEMENTATION; SURFACE REACTION MECHANISM; THERMODYNAMIC DATA;

CATALYTIC OXIDATION; EQUILIBRIUM CONSTANTS; NASA; SUBLIMATION; SURFACE CHEMISTRY; SURFACE REACTIONS;

COMPUTATIONAL FLUID DYNAMICS;

EID: 84867548567     PISSN: None     EISSN: None     Source Type: Conference Proceeding    
DOI: None     Document Type: Conference Paper

References (39)

1. Rakich, J.V., Stewart, D.A., and Lanfranco, M.J., "Results of a Flight Experiment on the Catalytic Efficiency of the Space Shuttle Heat Shield, " AIAA Paper 82-0944, 1982.
2. Stewart, D.A., Rakich, J.V., and Chen, Y.-K., "Flight Experiment Demonstrating the Effect of Surface Catalysis on the Heating Distribution Over the Space Shuttle Heat Shield, " NASA CP-3248, NASA CP 3248, Williamsburg, VA, 1995.
3. Stewart, D.A., Rakich, J.V., and Lanfranco, M.J., "Catalytic Surface Effects Experiment on the Space Shuttle, " AIAA Paper 81-1143, 1981.
4. Stewart, D.A., Rakich, J.V., and Lanfranco, M.J., "Catalytic Surface Effects on Space Shuttle Thermal Protection System during Earth Entry of Flights STS-2 through STS-5, " NASA CP-2283, Hampton, VA, March 1983.
5. Laux, T., Feigl, M., Stöckle, T., and Auweter-Kurtz, M., "Estimation of the Surface Catalyticity of PVDCoatings by Simultaneous Heat Flux and LIF Measurements in High Enthalpy Air Flows, " AIAA Paper 2000-2364, June 2000
6. Kurotaki, T., "Catalytic Model on SiO2-Based Surface and Application to Real Trajectory, " Journal of Spacecraft and Rockets, Vol. 38, No. 5, 2001, pp. 798-800.
7. Copeland, R.A., Pallix, J.B., and Stewart, D.A., "Surface-Catalyzed Production of NO from Recombination of N and O Atoms, " Journal of Thermophysics and Heat Transfer, Vol. 12, No. 4, 1998, pp. 496-499.
8. Pejakovic, D., Marschall, J., Duan, L., and Martin, M.P., "Nitric Oxide Production from Surface Recombination of Oxygen and Nitrogen Atoms, " Journal of Thermophysics and Heat Transfer, Vol. 22, No. 2, 2008, pp. 178-186.
9. Pejakovic, D., Marschall, J., Duan, L., and Martin, M.P., "Direct Detection of NO Produced by High-Temperature Surface-Catalyzed Atom Recombination, " Journal of Thermophysics and Heat Transfer, Vol. 24, No. 3, 2010, pp. 603-611.
10. Marschall, J., Copeland, R.A., Hwang, H.H., and Wright, M.J., "Surface Catalysis Experiments on Metal Surfaces in Oxygen and Carbon Monoxide Mixtures, " AIAA Paper 2006-181, January 2006.
11. Sepka, S., Chen, Y.-K., Marschall, J., and Copeland, R.A., "Experimental Investigation of Surface Reactions in Carbon Monoxide and Oxygen Mixtures, " Journal of Thermophysics and Heat Transfer, Vol. 14, No. 1, 2000, pp. 45-52.
12. Hollis, B.R., Liechty, D.S., Wright, M.J., Holden, M.S., Wadhams, T.P., and MacLean, M., "Transition Onset and Turbulent Heating Measurements for the Mars Science Laboratory Entry Vehicle, " AIAA Paper 2005-1437, January 2005.
13. Wright, M.J., Olejniczak, J., Brown, J.L., Hornung, H.G., and Edquist, K.L., "Computational Modeling of T5 Laminar and Turbulent Heating Data on Blunt Cones, Part 2: Mars Applications, " AIAA Paper 2005-177, January 2005.
14. Greaves, J.C. and Linnett, J.W., "Recombination of Atoms at Surfaces, Part 6-Recombination of Oxygen Atoms on Silica from 20 °C to 600 °C, " Transactions of the Faraday Society, Vol. 55, 1959, pp. 1355-1361.
15. Balat-Pichelin, M., Badie, J.M., Berjoan, R., and Boubert, P., "Recombination Coefficient of Atomic Oxygen on Ceramic Materials Under Earth Re-Entry Conditions by Optical Emission Spectroscopy, " Chemical Physics, Vol. 291, 2003, pp. 181-194.
16. Marschall, J., "Experimental Determination of Oxygen and Nitrogen Recombination Coefficients at Elevated Temperature Using Laser-Induced Fluorescence, " AIAA Paper 97-3879, August 1997.
17. Marschall, J., "Laboratory Determination of Thermal Protection System Materials Surface Catalytic Properties, " RTO-AVT-VKI Lecture Series 2006: Experiment, Modeling and Simulation of Gas-Surface Interactions for Reactive Flows in Hypersonic Flights, Vol., 2006, pp.
18. Marschall, J., Chamberlain, A., Crunkleton, D., and Rogers, B., "Catalytic Atom Recombination on ZrB2/SiC and HfB2/SiC Ultrahigh-Temperature Ceramic Composites, " Journal of Spacecraft and Rockets, Vol. 41, No. 4, 2004, pp. 576-581.
19. Clark, R.K., Cunnington, J., G. R., and Wiedemann, K.E., "Determination of the Recombination Efficiency of Thermal Control Coatings for Hypersonic Vehicles, " Journal of Spacecraft and Rockets, Vol. 32, No. 1, 1995, pp. 89-96.
20. Stewart, D.A., "Determination of Surface Catalytic Efficiency for Thermal Protection Materials-Room Temperature to Their Upper Use Limit, " AIAA Paper 96-1863, June 1996.
21. Stewart, D.A., "Surface Catalytic Efficiency of Advanced Carbon Carbon Candidate Thermal Protection Materials for SSTO Vehicles, " NASA TM-110383, February 1996.
22. Stewart, D.A., "Surface Catalysis and Characterization of Proposed Candidate TPS for Access-to-Space Vehicles, " NASA TM-112206, July 1997.
23. Stewart, D.A., Chen, Y.-K., Bamford, D.J., and Romanovsky, A.B., "Predicting Material Surface Catalytic Efficiency Using Arc-Jet Tests, " AIAA Paper 1995-2013, June 1995.
24. Enzian, A., Ito, T., Balat-Pichelin, M., Desportes, A., Vervisch, P., Guyon, C., Amouroux, J., Tran, P., Sauvage, N., and Thivet, F., "Post-Flight Analysis of the OREX Catalycity Experiment, " High Technology Plasma Processes, Vol. 9, 2005, pp. 353-361.
25. Wright, M.J., Candler, G.V., and Bose, D., "Data-Parallel Line Relaxation Method for the Navier-Stokes Equations, " AIAA Journal, Vol. 36, No. 9, 1998, pp. 1603-1609.
26. MacLean, M., Marschall, J., and Driver, D.M., "Finite-Rate Surface Chemistry Model, II: Coupling to Viscous Navier-Stokes Code, " AIAA Paper accepted to the 42nd AIAA Thermophysics Conference, June 2011.
27. Lefèvre, L., Belmonte, T., and Michel, H., "Modeling of Nitrogen Atom Recombination on Pyrex: Influence of the Vibrationally Excited N2 Molecules on the Loss Propability of N, " Journal of Applied Physics, Vol. 87, No. 10, 2000, pp. 7497-7507.
28. Guerra, V., "Analytical Model of Heterogeneous Atomic Recombination on Silicalike Surface, " IEEE Transactions On Plasma Science, Vol. 35, No. 5, 2007, pp. 1397-1412.
29. Thömel, J., Lukkien, J.J., and Chazot, O., "A Multiscale Approach for Building a Mechanism Based Catalysis Model for High Enthalpy CO2 Flow, " AIAA Paper 2007-4399, June 2007.
30. Tannehill, J.C., Anderson, D.A., and Pletcher, R.H., Computational Fluid Mechanics and Heat Transfer, 2nd Edition, Taylor & Francis, Washington DC, 1997.
31. Gordon, S. and McBride, B.J., "Computer Program for Calculation of Complex Chemical Equilibrium Compositions and Applications I. Analysis, " NASA RP-1311, NASA Lewis Research Center, Cleveland, Ohio, October 1994.
32. Chen, Y.-K., Henline, W.D., Stewart, D.A., and Candler, G.V., "Navier-Stokes Solutions with Surface Catalysis for Martian Atmospheric Entry, " Journal of Spacecraft and Rockets, Vol. 30, 1993, pp. 32-42.
33. Mitcheltree, R.A. and Gnoffo, P.A., "Wake Flow about the Mars Pathfinder Entry Vehicle, " Journal of Spacecraft and Rockets, Vol. 32, No. 5, 1995, pp. 771-776.
34. Gupta, R.N., Lee, K.P., and Scott, C.D., "Aerothermal Study of Mars Pathfinder Aeroshell " Journal of Spacecraft and Rockets, Vol. 33, No. 1, 1996, pp. 61-69.
35. Bose, D., Wright, M.J., and Palmer, G.E., "Uncertainty Analysis of Laminar Aeroheating Predictions for Mars Entries, " Journal of Thermophysics and Heat Transfer, Vol. 20, No. 4, 1996, pp. 652-662.
36. Kolesnikov, A.F., Pershin, I.S., Vasil'evskii, S.A., and Yakushin, M.I., "Study of Quartz Surface Catalycity in Dissociated Carbon Dioxide Subsonic Flows, " Journal of Spacecraft and Rockets, Vol. 37, No. 5, 2000, pp. 573-579.
37. Rini, P., Garcia, A., Magin, T., and Degrez, G., "Numerical Simulation of Nonequilibrium Stagnation-Line CO2 Flows with Catalyzed Surface Reactions, " Journal of Thermophysics and Heat Transfer, Vol. 18, No. 1, 2004, pp. 114-121.
38. Valentini, P., Schwartzentruber, T.E., and Cozmuta, I., "A Mechanism-Based Finite-Rate Surface Catalysis Model for Simulating Reacting Flows, " AIAA Paper 2009-3935, June 2009
39. Afonina, N.E., Gromov, V.G., and Kovalev, V.L., "Catalysis Modeling for Thermal Protection Systems of Vehicles Entering into Martian Atmosphere, " AIAA Paper 2001-2832, June 2001.