Surface catalysis experiments on metal surfaces in oxygen and carbon monoxide mixtures

Collection of Technical Papers - 44th AIAA Aerospace Sciences Meeting

Volumn 4, Issue , 2006, Pages 2204-2224

  Marschall, Jochen ^a,c,d   Copeland, Richard A ^a,c   Hwang, Helen H ^b,d,e   Wright, Michael J ^b,d,e  

^a SRI INTERNATIONAL   (United States)

^b NASA AMES RESEARCH CENTER   (United States)

^c Molecular Physics Laboratory   (United States)

^d AIAA   (United States)

^e Reacting Flow Environments Branch   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; FLUORESCENCE; OXYGEN; PLATINUM; STAINLESS STEEL; THERMAL EFFECTS;

DIFFUSION TUBE; LASER-INDUCED FLUORESCENCE; ROOM TEMPERATURE; SIDE-ARM REACTOR;

BINARY MIXTURES;

EID: 34250846509     PISSN: None     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.2514/6.2006-181     Document Type: Conference Paper

References (53)

1. Chen, Y.-K., Henline, W.D., Stewart, D.A., and Candler, G.V., "Navier-Stokes Solutions with Surface Catalysis for Martian Atmospheric Entry," Journal of Spacecraft and Rockets, Vol. 30, 1993, pp. 32-42.
2. Sepka, S., Chen, Y.-K., Marschall, J., and Copeland, R.A., "Experimental Investigation of Surface Reactions in Carbon Monoxide and Oxygen Mixtures," Journal of Thermophysics and Heat Transfer, Vol. 14, 2000, pp. 45-52.
3. Wright, M.J., Olejniczak, J., Brown, J.L., Hornung, H.G., and Edquist, K.L., "Computational Modeling of T5 Laminar and Turbulent Heating Data on Blunt Cones, Part 2: Mars Applications," AIAA Paper 2005-177, January 2005.
4. Mollis, B.R., Liechty, D.S., Wright, M.J., Holden, M.S., Wadhams, T.P., and MacLean, M., "Transition Onset and Turbulent Heating Measurements for the Mars Science Laboratory Entry Vehicle," AIAA Paper 2005-1437, January 2005.
5. Bonzel, H.P. and Ku, R., "Mechanisms of the Catalytic Carbon Monoxide Oxidation on Pt(l 10)," Surface Science, Vol. 33, 1972, pp. 91-106.
6. Bonzel, H.P. and Ku, R., "Carbon Monoxide Oxidation on a Pt(l 10) Single Crystal Surface," Journal of Vacuum Science and Technology, Vol. 9, 1972, pp. 663-667.
7. Smith, W.V., "The Surface Recombination of H Atoms and OH Radicals," Journal of Chemical Physics, Vol. 11,1943, pp. 110-125.
8. Marschall, J., "Experimental Determination of Oxygen and Nitrogen Recombination Coefficients at Elevated Temperature Using Laser-Induced Fluorescence," AIAA Paper 97-3879, August 1997.
9. 2/SiC Ultra-High Temperature Ceramic Composites," Journal of Spacecraft and Rockets, Vol. 41, 2004, pp. 576-581.
10. Stewart, D.A., "Determination of Surface Catalytic Efficiency for Thermal Protection Materials - Room Temperature to Their Upper Use Limit," AIAA Paper 96-1863, June 1996.
11. Stewart, D. A., "Surface Catalytic Efficiency of Advanced Carbon Carbon Candidate Thermal Protection Materials for SSTO Vehicles," NASA TM-110383, February 1996.
12. Stewart, D.A., "Surface Catalysis and Characterization of Proposed Candidate TPS for Access-to-Space Vehicles," NASA TM-112206, July 1997.
13. Fiedler, J., Salmain, M., Jaouen, G., and Pospíšil, L., "Purification of Gaseous CO from Fe(CO)5 Traces Formed in Steel Storage Cylinders," Inorganic Chemistry Communications, Vol. 4, 2001, pp. 613-616.
14. Bischel, W.K., Perry, B.E., and Crosley, D.R., "Two-Photon Laser-Induced Fluorescence in Oxygen and Nitrogen Atoms," Chemical Physics Letters, Vol. 82, 1981, pp. 85-88.
15. Bischel, W.K., Perry, B.E., and Crosley, D.R., "Detection of Fluorescence from O and N Atoms Induced by Two-Photon Absorption," Applied Optics, Vol. 21, 1982, pp. 1419-1428.
16. Aldén, M., Wallin, S., and Wendt, W., "Applications of Two-Photon Absorption for Detection of CO in Combustion Gases," Applied Physics B, Vol. 33, 1984, pp. 205-212.
17. + Rydberg States of CO," Journal of Chemical Physics, Vol. 91, 1989, pp. 2041-2048.
18. Pezé, P., Paillous, A., Siffre, J., and Dubreuil, B., "Quantitative Measurements of Oxygen Atom Density using LIF," Journal of Physics D, Vol. 26, 1993, pp. 1622-1629.
19. Wright, M.J., Candler, G.V., and Bose, D., "Data-Parallel Line Relaxation Method for the Navier-Stokes Equations," AIAA Journal, Vol. 36, 1998, pp. 1603-1609.
20. Pallix, J.B. and Copeland, R. A., "Measurement of Catalytic Recombination Coefficients on Quartz Using Laser-Induced Fluorescence," Journal of Thermophysics and Heat Transfer, Vol. 10, 1996, pp. 224-233.
21. Yun, K.S. and Mason, E.A., "Collision Integrals for the Transport Properties of Dissociating Air at High Temperatures," Physics of Fluids, Vol. 5, 1962, pp. 380-386.
22. Marrero, T.R. and Mason, E.A., "Gaseous Diffusion Coefficients," Physical and Chemical Reference Data, Vol. 1, 1972, pp. 3-118.
23. Wilke, C.R., "Diffusional Properties of Multicomponent gases," Chemical Engineering Progress, Vol. 46, 1950, pp. 95-104.
24. Cheatwood, P.M. and Gnoffo, P.A., "User's Manual for the Langley Aerothermodynamic Upwind Relaxation Algorithm (LAURA)," NASA TM-4764, April 1996.
25. Ramshaw, J.D., "Self-Consistent Effective Binary Diffusion in Multicomponent Gas Mixtures," Journal of Non-Equilibrium Thermodynamics, Vol. 15, 1990, pp. 295-300.
26. Gupta, R., Yos, J., Thompson, R., and Lee, K., "A Review of Reaction Rates and Thermodynamic and Transport Properties for an 11-Species Air Model for Chemical and Thermal Nonequilibrium Calculations to 30000 K," NASA RP-1232, August 1990.
27. Wright, M.J., Bose, D., Palmer, G.E., and Levine, E., "Recommended Collision Integrals for Transport Property Computations I: Air Species," AIAA Journal, Vol. 43, 2005, pp. 2558-2564.
28. Riabov, V.V., "Approximate Calculations of Transport Coefficients of Earth and Mars Atmospheric Dissociating Gases," Journal of Thermophysics and Heat Transfer, Vol. 10, 1996, pp. 209-216.
29. Bzowski, J., Kestin, J., Mason, E.A., and Uribe, F.J., "Equilibrium and Transport Properties of Gaseous Mixtures at Low Density," Journal of Physical and Chemical Reference Data, Vol. 19, 1990, pp. 1179-1231.
30. Mitcheltree, R.A. and Gnoffo, P.A., "Wake Flow about the Mars Pathfinder Entry Vehicle," Journal of Spacecraft and Rockets, Vol. 32, 1995, pp. 771-776.
31. Bose, D. and Wright, M., "Uncertainty Analysis of Laminar Aeroheating Predictions for Mars Entries," AIAA Paper 2005-4682, June 2005.
32. Carty, G., Magne, L., and Cernogora, G., "Atomic Oxygen Recombination on Fused Silica: Experimental Evidence of the Surface State Influence," Journal of Physics D: Applied Physics, Vol. 32, 1999, pp. L53-L56.
33. Kim, Y.C. and Boudart, M., "Recombination of O, N, and H Atoms on Silica: Kinetics and Mechanism," Langmuir, Vol. 7, 1991, pp. 2999-3005.
34. Hacker, D.S., Marshall, S.A., and Steinberg, M., "Recombination of Atomic Oxygen on Surfaces," Journal of Chemical Physics, Vol. 35, 1961, pp, 1788-1792.
35. Berkowitz, J., "Catalytic Oxygen Atom Recombination on Solid Surfaces," in The Structure and Chemistry of Solid Surfaces, edited by G. A. Somorjai, (John Wiley & Sons, Inc., New York, 1968), p. 80.81-80.16.
36. Sander, K.M., "Luminescence of Solids Excited by Surface Recombination of Atoms. V. Quantitative Dependence of Luminescence Responce on Oxygen- and Nitrogen-Atom Densities," Journal of Chemical Physics, Vol. 42, 1965, pp. 1240-1243.
37. Greaves, J.C. and Linnett, J.W., "Recombination of Atoms at Surfaces, Part 6 - Recombination of Oxygen Atoms on Silica from 20 °C to 600 °C," Transactions of the Faraday Society, Vol. 55, 1959, pp. 1355-1361.
38. Melin, G.A. and Madix, R.J., "Energy Accomodation During Oxygen Atom Recombination on Metal Surfaces," Transactions of the Faraday Society, Vol. 67, 1971, pp. 198-211.
39. Cauquot, P., Cavadias, S., and Amouroux, J., "Thermal Energy Accommodation from Oxygen Atoms Recombination on Metallic Surfaces," Journal of Thermophysics and Heat Transfer, Vol. 12, 1998, pp. 206-213.
40. Dickens, P.G. and Sutcliffe, M.B., "Recombination of Oxygen Atoms on Oxide Surfaces," Transactions of the Faraday Society, Vol. 60, 1964, pp. 1272-1285.
41. 2.1.0) Atoms by Rare Gases and Small Molecules," Chemical Physics Letters, Vol. 143, 1988, pp. 571-576.
42. +(v′ = 0) Probed by Two-Photon Laser-Induced Fluorescence Using a Picosecond Laser," Journal of Chemical Physics, Vol. 113, 2000, pp. 3046-3054.
43. Settersten, T.B., Dreizler, A., and Farrow, R.L., "Temperature- and Species-Dependent Quenching of CO B Probed by Two-Photon Laser-Induced Fluorescence Using a Picosecond Laser," Journal of Chemical Physics, Vol. 117, 2002, pp. 3173-3179.
44. Masel, R.I., Adsorption and Reaction on Solid Surfaces, John Wiley & Sons, Inc., New York, 1996.
45. Nakai, I., Kondoh, H., Amemiya, K., Nagasaka, M., Shimada, T., Yokota, R., Nambu, A., and Ohta, T., "Mechanism of the CO Oxidation Reaction on O-Precovered Pt(111) Surfaces Studied with Near-Edge X-Ray Absorption Fine Structure Spectroscopy," Journal of Chemical Physics, Vol. 122, 2005, pp. 134709.
46. Wintterlin, J., Völkening, S., Janssens, T.V.W., Zambelli, T., and Ertl, G., "Atomic and Macroscopic Reaction Rates of a Surface-Catalyzed Reaction," Science, Vol. 278, 1997, pp. 1931-1934.
47. Wolf, R.M., Siera, J., van Delft, F., and Nieuwenhuys, B.E., "A Comparative Study of the Behaviour of Single-Crystal Surfaces and Supported Catalysts in NO Reduction and CO Oxidation over Pt-Rh Alloys," Faraday Discussions of the Chemical Society, Vol. 87, 1989, pp. 275-289.
48. Subbotin, A.N., Gudkov, B.S., Dykh, Z.L., and Yakerson, V.I., "Temperature Hysteresis in CO Oxidation on Catalysts of Various Nature," Reaction Kinetics and Catalysis Letters, Vol. 66, 1999, pp. 97-104.
49. 2 Catalysts with Different Pretreatments," Journal of Catalysis, Vol. 233, 2005, pp. 41-50.
50. Hendriksen, B.L.M. and Frenken, J.W.M., "CO Oxidation on Pt(110): Scanning Tunneling Microscopy Inside a High-Pressure Flow Reactor," Physical Review Letters, Vol. 89, 2002, pp. 046101.
51. Slanger, T. and Copeland, R.A., "Energetic Oxygen in the Upper Atmosphere and the Laboratory," Chemical Reviews, Vol. 103, 2003, pp. 4731-4765.
52. g)," Journal of Chemical Physics, Vol. 91, 1989, pp. 7947-7950.
53. 2," Physical Review Letters, Vol. 90, 2003, pp. 086403.