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Volumn 13, Issue 15, 2012, Pages 3542-3548

Hyperfine coupling constants of β-phosphorylated nitroxides: A tool to probe the cybotactic effect by electron paramagnetic resonance

Author keywords

EPR spectroscopy; magnetic properties; nitroxides; radicals; solvent effects

Indexed keywords

ELECTRON RESONANCE; ELECTRON SPIN RESONANCE SPECTROSCOPY; FLUORINE; HYDROGEN; HYDROGEN BONDS; ISOMERS; MAGNETIC PROPERTIES; NITROGEN OXIDES; PARAMAGNETISM; PHOSPHORUS; SOLVENTS;

EID: 84867497558     PISSN: 14394235     EISSN: 14397641     Source Type: Journal    
DOI: 10.1002/cphc.201200420     Document Type: Article
Times cited : (15)

References (41)
  • 4
    • 80052829953 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2011, 50, 9108-9111.
    • (2011) Angew. Chem. Int. Ed. , vol.50 , pp. 9108-9111
  • 7
    • 70349915866 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2009, 48, 3060-3064.
    • (2009) Angew. Chem. Int. Ed. , vol.48 , pp. 3060-3064
  • 14
    • 84875076248 scopus 로고    scopus 로고
    • As quoted by Reichardt (ref. [13]): "A cybotactic region may be defined as the volume around a solute molecule in which the ordering of the solvent molecules has been influenced by the solute, including both the first solvation shell and the transition region." See ref. [14]
    • As quoted by Reichardt (ref. [13]): "A cybotactic region may be defined as the volume around a solute molecule in which the ordering of the solvent molecules has been influenced by the solute, including both the first solvation shell and the transition region." See ref. [14].
  • 29
    • 84875061796 scopus 로고    scopus 로고
    • P,β dropped from 45.9 G in methylcyclopentane to 18.8 G in MeOH
    • P,β dropped from 45.9 G in methylcyclopentane to 18.8 G in MeOH.
  • 31
    • 84875065894 scopus 로고    scopus 로고
    • N, as expected
    • N, as expected.
  • 32
    • 84875064304 scopus 로고    scopus 로고
    • 2=0.977, N=10
    • 2=0.977, N=10.
  • 38
    • 84875065677 scopus 로고    scopus 로고
    • Errors are on average ±0.06 for all hyperfine coupling constants and are of the size of the symbols in Figure 4
    • Errors are on average ±0.06 for all hyperfine coupling constants and are of the size of the symbols in Figure 4.
  • 39
    • 84875060207 scopus 로고    scopus 로고
    • Misreported data cannot be discarded
    • Misreported data cannot be discarded.
  • 40
    • 84875065320 scopus 로고    scopus 로고
    • 4 and EG were not recorded for 5 and 4, respectively
    • 4 and EG were not recorded for 5 and 4, respectively.
  • 41
    • 84875080060 scopus 로고    scopus 로고
    • Cohesive pressure of 25 (TEG) is not available
    • Cohesive pressure of 25 (TEG) is not available.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.