Does acetone react with HO2 in the upper-troposphere?

Atmospheric Chemistry and Physics

Volumn 12, Issue 3, 2012, Pages 1339-1351

  Dillon, T J ^a   Pozzer, A ^a,b,c   Vereecken, L ^a   Crowley, J N ^a   Lelieveld, J ^a,b,d  

^a MAX PLANCK INSTITUTE FOR CHEMISTRY   (Germany)

^b CYPRUS INSTITUTE   (Cyprus)

^c ABDUS SALAM INTERNATIONAL CENTRE FOR THEORETICAL PHYSICS   (Italy)

^d KING SAUD UNIVERSITY   (Saudi Arabia)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ACETONE; ATMOSPHERIC CHEMISTRY; ATMOSPHERIC MODELING; THREE-DIMENSIONAL MODELING; TROPOPAUSE; TROPOSPHERE;

EID: 84867371887     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-12-1339-2012     Document Type: Article

References (45)

1. Aloisio, S. and Francisco, J. S.: Complexes of Hydroxyl and Hy-droperoxyl Radical with Formaldehyde, Acetaldehyde, and Acetone, J. Phys. Chem. A, 104, 3211-3224, 2000.
2. Arnold, F., Knop, G., and Ziereis, H.: Acetone measurements in the upper troposphere and lower stratosphere - implications for hydroxyl radical abundances, Nature, 321, 505-507, 1986. (Pubitemid 17279480)
3. Arnold, S. R., and Chipperfield., M. P., and Blitz, M.A.: A three-dimensional model study of the effect of new temperature-dependent quantum yields for acetone photolysis, J. Geophys. Res.-Atmos., 110, D22305 doi:10.1029/2005JD005998, 2005. (Pubitemid 43051324)
4. Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605-4638, 2003.
5. x species, Atmos. Chem. Phys., 4, 1461-1738, doi:10.5194/acp-4-1461-2004, 2004. (Pubitemid 39342128)
6. Atkinson, R., and Baulch., D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II - gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625-4055, doi:10.5194/acp-6-3625-2006, 2006. (Pubitemid 44369557)
7. 2 radicals with aldehydes and ketones, Int. J. Chem. Kinet., 33, 509-512, 2001. (Pubitemid 32820013)
8. Blitz, M. A., and Heard., D. E., Pilling, M. J., Arnold, S. R., and Chipperfield, M.P.: Pressure and temperature-dependent quantum yields for the photodissociation of acetone between 279 and 327.5 nm, Geophys. Res. Lett., 31, L06111, doi:10.1029/2003GL018793, 2004
9. 2 Reaction, J. Phys. Chem. A., 115, 1069-1085, 2011.
10. 3OH Complex: Thermodynamics and Kinetics of Formation, J. Phys. Chem. A 110, 6948-6959, 2006. (Pubitemid 43953072)
11. 2 radical with acetone, Int. J. Quantum Chem., 107, 1344-1354, 2007. (Pubitemid 46480204)
12. Curtis, A. R. and Sweetenham, W. P.: Facsimile, AERE, Report (R-12)805, 1987.
13. 2 and other substituted peroxy radicals, Atmos. Chem. Phys., 8, 4877-4889, doi:10.5194/acp-8-4877-2008, 2008.
14. Dillon, T. J., Hölscher, D., Sivakumaran, V., Horowitz, A., and Crowley, J.N.: Kinetics of the reactions of HO with methanol (210-351 K) and with ethanol (216-368 K), Phys. Chem. Chem. Phys., 7, 349-355, 2005.
15. 3): rate coefficients and mechanism, Phys. Chem. Chem. Phys., 8, 236-246, 2006.
16. Fry, J. L., and Nizkorodov., S. A., Okumura, M., Roehl, C. M., and Francisco., J. S., and Wennberg, P. O,: Cis-cis and trans-perp HOONO: Action spectroscopy and isomerization kinetics, J. Chem. Phys., 121, 1432-1448, 2004.
17. 2 Using Infrared Kinetic Spectroscopy, J. Phys. Chem. A, 115, 10527-10538, 2011.
18. 2 radical react with ketones?, Int. J. Chem. Kinet., 32, 573-580, 2000.
19. Gierczak, T., and Burkholder., J. B., Bauerle, S., and Ravishankara, A.R.: Photochemistry of acetone under tropospheric conditions, Chem. Phys., 231, 229-244, 1998.
20. Gierczak, T., and Gilles., M. K., Bauerle, S., and Ravishankara, A.R.: Reaction of hydroxyl radical with acetone. 1. Kinetics of the reactions of OH, OD, and (OH)-O-18 with acetone and acetone-D(6), J. Phys. Chem. A, 107, 5014-5020, 2003.
21. 2) radicals, J. Phys. Chem. A, 108, 5979-5989, 2004.
22. 2-initiated oxidation as an efficient acetone sink, J. Am. Chem. Soc., 126, 9908-9909, 2004. (Pubitemid 39079396)
23. 2-initiated oxidation of ketones/aldehydes near the tropopause, J. Phys. Chem. A, 109, 4303-4311, 2005. (Pubitemid 40751100)
24. Hoell, J. M., and Davis., D. D., Jacob, D. J., Rodgers, M. O., and Newell., R. E., Fuelberg, H. E., McNeal, R. J., and Raper., J. L., and Bendura, R.J.: Pacific Exploratory Mission in the tropical Pacific: PEM-Tropics A, August-September 1996, J. Geophys. Res.-Atmos., 104, 5567-5583, 1999. (Pubitemid 29348053)
25. IUPAC Subcommittee for gas kinetic data evaluation (Ammann, M., Atkinson, R., Cox, R.A., Crowley, J.N., Hynes, R. G., Jenkin, M.E., Mellouki, W., Rossi, M. J., Troe, J., and Wallington, T. J.): Evaluated kinetic data: http://www.iupac-kinetic.ch.cam.ac.uk/, 2011.
26. Jacob, D. J., and Field., B. D., Jin, E. M., Bey, I., Li, Q., and Logan., J. A., Yantosca, R. M., and Singh, H.B.: Atmospheric budget of acetone, J. Geophys. Res., 107, 4100, doi:10.1029/2001JD000694, 2002.
27. 2 reaction in the gas phase, Phys. Chem. Chem. Phys., 10, 4274-4280, 2008.
28. Jeuken, A., Siegmund, P., Heijboer, L., Feichter, J., and Bengtsson, L.: On the potential assimilating meteorological analyses in a global model for the purpose of model validation, J. Geophys. Res., 101, 16939-16950, 1996
29. Jöckel, P., Sander, R., Kerkweg, A., Tost, H., and Lelieveld, J.: Technical Note: The Modular Earth Submodel System (MESSy) - a new approach towards Earth System Modeling, Atmos. Chem. Phys., 5, 433-444, doi:10.5194/acp-5-433-2005, 2005. (Pubitemid 40405294)
30. Jöckel, P., Tost, H., Pozzer, A., Brühl, C., Buchholz, J., Ganzeveld, L., Hoor, P., Kerkweg, A., and Lawrence., M. G., Sander, R., Steil, B., Stiller, G., Tanarhte, M., Taraborrelli, D., van Aardenne, J., and Lelieveld, J.: The atmospheric chemistry general circulation model ECHAM5/MESSy1: consistent simulation of ozone from the surface to the mesosphere, Atmos. Chem. Phys., 6, 5067-5104, doi:10.5194/acp-6-5067-2006, 2006. (Pubitemid 44717487)
31. Lelieveld, J., Brühl, C., Jöckel, P., Steil, B., and Crutzen., P. J., Fischer, H., Giorgetta, M. A., Hoor, P., and Lawrence., M. G., Sausen, R., and Tost, H.: Stratospheric dryness: model simulations and satellite observations, Atmos. Chem. Phys., 7, 1313-1332, doi:10.5194/acp-7-1313-2007, 2007. (Pubitemid 46353432)
32. Maricq, M. M. and Szente, J. J.: The UV spectrum of acetyl and the kinetics of the chain reaction between acetaldehyde and chlorine, Chem. Phys. Lett., 253, 333-339, 1996. (Pubitemid 126162859)
33. McKeen, S. A., Gierzak, T., Burkholder, J. B., and Wennberg., P. O., Hanisco, T. F., Keim, E. R., Gao, R.-S., and Liu., S. C., Ravishankara, A. R., and Fahey, D.W.: The photochemistry of acetone in the upper troposphere: A source of odd-hydrogen radicals, Geophys. Res. Lett., 24, 3177-3180, 1997.
34. 2CO from 215 K to 300 K, J. Phys. Chem., 92, 4030-4032, 1988.
35. Orlando, J. J., and Tyndall., G. S., Vereecken, L., and Peeters, J.: The Atmospheric Chemistry of the Acetonoxy Radical, J. Phys. Chem. A, 104, 11578-11588, 2000. (Pubitemid 32036063)
36. Paulot, F., Wunch, D., Crounse, J. D., and Toon., G. C., Millet, D. B., DeCarlo, P. F., Vigouroux, C., and Deutscher., N. M., González Abad, G., Notholt, J., Warneke, T., Hannigan, J. W., Warneke, C., de Gouw, J. A., Dunlea, E. J., De Mazière, M., Griffith, D. W. T., Bernath, P., Jimenez, J. L., and Wennberg, P. O.: Importance of secondary sources in the atmospheric budgets of formic and acetic acids, Atmos. Chem. Phys., 11, 1989-2013, doi:10.5194/acp-11-1989-2011, 2011.
37. Pozzer, A., Jöckel, P., Tost, H., Sander, R., Ganzeveld, L., Kerkweg, A., and Lelieveld, J.: Simulating organic species with the global atmospheric chemistry general circulation model ECHAM5/MESSy1: a comparison of model results with observations, Atmos. Chem. Phys., 7, 2527-2550, doi:10.5194/acp-7-2527-2007, 2007. (Pubitemid 46753010)
38. Sander, R., Kerkweg, A., Jöckel, P., and Lelieveld, J.: Technical note: The new comprehensive atmospheric chemistry module MECCA, Atmos. Chem. Phys., 5, 445-450, doi:10.5194/acp-5-445-2005, 2005. (Pubitemid 40405295)
39. Singh, H. B., Kanakidou, M., Crutzen, P. J., and Jacob, D.J.: High concentrations and photochemical fate of oxygenated hydrocarbons in the global troposphere, Nature, 378, 50-54, 1995. (Pubitemid 26442085)
40. Talukdar, R. K., Gierczak, T., McCabe, D. C., and Ravishankara, A.R.: Reaction of Hydroxyl Radical with Acetone. 2. Products and Reaction Mechanism, J. Phys. Chem. A, 107, 5021-5032, 2003.
41. 2, and H atoms, Ann. Acad. Sci. Fenn. Ser. A2, 218, 5-45, 1988.
42. 2 in the gas phase, J. Phys. Chem. A, 105, 3505-3514, 2001.
43. Veyret, B., Lesclaux, R., Rayez, M.-T., Rayez, J.-C., and Cox., R. A., and Moortgat, G.K.: Kinetics and mechanism of the photooxidation of formaldehyde. 1. Flash photolysis study, J. Phys. Chem., 93, 2368-2374, 1989.
44. 3 in the upper troposphere, Science, 279, 49-53, 1998. (Pubitemid 28079149)
45. Wollenhaupt, M., and Carl., S. A., Horowitz, A., and Crowley, J.N.: Rate coefficients for reaction of OH with acetone between 202 and 395 K, J. Phys. Chem., 104, 2695-2705, 2000.