A product yield study of the reaction of HO 2 radicals with ethyl peroxy (C 2H 5O 2), acetyl peroxy (CH 3C(O)O 2), and acetonyl peroxy (CH 3C(O)CH 2O 2) radicals

Journal of Physical Chemistry A

Volumn 108, Issue 28, 2004, Pages 5979-5989

  Hasson, Alam S ^a   Tyndall, Geoffrey S ^b   Orlando, John J ^b  

^a CALIFORNIA STATE UNIVERSITY   (United States)

^b NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FLURESCENCE DETECTION; FOG DROPLETS; HYDROPEROXIDES; ORGANIC POLLUTANTS;

COMPUTER SIMULATION; INFRARED SPECTROSCOPY; LIQUID CHROMATOGRAPHY; OXIDATION; OZONE; RADIAL FLOW; REACTION KINETICS; THERMODYNAMICS; TOXICITY; ULTRAVIOLET SPECTROSCOPY;

AROMATIC COMPOUNDS;

EID: 3242875153     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp048873t     Document Type: Article

References (34)

1. Finlayson-Pitts, B. J.; Pitts, J. N. Chemistry of the Upper and Lower Atmosphere; Academic Press: San Diego, CA, 2000.
2. Atkinson, R. Gas-Phase Tropospheric Chemistry of Volatile Organic Compounds: 1. Alkanes and Alkenes. J. Phys. Chem. Ref. Data 1997, 26(2), 215.
3. 2 in Air at 295 K: A Product Study. Chem. Phys. Lett. 1990, 167, 513-518.
4. 2 in Air at 295 K. Chem. Phys. Lett. 1990, 166, 495-499.
5. 2 Reactions between 600 and 719 K: Unimolecular Decomposition of Methylhydro-peroxide. J. Chem. Soc,. Faraday Trans. 1991, 87, 3213-3220.
6. 2 over the Pressure Range 15-700 Torr at 295 K. J. Chem. Soc., Faraday Trans. 1991, 87, 2379-2382.
7. 2 Reaction in 760 Torr of Air at 284-312 K. Chem. Phys. Lett. 2000, 321, 57-61.
8. 2 Reaction. Int. J. Chem. Kinet. 2001, 33(6), 363-376.
9. Jackson, A. V.; Hewitt, C. N. Atmospheric hydrogen peroxide and organic hydroperoxides: a review. Crit. Rev. Env. Sci. Tech. 1999, 29, 175-228.
10. Sander, R. Compilation of Henry's Law Constants for Inorganic and Organic Species of Potential Importance in Environmental Chemistry, Version 3. http://www.mpch-mainz.mpg.de/~sander/res/henry.html (accessed 1999).
11. Friedlander, S. K.; Yeh, E. K. The Submicron Atmospheric Aerosol as a Carrier of Reactive Chemical Species: Case of Peroxides. Appl. Occup. Environ. Hyg. 1998, 13(6), 416.
12. Hasson, A. S.; Paulson, S. E. An Investigation of the Relationship between Gas-phase and Aerosol-borne Hydroperoxides in Urban Air. J. Aerosol Sci. 2003, 34, 459-468.
13. Niki, H.; Maker, P. D.; Savage, C. M.; Breitenbach, L. P. FTIR Study of the Kinetics and Mechanism for Cl-Atom-Initiated Reactions of Acetaldehyde. J. Phys. Chem. 1985, 89, 588-591.
14. 2 in the Temperature Range 253-368 K. Chem. Phys. Lett. 1989, 160, 443-447.
15. 2 between 263 and 333 K. J. Chem. Soc., Faraday Trans. 1992, 88, 3305-3312.
16. 2 Reaction. J. Phys. Chem. A 1999, 103, 365-378.
17. 2 in the Gas Phase. J. Phys. Chem. A 2001, 105, 3505-3514.
18. Orlando, J. J.; Tyndall, G. S.; Vereecken, L.; Peeters, J. The Atmospheric Chemistry of the Acetonoxy Radical. J. Phys. Chem. A 2000, 104, 11578-11588.
19. Tyndall, G. S.; Cox, R. A.; Granier, C.; Lesclaux, R.; Moortgat, G. K.; Pilling, M. J.; Ravishankara, A. R.; Wallington, T. J. Atmospheric Chemistry of Small Peroxy Radicals. J. Geophys. Res. D 2001, 106, 12157-12182.
20. 2 Reaction. Chem. Phys. Lett. 2003, 381, 14-21.
21. Miller, C. E.; Lynton, J. I.; Keevil, D. M.; Francisco, J. S. Dissociation Pathways of Peroxyacetyl Nitrate (PAN). J. Phys. Chem. A 1999, 103, 11451-11459.
22. 2. Chem. Phys. Lett. 1993, 211, 41-47.
23. 2. Chem. Phys. Lett. 1994, 218, 34-42.
24. 2. Chem. Phys. Lett. 1996, 251, 164-173.
25. Shetter, R. E.; Davidson, J. A.; Cantrell, C. A.; Calvert, J. G. Rev. Sci. Instrum. 1987, 58, 1427.
26. Hasson, A. S.; Orzechowska, G. E.; Paulson, S. E. Production of Stabilized Criegee Intermediates and Peroxides in the Gas-Phase Ozonolysis of Alkenes: 1. Ethene, Trans-2-Butene and 2,3-Dimethyl-2-Butene. J. Geophs. Res. 2001, 106(D24), 34131-34142.
27. Hasson, A. S.; Ho, A.; Kuwata, K. T.; Paulson, S. E. Production of Stabilized Criegee Intermediates and Peroxides in the Gas-Phase Ozonolysis of Alkenes: 2. Asymmetric and Biogenic Alkenes. J. Geophys. Res. 2001, 106 (D24), 34143.
28. Hartkamp, H.; P. Bachhausen. A Method for the Determination of Hydrogen Peroxide in Air. Atmos. Environ. 1987, 27(10), 2207-2213.
29. 2 Radicals. J. Phys. Chem. 1982, 86, 3825-3829.
30. 2 Radicals in Air at 295 K. Int. J. Chem. Kinet. 1989, 21, 1077-1089.
31. DeMore, W. B.; Sander, S. P.; Golden, D. M.; Hampson, R. F.; Kurylo, M. J.; Howard, C. J.; Ravishankara, A. R.; Kolb, C. E.; Molina, M. J. Chemical Kinetics and Photochemical Data for use in Stratospheric Modeling: Evaluation No. 11, Jet Propulsion Laboratory Publication 97-4, 1997.
32. Braun, W.; Herron, J. T.; Kahaner, D. K. Int. J. Chem. Kinet. 1988, 20, 51.
33. Bridier, I.; Veyret, B.; Lesclaux, R.; Jenkin, M. E. Flash Photolysis Study of the UV Spectrum and Kinetics of Reactions of the Acetonylperoxy Radical. J. Chem. Soc., Faraday Trans. 1993, 89, 2993-2997.
34. Ozone Isopleth Plotting Program Research Version; Environmental Protection Agency.