Elucidation of the mechanism of surface-initiated atom transfer radical polymerization from a diazonium-based initiator layer

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 50, Issue 21, 2012, Pages 4465-4475

  Chernyy, Sergey ^a   Iruthayaraj, Joseph ^a   Ceccato, Marcel ^a   Hinge, Mogens ^a   Pedersen, Steen Uttrup ^a   Daasbjerg, Kim ^a  

^a AARHUS UNIVERSITY   (Denmark)

Author keywords

aryldiazonium salt; electrografting; inner sphere electron transfer; multilayer initiator; poly(methyl methacrylate); polymer brushes of different graft densities; precursor complex; quartz crystal microbalance with dissipation monitoring; surface initiated atom transfer radical polymerization; X ray photoelectron spectroscopy

Indexed keywords

ARYLDIAZONIUM SALTS; ELECTROGRAFTING; GRAFT DENSITY; INNER-SPHERE ELECTRON; PRECURSOR COMPLEXES; QUARTZ CRYSTAL MICROBALANCE WITH DISSIPATION MONITORING; SURFACE-INITIATED ATOM TRANSFER RADICAL POLYMERIZATIONS;

ACRYLIC MONOMERS; ATOM TRANSFER RADICAL POLYMERIZATION; BROMINE; BROMINE COMPOUNDS; ESTERS; ETHANOL; FILM PREPARATION; MONOLAYERS; MULTILAYERS; PHOTOELECTRONS; X RAY PHOTOELECTRON SPECTROSCOPY;

POLYMERIZATION;

EID: 84867054022     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.26253     Document Type: Article

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