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Volumn 64, Issue 4, 2001, Pages 18-

Time-resolved photoelectron angular distributions as a probe of coupled polyatomic dynamics

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EID: 84866857326     PISSN: 10502947     EISSN: 10941622     Source Type: Journal    
DOI: 10.1103/PhysRevA.64.042504     Document Type: Article
Times cited : (3)

References (73)
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    • J. Manz, L. Wöste, Weinheim, Basel
    • Femtosecond Chemistry, edited by J. Manz and L. Wöste (Weinheim, Basel, 1995).
    • (1995) Femtosecond Chemistry
  • 6
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    • C. C. Hayden and A. Stolow, in Photoionization and Photodetachment, edited by C.-Y. Ng, Advanced Series in Physical Chemistry Vol. 10A (World Scientific, Singapore, 1999), and references therein
    • C. C. Hayden and A. Stolow, in Photoionization and Photodetachment, edited by C.-Y. Ng, Advanced Series in Physical Chemistry Vol. 10A (World Scientific, Singapore, 1999), and references therein.
  • 15
    • 85037223744 scopus 로고    scopus 로고
    • Ch. Meier and V. Engel, in Femtosecond Chemistry (Ref. 2), p. 369
    • Ch. Meier and V. Engel, in Femtosecond Chemistry (Ref. 2), p. 369.
  • 27
    • 85037224474 scopus 로고    scopus 로고
    • For a review of the theory of time-resolved PADs, see T. Seideman, Annu. Rev. Phys. Chem. (to be published)
    • For a review of the theory of time-resolved PADs, see T. Seideman, Annu. Rev. Phys. Chem. (to be published).
  • 38
    • 85037255824 scopus 로고    scopus 로고
    • A. Stolow (private communications);A. Sanov (private communications).
    • Stolow, A.1    Sanov, A.2
  • 39
    • 0001065356 scopus 로고
    • (b) B. R. Henry and W. Siebrand, in Molecular Luminescence, edited by E. C. Lim (Benjamin, New York, 1969) p. 423;, (c) E. C. Lim, in Molecular Luminescence [Ref. 32(b)], p. 469;, (d)M. A. El-Sayed, in Molecular Luminescence [Ref. 32(b)], p. 715;, (e) K. F. Freed, in Radiationless Processes in Molecules and Condensed Phases, edited by F. K. Fong (Springer, Berlin, 1976), p. 23
    • Several of the historical reviews about nonradiative transitions are given in: (a) J. Jortner, S. A. Rice, and R. M. Hochstrasser, Adv. Photochem. 7, 149 (1969);(b) B. R. Henry and W. Siebrand, in Molecular Luminescence, edited by E. C. Lim (Benjamin, New York, 1969) p. 423;(c) E. C. Lim, in Molecular Luminescence [Ref. 32(b)], p. 469;(d)M. A. El-Sayed, in Molecular Luminescence [Ref. 32(b)], p. 715;(e) K. F. Freed, in Radiationless Processes in Molecules and Condensed Phases, edited by F. K. Fong (Springer, Berlin, 1976), p. 23.
    • (1969) Adv. Photochem. , vol.7 , pp. 149
    • Jortner, J.1    Rice, S.A.2    Hochstrasser, R.M.3
  • 40
    • 85037249134 scopus 로고    scopus 로고
    • As stated in [Ref. 32(a)], “all photochemical reactions depend, in some step of the mechanism, on the existence of one or more radiationless processes
    • As stated in [Ref. 32(a)], “all photochemical reactions depend, in some step of the mechanism, on the existence of one or more radiationless processes.”
  • 45
    • 0002675364 scopus 로고    scopus 로고
    • A related ongoing experiment is described by M. J. J. Vrakking, Faraday Discuss. 115, 90 (2000).
    • (2000) Faraday Discuss. , vol.115 , pp. 90
    • Vrakking, M.J.J.1
  • 49
    • 85037209875 scopus 로고    scopus 로고
    • By “rigid” one refers to molecules for which tunneling between equivalent equilibrium conformations does not take place on the time scale of the experiment, see Ref. 44 p. 5,6. It is important to note that this definition of a rigid molecule allows nonzero vibration amplitude and centrifugal distortion. We note also that molecules may well behave as rigid on the time-scale of a short pulse pump-probe experiment even if analysis of a CW spectrum requires that large amplitude motion be taken into account
    • By “rigid” one refers to molecules for which tunneling between equivalent equilibrium conformations does not take place on the time scale of the experiment, see Ref. 44 p. 5,6. It is important to note that this definition of a rigid molecule allows nonzero vibration amplitude and centrifugal distortion. We note also that molecules may well behave as rigid on the time-scale of a short pulse pump-probe experiment even if analysis of a CW spectrum requires that large amplitude motion be taken into account.
  • 50
    • 85037223941 scopus 로고    scopus 로고
    • We distinguish between the subscript (Formula presented), which labels the energy levels and magnetic states of the initial electronic state, and the subscript i, which labels the energy level and magnetic state of the initial rovibrational level, since a nonperturbative field excites in general a wave packet of (Formula presented) and (Formula presented) levels
    • We distinguish between the subscript (Formula presented), which labels the energy levels and magnetic states of the initial electronic state, and the subscript i, which labels the energy level and magnetic state of the initial rovibrational level, since a nonperturbative field excites in general a wave packet of (Formula presented) and (Formula presented) levels.
  • 58
    • 85037182022 scopus 로고    scopus 로고
    • It is more precise to consider the molecular point group as the group of vibronic symmetry operations of a rigid molecule, whereas the symmetry group of the full molecular Hamiltonian is referred to as the “molecular symmetry group” in Ref. 55. Thus, the operations of the molecular point group do not transform the Euler angles. In the case of rigid 42 nonlinear molecules considered here the molecular symmetry group is isomorphic to the molecular point group and hence we prefer the standard usage of “point group” for the “molecular symmetry group
    • It is more precise to consider the molecular point group as the group of vibronic symmetry operations of a rigid molecule, whereas the symmetry group of the full molecular Hamiltonian is referred to as the “molecular symmetry group” in Ref. 55. Thus, the operations of the molecular point group do not transform the Euler angles. In the case of rigid 42 nonlinear molecules considered here the molecular symmetry group is isomorphic to the molecular point group and hence we prefer the standard usage of “point group” for the “molecular symmetry group.”
  • 67
    • 0003851731 scopus 로고
    • M. Abramowitz, I. A. Stegun, National Bureau of Standards, Washington D.C
    • M. Abramowitz, in Handbook of Mathematical Functions, edited by M. Abramowitz and I. A. Stegun, Applied Math Series 55 (National Bureau of Standards, Washington D.C., 1972).
    • (1972) Handbook of Mathematical Functions
    • Abramowitz, M.1
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    • See, for instance, H. Petek, J. Chem. Phys. 102, 4726 (1994).
    • (1994) J. Chem. Phys. , vol.102 , pp. 4726
    • Petek, H.1


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