Predictions of rotation-vibration effects in time-resolved photoelectron angular distributions

Journal of Chemical Physics

Volumn 113, Issue 18, 2000, Pages 7901-7910

  Althorpe, Stuart C ^a   Seideman, Tamar ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

IONIZATION; MOLECULAR VIBRATIONS; ULTRAFAST PHENOMENA;

TIME-RESOLVED PHOTOELECTRON ANGULAR DISTRIBUTIONS;

MOLECULAR PHYSICS;

EID: 0034323826     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1315356     Document Type: Article

References (37)

1. A. H. Zewail, Femtochemistry: Ultrafast Dynamics of the Chemical Bond (World Scientific, Singapore, 1994); in Femtosecond Chemistry, edited by J. Manz, and L. Wöste (Weinheim, Basel, 1995); D. Zhong and A. H. Zewail, J. Phys. Chem. A 102, 4031 (1998).
2. A. H. Zewail, Femtochemistry: Ultrafast Dynamics of the Chemical Bond (World Scientific, Singapore, 1994); in Femtosecond Chemistry, edited by J. Manz, and L. Wöste (Weinheim, Basel, 1995); D. Zhong and A. H. Zewail, J. Phys. Chem. A 102, 4031 (1998).
3. A. H. Zewail, Femtochemistry: Ultrafast Dynamics of the Chemical Bond (World Scientific, Singapore, 1994); in Femtosecond Chemistry, edited by J. Manz, and L. Wöste (Weinheim, Basel, 1995); D. Zhong and A. H. Zewail, J. Phys. Chem. A 102, 4031 (1998).
4. P. M. Felker, J. Phys. Chem. 96, 7844 (1992).
5. G. M. Nathanson and G. M. McClelland, J. Chem. Phys. 81, 629 (1984); Chem. Phys. Lett. 114, 441 (1985).
6. G. M. Nathanson and G. M. McClelland, J. Chem. Phys. 81, 629 (1984); Chem. Phys. Lett. 114, 441 (1985).
7. T. Noguchi, S. Sato, and Y. Fujimura, Chem. Phys. Lett. 155, 177 (1989).
8. K. L. Reid, Chem. Phys. Lett. 215, 25 (1993).
9. K. L. Reid, S. P. Duxon, and M. Towne, Chem. Phys. Lett. 228, 351 (1994).
10. T. Seideman, J. Chem. Phys. 107, 7859 (1997).
11. K. L. Reid, T. A. Field, M. Towrie, and P. Matousek, J. Chem. Phys. 111, 1438 (1999).
12. T. Seideman and S. C. Althorpe, J. Electron. Spectrosc. Relat. Phenom. 108, 99 (2000).
13. T. Seideman, J. Chem. Phys. 103, 7887 (1995).
14. S. C. Althorpe and T. Seideman, J. Chem. Phys. 110, 147 (1999).
15. T. Seideman, Phys. Rev. Lett. 83, 4971 (1999).
16. Y. Arasaki et al., Chem. Phys. Lett. 302, 363 (1999).
17. T. Seidemann, J. Chem. Phys. 113, 1677 (2000).
18. T. Seideman (unpublished).
19. (a) T. Baumert, R. Thalweiser, and G. Gerber, Chem. Phys. Lett. 209, 29 (1993).
20. (b) For a review, see, for instance, T. Baumert, J. Helbing, and G. Gerber, Adv. Chem. Phys. 101, 47 (1997).
21. (a) I. Fischer, D. M. Villeneuve, M. J. J. Vrakking, and A. Stolow, J. Chem. Phys. 102, 5566 (1995).
22. (b) For a review, see. for instance, C. C. Hayden and A. Stolow, in Advanced Series in Physical Chemistry, Vol. 10: Photoionization and Photodetachment, edited by C.-Y. Ng (World Scientific, Singapore. 2000), p. 31.
23. L. Wang, H. Kohguchi, and T. Suzuki, Faraday Discuss. 113, 37 (1999).
24. Femtosecond photoelectron-photoion coincidence experiments were reported by J. A. Davies, J. E. LeClaire, R. E. Continetti, and C. C. Hayden, J. Chem. Phys. 111, 1 (1999).
25. M. R. Aliev and J. K. G. Watson, in Molecular Spectroscopy: Modern Research, Vol. III, pp. 1-67, edited by K. Narahari Rao (Academic, Orlando. Florida, 1985).
26. By "RV interaction" we refer to both Coriolis coupling (cross terms of the angular momenta of rotation and vibration) and centrifugal coupling (vibrational dependence of the rotational Hamiltonian). (See also Refs. 20 and 22.)
27. G. Herzberg, Molecular Spectra and Molecular Structure III: Electronic Spectra and Electronic Structure of Polyatomic Molecules (Van Nostrand Reinhold, New York, 1966).
28. R. N. Zare, Angular Momentum. Understanding Spatial Aspects in Chemistry and Physics (Wiley, New York, 1988).
29. Franck-Condon approximation is used here in the standard sense, that is, neglect of the coordinate dependence of the electronic bound-free transition dipole elements.
30. G. Herzberg, Spectra of Diatomic Molecules (Van Nostrand Reinhold, New York, 1950).
31. C. Bordas, P. Labastie, J. Chevaleyre, and M. Broyer, Chem. Phys. 129, 21 (1989).
32. I. Sh. Averbukh and N. F. Perel'man, Sov. Phys. JETP 69, 464 (1989); C. Leichtle, I. Sh. Averbukh, and W. P. Schleich, Phys. Rev. Lett. 77, 3999 (1996); Phys. Rev. A 54, 5299 (1996).
33. I. Sh. Averbukh and N. F. Perel'man, Sov. Phys. JETP 69, 464 (1989); C. Leichtle, I. Sh. Averbukh, and W. P. Schleich, Phys. Rev. Lett. 77, 3999 (1996); Phys. Rev. A 54, 5299 (1996).
34. I. Sh. Averbukh and N. F. Perel'man, Sov. Phys. JETP 69, 464 (1989); C. Leichtle, I. Sh. Averbukh, and W. P. Schleich, Phys. Rev. Lett. 77, 3999 (1996); Phys. Rev. A 54, 5299 (1996).
35. J. A. Yearell and C, R. Stroud, Jr., Phys. Rev. A 43, 5153 (1991).
36. M. J. J. Vrakking, D. M. Villeneuve, and A. Stolow, Phys. Rev. A 54, R37 (1996).
37. l) gives almost the same β(Δt) as those shown in Figs. 2-5. They differ only in the overall shape of the PAD, and in the response of β(Δt) on the rotational time scale. These results are not shown here.