Mechanistic insight into the cyclohexene epoxidation with VO(acac) 2 and tert-butyl hydroperoxide

Journal of Catalysis

Volumn 294, Issue , 2012, Pages 1-18

  Vandichel, Matthias ^a   Leus, Karen ^a   Van Der Voort, Pascal ^a   Waroquier, Michel ^a   Van Speybroeck, Veronique ^a  

^a GHENT UNIVERSITY   (Belgium)

Author keywords

Catalysis; Chemical kinetics; Cyclohexene; DFT; Epoxidation; Rate constants; tert Butyl hydroperoxide (TBHP); Vanadyl acetylacetonate (VO(acac) 2)

Indexed keywords

ACTIVE COMPLEXES; ACTIVE SPECIES; AS-LIGANDS; CATALYTIC CYCLES; CATALYTIC SYSTEM; CHEMICAL KINETICS CALCULATION; CYCLOHEXENE EPOXIDATION; CYCLOHEXENES; DECOMPOSITION REACTION; DFT; EPOXIDATION MECHANISM; EPOXIDATION REACTIONS; EXPERIMENTAL KINETICS; INACTIVE SPECIES; KINETIC STUDY; LIGAND EXCHANGE REACTIONS; OXIDATION STATE; QUALITATIVE COMPOSITIONS; REACTION MECHANISM; REACTION MIXTURE; TERT-BUTYLHYDROPEROXIDE; THEORETICAL VALUES; THERMODYNAMIC EQUILIBRIA; VANADYL ACETYLACETONATE;

CATALYSIS; EPOXIDATION; KINETICS; MIXTURES; OLEFINS; RATE CONSTANTS; REACTION KINETICS;

VANADIUM COMPOUNDS;

EID: 84865742568     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2012.06.002     Document Type: Article

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