Synthesis of stable ligand-free gold-palladium nanoparticles using a simple excess anion method

ACS Nano

Volumn 6, Issue 8, 2012, Pages 6600-6613

  Sankar, Meenakshisundaram ^a   He, Qian ^b   Morad, Moataz ^a   Pritchard, James ^a   Freakley, Simon J ^a   Edwards, Jennifer K ^a   Taylor, Stuart H ^a   Morgan, David J ^a   Carley, Albert F ^a   Knight, David W ^a   Kiely, Christopher J ^b   Hutchings, Graham J ^a  

^a CARDIFF UNIVERSITY   (United Kingdom)

^b Lehigh University   (United States)

Author keywords

anion excess; direct synthesis of hydrogen peroxide; gold palladium; ligand free synthesis; modified impregnation

Indexed keywords

AEROBIC OXIDATIONS; ANION CONCENTRATIONS; ANION-EXCESS; AVERAGE PARTICLE SIZE; BENZYL ALCOHOL; COMPOSITIONAL UNIFORMITY; DIRECT SYNTHESIS; EDX ANALYSIS; GOLD-PALLADIUM; IMMOBILIZATION METHOD; IMPREGNATION METHODS; INDIVIDUAL PARTICLES; LIGAND-FREE; NANOALLOY PARTICLES; PARTICLE SURFACE; RANDOM ALLOY; SOLVENT FREE;

CATALYSTS; GOLD; HYDROGEN PEROXIDE; IMPREGNATION; NANOPARTICLES; PARTICLE SIZE ANALYSIS; SOLS;

IONS;

ANION; BENZYL ALCOHOL; GOLD; LIGAND; METAL NANOPARTICLE; PALLADIUM;

ARTICLE; CATALYSIS; CHEMISTRY; CONFORMATION; CRYSTALLIZATION; MACROMOLECULE; MATERIALS TESTING; METHODOLOGY; OXIDATION REDUCTION REACTION; PARTICLE SIZE; SURFACE PROPERTY;

ANIONS; BENZYL ALCOHOL; CATALYSIS; CRYSTALLIZATION; GOLD; LIGANDS; MACROMOLECULAR SUBSTANCES; MATERIALS TESTING; METAL NANOPARTICLES; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; PALLADIUM; PARTICLE SIZE; SURFACE PROPERTIES;

EID: 84865608873     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn302299e     Document Type: Article

References (57)

1. Haruta, M.; Kobayashi, T.; Sano, H.; Yamada, N. Novel Gold Catalysts for the Oxidation of Carbon-Monoxide at a Temperature Far Below 0 °C Chem. Lett. 1987, 405-408
2. Hutchings, G. J. Vapor Phase Hydrochlorination of Acetylene: Correlation of Catalytic Activity of Supported Metal Chloride Catalysts J. Catal. 1985, 96, 292-295
3. Choudhary, T. V.; Goodman, D. W. Oxidation Catalysis by Supported Gold Nano-clusters Top. Catal. 2002, 21, 25-34
4. Haruta, M.; Yamada, N.; Kobayashi, T.; Iijima, S. Gold Catalysts Prepared by Co-precipitation for Low-Temperature Oxidation of Hydrogen and of Carbon Monoxide J. Catal. 1989, 115, 301-309
5. Bond, G. C.; Thompson, D. T. Catalysis by Gold Catal. Rev., Sci. Eng. 1999, 41, 319-388
6. Haruta, M.; Daté, M. Advances in the Catalysis of Au Nanoparticles App. Catal. A: Gen. 2001, 222, 427-437
7. 2 Increases the Activity of Au for CO Oxidation by Two Orders of Magnitude Angew. Chem., Intl. Ed. 2004, 43, 2538-2540
8. Fu, Q.; Saltsburg, H.; Flytzani-Stephanopoulos, M. Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts Science 2003, 301, 935-938
9. 2 via Gold for Use in Fuel Cells Chem. Commun. 2005, 3385-3387
10. Corma, A.; Garcia, H. Supported Gold Nanoparticles as Catalysts for Organic Reactions Chem. Soc. Rev. 2008, 37, 2096-2126
11. Corma, A.; Serna, P. Chemoselective Hydrogenation of Nitro Compounds with Supported Gold Catalysts Science 2006, 313, 332-334
12. Della Pina, C.; Falletta, E.; Prati, L.; Rossi, M. Selective Oxidation Using Gold Chem. Soc. Rev. 2008, 37, 2077-2095
13. Edwards, J. K.; Hutchings, G. J. Palladium and Gold-Palladium Catalysts for the Direct Synthesis of Hydrogen Peroxide Angew. Chem., Int. Ed. 2008, 47, 9192-9198
14. Corma, A.; Juarez, R.; Boronat, M.; Sanchez, F.; Iglesias, M.; Garcia, H. Gold Catalyzes the Sonogashira Coupling Reaction without the Requirement of Palladium Impurities Chem. Commun. 2011, 47, 1446-1448
15. 2 Catalyst Science 2006, 311, 362-365
16. Kobayashi, H.; Yamauchi, M.; Ikeda, R.; Kitagawa, H. Atomic-Level Pd-Au Alloying and Controllable Hydrogen-Absorption Properties in Size-Controlled Nanoparticles Synthesized by Hydrogen Reduction Chem. Commun. 2009, 4806-4808
17. Alayoglu, S.; Nilekar, A. U.; Mavrikakis, M.; Eichhorn, B. Ru-Pt Core-Shell Nanoparticles for Preferential Oxidation of Carbon Monoxide in Hydrogen Nat. Mater. 2008, 7, 333-338
18. Ferrando, R.; Jellinek, J.; Johnston, R. L. Nanoalloys: From Theory to Applications of Alloy Clusters and Nanoparticles Chem. Rev. 2008, 108, 845-910
19. 2 Catalysts Science 2006, 311, 362-365
20. Daniel, M. C.; Astruc, D. Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications Toward Biology, Catalysis, and Nanotechnology Chem. Rev. 2004, 104, 293-346
21. Campelo, J. M.; Luna, D.; Luque, R.; Marinas, J. M.; Romero, A. A. Sustainable Preparation of Supported Metal Nanoparticles and Their Applications in Catalysis ChemSusChem 2009, 2, 18-45
22. 2 J. Phys. Chem. B 2002, 106, 7634-7642
23. 2 Catal. Lett. 1998, 51, 53-58
24. Serpell, C. J.; Cookson, J.; Ozkaya, D.; Beer, P. D. Core@Shell Bimetallic Nanoparticle Synthesis via Anion Coordination Nat. Chem. 2011, 3, 478-483
25. Villa, A.; Wang, D.; Su, D. S.; Prati, L. Gold Sols as Catalysts for Glycerol Oxidation: The Role of Stabilizer ChemCatChem 2009, 1, 510-514
26. Comotti, M.; Li, W.-C.; Spliethoff, B.; Schüth, F. Support Effect in High Activity Gold Catalysts for CO Oxidation J. Am. Chem. Soc. 2005, 128, 917-924
27. 2 Catalysts for CO Oxidation by Deposition-Precipitation or Impregnation J. Catal. 2006, 237, 190-196
28. Baatz, C.; Decker, N.; Prüe, U. New Innovative Gold Catalysts Prepared by an Improved Incipient Wetness Method J. Catal. 2008, 258, 165-169
29. Zheng, N.; Stucky, G. D. A General Synthetic Strategy for Oxide-Supported Metal Nanoparticle Catalysts J. Am. Chem. Soc. 2006, 128, 14278-14280
30. Yan, W.; Brown, S.; Pan, Z.; Mahurin, S. M.; Overbury, S. H.; Dai, S. Ultrastable Gold Nanocatalyst Supported by Nanosized Non-oxide Substrate Angew. Chem., Int. Ed. 2006, 45, 3614-3618
31. Edwards, J. K.; Solsona, B.; N, E. N.; Carley, A. F.; Herzing, A. A.; Kiely, C. J.; Hutchings, G. J. Switching-Off Hydrogen Peroxide Hydrogenation in the Direct Synthesis Process Science 2009, 323, 1037-1041
32. 2 Using Supported Au-Pd Catalysts Faraday Discuss. 2008, 138, 225-239
33. Haruta, M. Gold as a Novel Catalyst in the 21st Century: Preparation, Working Mechanism and Applications Gold Bull. 2004, 37, 27-36
34. Lopez-Sanchez, J. A.; Dimitratos, N.; Hammond, C.; Brett, G. L.; Kesavan, L.; White, S.; Miedziak, P.; Tiruvalam, R.; Jenkins, R. L.; Carley, A. F.; Knight, D.; Kiely, C. J.; Hutchings, G. J. Facile Removal of Stabilizer-Ligands from Supported Gold Nanoparticles Nat. Chem. 2011, 3, 551-556
35. Carabineiro, S. A. C.; Thompson, D. T. Catalytic Applications for Gold Nanotechnology Nanocatalysis 2007, 377-489
36. Kung, H. H.; Kung, M. C.; Costello, C. K. Supported Au Catalysts for Low Temperature CO Oxidation J. Catal. 2003, 216, 425-432
37. Oh, H. S.; Yang, J. H.; Costello, C. K.; Wang, Y. M.; Bare, S. R.; Kung, H. H.; Kung, M. C. Selective Catalytic Oxidation of CO: Effect of Chloride on Supported Au Catalysts J. Catal. 2002, 210, 375-386
38. Kung, M. C.; Davis, R. J.; Kung, H. H. Understanding Au-Catalyzed Low-Temperature CO Oxidation J. Phys. Chem. C 2007, 111, 11767-11775
39. Bowker, M.; Nuhu, A.; Soares, J. High Activity-Supported Gold Catalysts by Incipient Wetness Impregnation Catal. Today 2007, 122, 245-247
40. Ivanova, S.; Petit, C.; Pitchon, V. A New Preparation Method for the Formation of Gold Nanoparticles on an Oxide Support Appl. Catal. A: Gen. 2004, 267, 191-201
41. Pritchard, J. C.; He, Q.; Ntainjua, E. N.; Piccinini, M.; Edwards, J. K.; Herzing, A. A.; Carley, A. F.; Moulijn, J. A.; Kiely, C. J.; Hutchings, G. J. The Effect of Catalyst Preparation Method on the Performance of Supported Au-Pd Catalysts for the Direct Synthesis of Hydrogen Peroxide Green Chem. 2010, 12, 915-921
42. Pritchard, J.; Kesavan, L.; Piccinini, M.; He, Q.; Tiruvalam, R.; Dimitratos, N.; Lopez-Sanchez, J. A.; Carley, A. F.; Edwards, J. K.; Kiely, C. J.; Hutchings, G. J. Direct Synthesis of Hydrogen Peroxide and Benzyl Alcohol Oxidation Using Au-Pd Catalysts Prepared by Sol Immobilization Langmuir 2010, 26, 16568-16577
43. 0 Nanoparticle Formation on Hydroxyapatite and Its Application for Regioselective Quinoline Hydrogenation Chem. Lett. 2010, 39, 832-834
44. Meenakshisundaram, S.; Nowicka, E.; Miedziak, P. J.; Brett, G. L.; Jenkins, R. L.; Dimitratos, N.; Taylor, S. H.; Knight, D. W.; Bethell, D.; Hutchings, G. J. Oxidation of Alcohols Using Supported Gold and Gold-Palladium Nanoparticles Faraday Discuss. 2010, 145, 341-356
45. Sankar, M.; Nowicka, E.; Tiruvalam, R.; He, Q.; Taylor, S. H.; Kiely, C. J.; Bethell, D.; Knight, D. W.; Hutchings, G. J. Controlling the Duality of the Mechanism in Liquid-Phase Oxidation of Benzyl Alcohol Catalysed by Supported Au-Pd Nanoparticles Chem.-Eur. J. 2011, 17, 6524-6532
46. Tiruvalam, R. C.; Pritchard, J. C.; Dimitratos, N.; Lopez-Sanchez, J. A.; Edwards, J. K.; Carley, A. F.; Hutchings, G. J.; Kiely, C. J. Aberration Corrected Analytical Electron Microscopy Studies of Sol-Immobilized Au + Pd, Au{Pd} and Pd{Au} Catalysts Used for Benzyl Alcohol Oxidation and Hydrogen Peroxide Production Faraday Discuss. 2011, 152, 63-86
47. 2-Supported Au-Pd Catalysts J. Catal. 2005, 236, 69-79
48. Herzing, A. A.; Watanabe, M.; Edwards, J. K.; Conte, M.; Tang, Z.-R.; Hutchings, G. J.; Kiely, C. J. Energy Dispersive X-ray Spectroscopy of Bimetallic Nanoparticles in an Aberration Corrected Scanning Transmission Electron Microscope Faraday Discuss. 2008, 138, 337-351
49. 2 Catalysts Appl. Catal. A: Gen. 2005, 290, 138-147
50. 2 Catalyst in CO Oxidation J. Mol. Catal. A: Chem. 2004, 213, 235-240
51. Arrii, S.; Morfin, F.; Renouprez, A. J.; Rousset, J. L. Oxidation of CO on Gold Supported Catalysts Prepared by Laser Vaporization: Direct Evidence of Support Contribution J. Am. Chem. Soc. 2004, 126, 1199-1205
52. Radnik, J.; Mohr, C.; Claus, P. On the Origin of Binding Energy Shifts of Core Levels of Supported Gold Nanoparticles and Dependence of Pretreatment and Material Synthesis Phys. Chem. Chem. Phys. 2003, 5, 172-177
53. 2 J. Catal. 2010, 269, 191-200
54. 2 Doped Amorphous Silica Appl. Catal. A: Gen. 2006, 310, 114-121
55. Egelhoff, W. F., Jr.; Tibbetts, G. G. Growth of Copper, Nickel, and Palladium Films on Graphite and Amorphous Carbon Phys. Rev. B 1979, 19, 5028-5035
56. 2 Precursor J. Catal. 2012, 286, 1-5
57. 2 Catalysts for Carbon Monoxide Hydrogenation Appl. Catal. 1990, 57, 55-70