Hydrogenation of cottonseed oil with nickel, palladium and platinum catalysts

JAOCS, Journal of the American Oil Chemists' Society

Volumn 89, Issue 8, 2012, Pages 1557-1566

  Cheng, H N ^a   Dowd, Michael K ^a   Easson, Michael W ^a   Condon, Brian D ^a  

^a SOUTHERN REGIONAL RESEARCH CENTER   (United States)

Author keywords

Cottonseed oil; Hydrogenation; Nickel catalyst; Palladium catalyst; Platinum catalyst; Trans Fatty acids

Indexed keywords

EXPERIMENTAL CONDITIONS; IODINE VALUE; KINETIC MODELING; LINOLEIC; NICKEL CATALYST; PALLADIUM CATALYST; PLATINUM CATALYSTS; PT CATALYSTS; RELATIVE REACTION RATES; TRANS FATTY ACID;

CATALYST SUPPORTS; COTTONSEED OIL; IODINE; ISOMERS; NICKEL; OLEIC ACID; PLATINUM; REACTION RATES; STEARIC ACID;

HYDROGENATION;

GOSSYPIUM HIRSUTUM; MICROPUS;

EID: 84865368223     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-012-2036-8     Document Type: Article

References (32)

1. National Cottonseed Products Association (accessed Sept. 2011) Twenty facts about cottonseed oil. http://www.cottonseed.com/publications/facts.asp
2. List GR, Friedrich JP (1989) Oxidative stability of seed oils extracted with supercritical carbon dioxide. J Am Oil Chem Soc 66:98-101
3. Zhu Q, Zang L, Zhang L, Yun Z (2012) Two approaches in preparation for cogeneration a-tocopherol and biodiesel from cottonseed. Can J Chem Eng 90:171-179
4. US Department of Agriculture, Foreign Agricultural Service (accessed January 2012) Major vegetable oils: world supply and distribution. http://www.fas.usda.gov/psdonline/
5. Patterson HBW (1994) Hydrogenation of fats and oils: theory and practice. AOCS Press, Champaign
6. Dijkstra AJ (2006) Revisiting the formation of trans isomers during partial hydrogenation of triacylglycerol oils. Eur J Lipid Sci Technol 108:249-264
7. List GR, Jackson M, Eller F, Adlof RO (2007) Low-trans shortening and spread fats produced by electrochemical hydrogenation. J Am Oil Chem Soc 84:497-501 (Pubitemid 46742396)
8. Jang ES, Jung MY, Min DB (2005) Hydrogenation for low trans and high conjugated fatty acids. Compreh Rev Food Sci Food Safety 1:22-30 (Pubitemid 44400592)
9. Beers AEW (2007) Low trans hydrogenation of edible oils. Lipid Technol 19:56-58
10. Beers AEW, Mangnus G (2004) Hydrogenation of edible oils for reduced trans fatty acid content. Inform 15:404-405
11. Willett WC (1994) Diet and health: what should we eat? Science 264(5158):532-537 (Pubitemid 24185857)
12. Hu FB, Stampfer MJ, Manson JE, Ascherio A, Colditz GA, Speizer FE, Hennekens CH, Willett WC (1999) Dietary saturated fats and their food sources in relation to the risk of coronary heart disease in women. Am J Clin Nutr 70:1001-1008
13. Mensick RP, Katan MB (1990) Effect of dietary trans fatty acids on high density and low density lipoprotein cholesterol levels in healthy subjects. New Engl J Med 323:435-495
14. Anon (2003) Trans fatty acids in nutrition labeling: final rules. Federal Register 11 July 2003. 68:41433-41506
15. List GR (2004) Decreasing trans and saturated fatty acid content in food oils. Food Technol 58:23-31
16. Jackson MA, List GR, Palmquist D (2008) Low trans-fat spreads and shortenings from a catalyst-switching strategy. J Am Oil Chem Soc 85:481-486
17. Fernandez MB, Tonetto GM, Crapiste GH, Damiani DE (2007) Revisiting the hydrogenation of sunflower oil over a Ni catalyst. J Food Eng 82:199-208 (Pubitemid 46560185)
18. Eller FJ, List GR, Teel JA, Steidley KR, Adlof RO (2005) Preparation of spread oils meeting U.S. Food and Drug Administration labeling requirements for trans fatty acids via pressurecontrolled hydrogenation. J Agric Food Chem 53:5982-5984 (Pubitemid 41126635)
19. Hsu N, Diosady LL, Graydon WF, Rubin LJ (1988) Catalytic behavior of palladium in the hydrogenation of edible oils. J Am Oil Chem Soc 65:608-688
20. Hsu N, Diosady LL, Graydon WF, Rubin LJ (1986) Heterogeneous catalytic hydrogenation of canola oil using palladium. J Am Oil Chem Soc 63:1036-1042 (Pubitemid 16609715)
21. Lee K-W, Mei BX, Bo Q, Kim Y-W, Chung K-W, Han Y (2007) Catalytic selective hydrogenation of soybean oil for industrial intermediates. J Ind Eng Chem 13:530-536
22. Miyake Y, Yokomizo K, Matsuzuki N (1998) Determination of unsaturated fatty acid composition by high-resolution NMR spectroscopy. J Am Oil Chem Soc 75:1091-1094 (Pubitemid 128567003)
23. AOAC (1984) Official Method, Ch 28.023. AOAC Press, Gaithersburg
24. BASF (accessed Sept 2011). Nysosel®. http://www.basf.com/group/ corporate/en/brand/NYSOSEL
25. Johnson Matthey (accessed Sept 2011). Chemical catalysts. http://www.jmcatalysts.com/chemicalcatalysts
26. Babaee Z, Nikoopour H, Safafar H (2007) A comparison of commercial nickel catalyst effects on hydrogenation of soybean oil. World Appl Sci J 2:621-626
27. Hashimoto K, Muroyama K, Nagata S (1971) Kinetics of the hydrogenation of fatty oils. J Am Oil Chem Soc 498:291-295
28. Fillion B, Morsi BI, Heier KR, Machado RM (2002) Kinetics, gas-liquid mass transfer, and modeling of the soybean oil hydrogenation process. Ind Eng Chem Res 41:697-709 (Pubitemid 34165734)
29. Krishnaiah D, Sarkar S (1990) Kinetics of liquid phase hydrogenation of cottonseed oil with nickel catalysts. J Am Oil Chem Soc 67:233-238 (Pubitemid 20706011)
30. Marangozis J, Keramidas OB, Paparisvas G (1977) Rate and mechanism of hydrogenation of cottonseed oil in slurry reactors. Ind Eng Chem Process Des Dev 16:361-369
31. Wisniak J, Albright LF (1961) Hydrogenating cottonseed oil at relatively high pressure. Ind Eng Chem 53:375-380
32. Eldib IA, Albright LF (1957) Operating variables in hydrogenating cottonseed oil. Ind Eng Chem 49:825-831