Giving physical insight into the Butler-Volmer model of electrode kinetics: Part 2 - Nonlinear solvation effects on the voltammetry of heterogeneous electron transfer processes

Journal of Electroanalytical Chemistry

Volumn 681, Issue , 2012, Pages 96-102

  Laborda, Eduardo ^a   Henstridge, Martin C ^a   Compton, Richard G ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

Electrode kinetics; Marcus Hush model; Matyushov model; Nonlinear solvation; Solvent force constants

Indexed keywords

EXPERIMENTS; RATE CONSTANTS; REDOX REACTIONS; SOLVATION; SOLVENTS; VOLTAMMETRY;

BUTLER-VOLMER; BUTLER-VOLMER MODELS; COMPTON; DIFFERENT SOLVENTS; ELECTROCHEMICAL EXPERIMENTS; ELECTRODE KINETICS; ELECTRODE PROCESS; ENERGY SURFACE; FORCE CONSTANTS; HETEROGENEOUS ELECTRON TRANSFER; MARCUS-HUSH; OXIDATION AND REDUCTION; REDOX SYSTEMS; SOLVATION EFFECT; SOLVENT REORGANIZATION; SURFACE BOUNDS; TRANSFER COEFFICIENT; VIBRATIONAL FORCE;

ELECTROCHEMICAL ELECTRODES;

EID: 84864741832     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2012.06.008     Document Type: Article

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