Glyphosate detection by voltammetric techniques. A comparison between statistical methods and an artificial neural network

Sensors and Actuators, B: Chemical

Volumn 171-172, Issue , 2012, Pages 528-536

  Laguarda Miro, Nicolás ^a   Ferreira, Francesca Werner ^b   García Breijo, Eduardo ^a   Ibáñez Civera, Javier ^a   Gil Sánchez, Luis ^a   Garrigues Baixauli, José ^a  

^a UNIVERSITAT POLITÈCNICA DE VALÈNCIA   (Spain)

^b UNIVERSIDADE REGIONAL DO NOROESTE DO ESTADO DO RIO GRANDE DO SUL   (Brazil)

Author keywords

Artificial neural network; Glyphosate; Mathematical modeling; Microcontroller; Partial Least Squares; Voltammetry

Indexed keywords

A-TRAIN; AQUEOUS DISSOLUTION; DEVELOPED MODEL; ELECTROCHEMICAL RESPONSE; GLYPHOSATES; MODEL-BASED OPC; NATURAL WATER BODIES; P-VALUES; PARTIAL LEAST SQUARE (PLS); QUANTIFICATION METHODS; REGRESSION COEFFICIENT; RESEARCH GROUPS; STATISTIC METHOD; VOLTAMMETRIC; VOLTAMMETRIC TECHNIQUES;

COBALT; HERBICIDES; MATHEMATICAL MODELS; MICROCONTROLLERS; NEURAL NETWORKS;

VOLTAMMETRY;

EID: 84864287537     PISSN: 09254005     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.snb.2012.05.025     Document Type: Article

References (38)

1. E.V. Sierra, M.A. Méndez, V.M. Sarria, and M.T. Cortés Electrooxidation of glyphosate on nickel and copper electrodes Quimica Nova 31 2008 220 226
2. Ministerio de la Presidencia Orden PRE/876/2007 de 30 de Marzo por la que se modifican los anexos II de los Reales Decretos 569/1990 de 27 de abril y 280/1994 de 18 de febrero, por los que se establecen los límites máximos de residuos plaguicidas y su control en determinados productos de origen animal y vegetal, respectivamente Boletín Oficial del Estado 83 2007 37
3. Comisión de las Comunidades Europeas DIRECTIVA 2006/60/CE DE LA COMISION de 7 de julio de 2006 que modifica los anexos de la Directiva 90/642/CEE del Consejo por lo que especta a los limites maximos de residuos de trifloxistrobin, tiabendazol, abamectina, benomilo, carbendazima, tiofanato-metil, miclobutanil, glifosato, trimetilsulfonio, fenpropimorf y clormequat Diario Oficial de la Unión Europea 206 2006 11
4. USEPA 2012 Edition of the Drinking Water Standards and Health Advisories 2012 United States Environmental Protection Agency http://www.epa.gov/
5. Glyphosate Guidelines for Canadian Drinking Water Quality - Supporting Documents - Glyphosate 1995 Health Canada www.hc-sc.gc.ca
6. C. Cox Glyphosate (roundup) Journal of Pesticide Reform 18 1998 3 17
7. F. Nirascou, Les pesticides dans les eaux, Dossier 5 IFEN (2006) 36.
8. J.W. Sawchuk, R.C.V Van Acker, and L.F. Friesen Influence of a range of dosages of MCPA, glyphosate, and thifensulfuron:tribenuron (2:1) on conventional canola (Brassica napus) and white bean (Phaseolus vulgaris) growth and yield Weed Technology 20 2006 184 197
9. V. Contardo-Jara, E. Klingelmann, and C. Wiegand Bioaccumulation of glyphosate and its formulation Roundup Ultra in Lumbriculus variegatus and their effects on biotransformation and antioxidant enzymes Environmental Pollution 157 2009 57 63
10. C. Accinelli, C. Screpanti, A. Vicari, and P. Catizone Influence of insecticidal toxins from Bacillus thuringiensis subsp. kurstaki on the degradation of glyphosate and glufosinate-ammonium in soil samples Agriculture, Ecosystems & Environment 103 3 2004 497 507
11. Hoja de manejo seguro, ESTELAR 480 SL, Dow Chemical, 1999.
12. C. Gasnier, C. Dumont, N. Benachour, E. Clair, M.-C. Chagnon, and G.-E. Séralini Glyphosate-based herbicides are toxic and endocrine disruptors in human cell lines Toxicology 262 2009 184 191
13. F. Sánchez-Bayo, R.V. Hyne, and K.L. Desseille An amperometric method for the detection of amitrole glyphosate and its aminomethyl-phosphonic acid metabolite in environmental waters using passive samplers Analytica Chimica Acta 675 2010 125 131
14. C.F.B. Coutinho, L.F.M. Coutinho, L.H. Mazo, S.L. Nixdorf, and C.A.P. Camara Rapid and direct determination of glyphosate and aminomethyl phosphonic acid in wáter using anion-exchange chromatography with coloumetric detection Journal of Chromatography A 1208 2008 246 249
15. H.Y. Chiu, Z.Y. Lin, H. Tu, and Ch. Whang Analysis of glyphosate and aminomethylphosphonic acid by capillary electrophoresis with electrochemiluminiscence detection Journal of Chromatography A 1177 2008 185 198
16. J. Jin, F. Takahashi, T. Kaneko, and Toshio Nakamura Characterization of electrochimiluminiscence of tris (2,2′-bipiridine)ruthenium (II) with glyphosate as coreactant in aqueous solution Electrochimica Acta 55 2010 5532 5537
17. S. Aquino Neto, and A.R. de Andrade Electrooxidation of glyphosate herbicide at different DSA compositions: pH, concentration and supporting electrolyte effect Electrochimica Acta 54 2009 2039 2045
18. M.A. Méndez, M.F. Suárez, M.T. Cortés, and V.M. Sarria Electrochemical properties and electro-aggregation of silvercarbonate sol on polycrystalline platinum electroda and its alactrocatalytic activity towards glyphosate oxidation Electrochemistry Communications 9 2007 2585 2590
19. C.F.B. Coutinho, M.O. Silva, M.L. Calegaro, S.A.S. Mahcado, and L.H. Mazo Investigation of copper dissolution in the presence of glyphosate using hydrodynamic voltammetry and chronoamperometry Solid State Ionics 178 2007 161 164
20. E.A. Songa, O.A. Arotiva, J.H.O. Owino, N. Jahed, P.G.L. Baker, and E.I. Iwuoha Electrochemical detection of glyphosate herbicide using horseradish peroxidase immobilized on sulfonated polymer matrix Bioelectrochemistry 75 2009 117 123
21. A. Khenifi, Z. Derriche, C. Forano, V. Prevot, C. Mousty, E. Scavetta, B. Ballarin, L. Guadagnini, and D. Tonelli Glyphosate and glufosinate detection at electrogenerated NiAl-LDH thin films Analytica Chimica Acta 654 2 2009 97 102
22. R. Masot, M. Alcañiz, A. Fuentes, F.C. Schmidt, L. Gil, D. Baigts, R. Martínez-Máñez, J. Soto, and J.M. Barat Design of a low-cost non-destructive system for punctual measurements of salt levels in food products using impedance spectroscopy Sensors and Actuators A 158 2010 217 223
23. J.M. Barat, L. Gil, E. García-Breijo, M-C. Aristoy, F. Toldrá, R. Martínez-Máñez, and J. Soto Freshness monitoring of sea bream (Sparus aurata) with a potentiometric sensor Food Chemistry 108 2008 681 688
24. I. Campos, R. Masot, M. Alcañiz, L. Gil, J.L. Vivancos, E. García-Breijo, R.H. Labrador, J.M. Barat, R. Martínez- Máñez, and J. Soto Accurate concentration determination of anions nitrate, nitrite and chloride in minced meat using a voltammetric electronic tongue Sensors and Actuators B 149 2010 71 78
25. E. García-Breijo, J.M. Barat, O.L. Torres, R. Grau, J. Ibáñez, M. Alcañiz, R. Masot, R. Fraile, and L. Gil Development of a puncture electronic device for electrical conductivity measurements throughout meat salting Sensors and Actuators A 148 2008 63 67
26. L. Gil, J.M. Barat, E. Garcia-Breijo, J. Ibañez, R. Martínez-Máñez, J. Soto, E. Llobet, J. Brezemes, M.-C. Aristoy, and F. Toldrá Fish freshness analysis using metallic potentiometric electrodes Sensors and Actuators B 131 2008 362 370
27. R.H. Labrador, R. Masot, M. Alcañiz, D. Baigts, R. Martínez-Máñez, E. García-Breijo, L. Gil, J. Soto, and J.M. Barat Prediction of NaCl, nitrate and nitrite contents in minced meat by using a voltammetric electronic tongue and an impedimetric sensor Food Chemistry 122 2010 864 870
28. L. Gil, J.M. Barat, D. Baigts, R. Martínez-Máñez, E. García-Breijo, M-C. Aristoy, F. Toldrá, J. Soto, and E. Llobet Monitoring of physical-chemical and microbiological changes in fresh pork meat under cold storage by means of a potentiometric electronic tongue Food Chemistry 126 2011 1261 1268
29. E. Garcia-Breijo, J. Atkinson, L. Gil-Sanchez, R. Masot, J. Ibañez, J. Garrigues, M. Glanc, N. Laguarda-Miro, and C. Olguin A comparison study of pattern recognition algorithms implemented on a microcontroller for use in an electronic tongue for monitoring drinking waters Sensors and Actuators A: Physical 2011 10.1016/j.sna.2011.09.039
30. J. Ibáñez Civera, E. Garcia Breijo, N. Laguarda Miró, L. Gil Sánchez, J. Garrigues Baixauli, I. Romero Gil, R. Masot Peris, and M. Alcañiz Fillol Artificial neural network onto eight bit microcontroller for Secchi depth calculation Sensors and Actuators B 156 2011 132 139
31. B. Martin del Rio Redes Neuronales y Sistemas Borrosos 2006 Ed. Rama Madrid
32. P. Neelamegam, and A. Rajendran Neural network based density measurement Bulgarian Journal of Physics 31 2004 163 169
33. C.M. Bishop Neural Networks for Pattern Recognition 1995 Oxford Univ. Press New York
34. N. Medrano-Marqués, and B. Martin-del-Brío Implementing neural networks onto standard low-cost microcontroller for sensor signal processing Emerging Technologies and Factory Automation, ETFA, 10th IEEE Conference September 2005 972 978
35. G.A. Carpenter, and S. Gossberg ART2: self-organization of stablecategory recognition codes for analog input patterns Applied Optics 26 1987 4919 4930 (page 24 of 51 accepted manuscript 24)
36. G.A. Carpenter, S. Gossberg, N. Markuzon, J. Reynolds, and D. Rosen Fuzzy artmap: a neural network architecture for incremental supervised learning of analog multidimensional maps IEEE Transactions on Neural Networks 3 1992 698 713
37. I. Ben-Gal Outlier detection O. Maimon, L. Rockach, Data Mining and Knowledge Discovery Handbook: A Complete Guide for Practitioners and Researchers 2005 Kluwer Academic Publishers Tel-Aviv University, Israel
38. S. Walfish A review of statistical outlier methods PharmTech 2 November 2006 1 5