The electroneutrality approximation in electrochemistry

Journal of Solid State Electrochemistry

Volumn 15, Issue 7-8, 2011, Pages 1335-1345

  Dickinson, Edmund J F ^a   Limon Petersen, Juan G ^a   Compton, Richard G ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ABSOLUTE VALUES; CHARGE DYNAMICS; CHARGE SEPARATIONS; DIMENSIONAL ANALYSIS; DYNAMIC PROCESS; ELECTROLYTIC SOLUTION; ELECTRONEUTRALITY; LIQUID JUNCTION POTENTIAL; NANOMETRES; PHYSICAL PICTURES; THEORETICAL TECHNIQUE;

COMPUTER SIMULATION;

ELECTROLYTIC ANALYSIS;

EID: 84863755005     PISSN: 14328488     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10008-011-1323-X     Document Type: Article

References (47)

1. Nernst W (1889) Die elektromotorische Wirksamkeit der Jonen. Z Phys Chem 4:129-181
2. Planck M (1890) Ueber die Erregung von Electricität und Wärme in Electrolyten. Wied Ann 39:161-186
3. Planck M (1890) Ueber die Potentialdifferenz zwischen zwei verdünnten Lösungen binärer Electrolyte. Wied Ann 40:561-576
4. Henderson P (1907) Zur Thermodynamik der Flüssigkeitsketten. Z Phys Chem 59:118-127
5. Guggenheim EA (1930) A study of cells with liquid-liquid junctions. J Am Chem Soc 52:1315-1337
6. Hickman HJ (1970) The liquid junction potential - the free diffusion junction. Chem Eng Sci 25:381-398
7. Jackson JL (1974) Charge neutrality in electrolytic solutions and the liquid junction potential. J Phys Chem 78:2060-2064
8. Perram JW, Stiles PJ (2006) On the nature of liquid junction and membrane potentials. Phys Chem Chem Phys 8:4200-4213
9. Dickinson EJF, Freitag L, Compton RG (2010) Dynamic theory of liquid junction potentials. J Phys Chem B 114:187-197
10. Ward KR, Dickinson EJF, Compton RG (2010) Dynamic theory of type 3 liquid junction potentials: formation of multilayer liquid junctions. J Phys Chem B 114:4521-4528
11. Ward KR, Dickinson EJF, Compton RG (2010) Dynamic theory of membrane potentials. J Phys Chem B 114:10763-10773
12. Bazant MZ, Thornton K, Ajdari A (2004) Diffuse-charge dynamics in electrochemical systems. Phys Rev E 70:021506
13. Bond AM, Fleischmann M, Robinson J (1984) Voltammetric measurements using microelectrodes in highly dilute solutions: theoretical considerations. J Electroanal Chem 172:11-25 (Pubitemid 14622852)
14. Amatore C, Deakin MR, Wightman RM (1987) Electrochemical kinetics at microelectrodes. Part IV. Electrochemistry in media of low ionic strength. J Electroanal Chem 225:49-63
15. Amatore C, Fosset B, Bartelt J, Deakin MR, Wightman RM (1988) Electrochemical kinetics at microelectrodes. Part V. Migrational effects on steady or quasi-steady-state voltammograms. J Electroanal Chem 256:255-268
16. Oldham KB (1988) Theory of microelectrode voltammetry with little electrolyte. J Electroanal Chem 250:1-21
17. Norton JD, White HS, Feldberg SW (1990) Effect of the electrical double layer on voltammetry at microelectrodes. J Phys Chem 94:6772-6780
18. Cooper JB, Bond AM, Oldham KB (1992) Microelectrode studies without supporting electrolyte: model and experimental comparison for singly and multiply charged ions. J Electroanal Chem 331:877-895
19. Oldham KB (1992) Theory of steady-state voltammetry without supporting electrolyte. J Electroanal Chem 337:91-126
20. Myland JC, Oldham KB (1993) General theory of steadystate voltammetry. J Electroanal Chem 347:49-91
21. Ciszkowska M, Jaworski A, Osteryoung JG (1997) Voltammetric reduction of hydrogen ion in solutions of polyprotic strong acids with and without supporting electrolyte. J Electroanal Chem 423:95-101 (Pubitemid 127417198)
22. Hyk W, Stojek Z (1997) Migrational chronoamperometry for various reaction stoichiometrics and a variety of types of supporting electrolytes. J Electroanal Chem 439:81-88 (Pubitemid 127436362)
23. Hyk W, Stojek Z (2002) Generalized theory of steady-state voltammetry without a supporting electrolyte. Effect of product and substrate diffusion coefficient diversity. Anal Chem 74:4805-4813
24. Hyk W, Stojek Z (2005) General theory for migrational voltammetry. Strong influence of diversity in redox species diffusivities on charge reversal electrode processes. Anal Chem 77:6481-6486 (Pubitemid 41436990)
25. Bond AM, Feldberg SW (1998) Analysis of simulated reversible cyclic voltammetric responses for charged redox species in the absence of added electrolyte. J Phys Chem B 102:9966-9974 (Pubitemid 128605091)
26. 4- couple in the absence of added supporting electrolyte at a rotating disk electrode. J Phys Chem A 105:9085-9093
27. Ciszkowska M, Stojek Z (2000) Voltammetric and amperometric detection without added electrolyte. Anal Chem 72:754A-760A
28. Bond AM (2004) Illustration of experimental and theoretical problems encountered in cyclic voltammetric studies of charged species without added supporting electrolyte. In: Pombeiro AJL, Amatore C (eds) Trends in molecular electrochemistry, chap 14. Marcel Dekker, New York, pp 445-502
29. Oldham KB, Bond AM (2001) How valid is the electroneutrality approximation in the theory of steady-state voltammetry? J Electroanal Chem 508:28-40 (Pubitemid 32683262)
30. Smith CP, White HS (1993) Theory of the voltammetric response of electrodes of submicron dimensions violation of electroneutrality in the presence of excess supporting electrolyte. Anal Chem 65:3343-3353
31. Hyk W, Palys M, Stojek Z (1996) Migrational chronoamperometry of uncharged substrates. Influence of electron transfer rate. J Electroanal Chem 415:13-22 (Pubitemid 126389562)
32. Bonnefont A, Argoul F, Bazant MZ (2001) Analysis of diffuse-layer effects on time-dependent interfacial kinetics. J Electroanal Chem 500:52-61 (Pubitemid 32263563)
33. He R, Chen S, Yang F, Wu B (2006) Dynamic diffuse doublelayer model for the electrochemistry of nanometer-sized electrodes. J Phys Chem B 110:3262-3270
34. Yang X, Zhang G (2007) Simulating the structure and effect of the electrical double layer at nanometer electrodes. Nanotechnology 18:335201/1-335201/9
35. Liu Y, He R, Zhang Q, Chen S (2010) Theory of electrochemistry for nanometer-sized disk electrodes. J Phys Chem C 114:10812-10822
36. Streeter I, Compton RG (2008) Numerical simulation of potential step chronoamperometry at low concentrations of supporting electrolyte. J Phys Chem C 112:13716-13728
37. Dickinson EJF, Compton RG (2010) The zero-field approximation for weakly supported voltammetry: a critical evaluation. Chem Phys Lett 497:178-183
38. Limon-Petersen JG, Streeter I, Rees NV, Compton RG (2008) Voltammetry in weakly supported media: the stripping of thallium from a hemispherical amalgam drop. Theory and experiment. J Phys Chem C 112:17175-17182
39. Limon-Petersen JG, Streeter I, Rees NV, Compton RG (2009) Quantitative voltammetry in weakly supported media: effects of the applied overpotential and supporting electrolyte concentration on the one electron oxidation of ferrocene in acetonitrile. J Phys Chem C 113:333-337
40. Dickinson EJF, Limon-Petersen JG, Rees NV, Compton RG (2009) How much supporting electrolyte is required to make a cyclic voltammetry experiment quantitatively 'diffusional'? A theoretical and experimental investigation. J Phys Chem C 113:11157-11171
41. Limon-Petersen JG, Dickinson EJF, Rees NV, Compton RG (2009) Quantitative voltammetry in weakly supported media. Two electron transfer chronoamperometry of electrodeposition and stripping for cadmium at microhemispherical mercury electrodes. J Phys Chem C 113:15320-15325
42. Limon-Petersen JG, Han JT, Rees NV, Dickinson EJF, Streeter I, Compton RG (2010) Quantitative voltammetry in weakly supported media. Chronoamperometric studies on diverse one electron couples containing various charged species, dissecting diffusional and migrational contributions and assessing the breakdown of electroneutrality. J Phys Chem C 114:2227-2236
43. Limon-Petersen JG, Dickinson EJF, Doneux T, Rees NV, Compton RG (2010) Voltammetry involving amalgam formation and anodic stripping in weakly supported media: theory and experiment. J Phys Chem C 114:7120-7127
44. Belding SR, Limon-Petersen JG, Dickinson EJF, Compton RG (2010) Cyclic voltammetry in the absence of excess supporting electrolyte offers extra kinetic and mechanistic insights: comproportionation of anthraquinone and the anthraquinone dianion in acetonitrile. Angew Chem Int Ed 49: 9242-9245
45. Limon-Petersen JG, Dickinson EJF, Belding SR, Rees NV, Compton RG (2010) Cyclic voltammetry in weakly supported media: the reduction of the cobaltocenium cation in acetonitrile - comparison between theory and experiment. J Electroanal Chem 650:135-142
46. Norton JD, Benson WW, White HS, Pendley BD, Abruña HD (1991) Voltammetric measurements of bimolecular electro-transfer rates in low ionic strength solutions. Anal Chem 63: 1909-1914
47. 60. Electrochem Commun 11:905-908