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Volumn 114, Issue 1, 2010, Pages 187-197

Dynamic theory of liquid junction potentials

Author keywords

[No Author keywords available]

Indexed keywords

ASYMPTOTIC ANALYSIS; ELECTRIC FIELDS; LIQUIDS;

EID: 75649102130     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp908024s     Document Type: Article
Times cited : (34)

References (31)
  • 3
    • 0001456896 scopus 로고
    • Planck, M. Wied. Ann. 1890, 39, 161-186.
    • (1890) Wied. Ann , vol.39 , pp. 161-186
    • Planck, M.1
  • 4
    • 0001369532 scopus 로고
    • Planck, M. Wied. Ann. 1890, 40, 561-576.
    • (1890) Wied. Ann , vol.40 , pp. 561-576
    • Planck, M.1
  • 5
    • 84906401126 scopus 로고    scopus 로고
    • In the case of a finitely positioned impermeable membrane, however, the liquid junction potential is not constant and an attainable equilibrium of zero concentration gradient exists, where the liquid junction potential is zero cf. ref 14, However, if the membrane is permeable to any species, the diffuse layer outside that membrane must be considered. Finitely positioned Dirichlet conditions are therefore to our minds unphysical for any system, excepting the imposition of a convectional Nernst layer
    • In the case of a finitely positioned impermeable membrane, however, the liquid junction potential is not constant and an attainable equilibrium of zero concentration gradient exists, where the liquid junction potential is zero (cf. ref 14). However, if the membrane is permeable to any species, the diffuse layer outside that membrane must be considered. Finitely positioned Dirichlet conditions are therefore to our minds unphysical for any system, excepting the imposition of a convectional Nernst layer.
  • 23


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.