Analysis of simulated reversible cyclic voltammetric responses for a charged redox species in the absence of added electrolyte

Journal of Physical Chemistry B

Volumn 102, Issue 49, 1998, Pages 9966-9974

  Bond, Alan M ^a   Feldberg, Stephen W ^b  

^a MONASH UNIVERSITY   (Australia)

^b BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001273560     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9828437     Document Type: Article

References (21)

1. Potentiometry is also a viable approach when both components of a redox couple are stable and easily prepared-not always the case.
2. Cyclic voltammetric protocol changes the potential of the working electrode between specified potential limits with dV/dt = ±v.
3. Throughout this paper we assume the IUPAC sign convention: reduction currents are negative, oxidation currents are positive.
4. Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications; J. Wiley and Sons: New York, 1980; pp 571-573.
5. e 2. Consideration of quasi-reversible electron transfer, already complicated by introduction of heterogeneous rate parameters, is further complicated by diffuse double layer effects.
6. Way, D. M.; Bond, A. M.; Wedd, A. G. Inorg. Chem. 1997, 36, 2826.
7. -). The implicit presumption in these analyses is that the concentration of adventitious ions will be a small fraction of the analyte concentration.
8. Norton, J. D.; White, H. S.; Feldberg, S. W. J. Phys. Chem. 1990, 90, 6772.
9. Smith, C. P.; White, H. S. Anal. Chem.1993, 65, 3343.
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14. Jaworski, A.; Donten, M.; Stojek, Z. J. Electroanal. Chem. 1997, 420, 307 (a correction to ref 13).
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16. half = 2 for examples in this paper).
17. 1/2.
18. A, for all species.
19. Rudolph, M In Physical Electrochemistry, Principles, Methods, and Applications; Rubinstein, I., Ed.; Marcel Dekker: New York, 1995.
20. 13,14 is for uncompensated chronoamperometry.
21. Oldham, K. B.; Feldberg, S. W. J. Phys. Chem., submitted for publication.