Theoretical elucidation on the regio-, diastereo-, and enantio- selectivities of chiral primary-tertiary diamine catalyst for asymmetric direct aldol reactions of aliphatic ketones

Journal of Physical Chemistry A

Volumn 116, Issue 26, 2012, Pages 7082-7088

  Sun, Xiangting ^a   Zhu, Rongxiu ^a   Gao, Jun ^a   Zhang, Dongju ^a   Feng, Dacheng ^a  

^a SHANDONG UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ALDOL REACTIONS; ALIPHATIC KETONES; BOND-FORMING STEP; CYCLOHEXANONES; DENSITY FUNCTIONAL THEORY CALCULATIONS; DIASTEREO-SELECTIVITY; DIRECT ALDOL REACTION; ENANTIO; HIGH ENANTIOSELECTIVITY; RELATIVE STABILITIES; THEORETICAL RESULT; TRANSITION STATE;

ACETONE; ALDEHYDES; CHEMICAL BONDS; CHEMICAL REACTIONS; DENSITY FUNCTIONAL THEORY; ORGANIC COMPOUNDS; STEREOSELECTIVITY;

CATALYST SELECTIVITY;

EID: 84863617016     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp2124873     Document Type: Article

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