Catalysis of the Hajos-Parrish-Eder-Sauer-Wiechert reaction by cis- and trans-4,5-methanoprolines: Sensitivity of proline catalysis to pyrrolidine ring conformation

Advanced Synthesis and Catalysis

Volumn 346, Issue 9-10, 2004, Pages 1111-1115

  Cheong, Paul Ha Yeon ^a   Houk, K N ^a   Warrier, Jayakumar S ^b   Hanessian, Stephen ^b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITÉ DE MONTRÉAL   (Canada)

Author keywords

Aldol; Asymmetric catalysis; Cyclization; Hybrid density functional theory; Organic catalysis; Proline

Indexed keywords

AMINE; PROLINE DERIVATIVE; PYRROLIDINE DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CONFORMATION; DENSITY FUNCTIONAL THEORY; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 5144225978     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/adsc.200404127     Document Type: Article

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43. σ.
44. C reflect the deviation from planarity of the iminium nitrogen and the carbon atoms.
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