Reality and future of rechargeable lithium batteries

Open Materials Science Journal

Volumn 5, Issue , 2011, Pages 204-214

  Tao, Haisheng ^a   Feng, Zhizhong ^a   Liu, Hao ^a   Kan, Xianwen ^a   Chen, P ^a  

^a UNIVERSITY OF WATERLOO   (Canada)

Author keywords

Anode; Cathode; Electrolyte; Rechargeable lithium battery; Review; Separator

Indexed keywords

CYCLE LIVES; DEVELOPING TREND; HIGHER ENERGY DENSITY; RECHARGEABLE LITHIUM BATTERY; SELF-DISCHARGES; SEPARATOR MATERIAL;

ANODES; CATHODES; ELECTROLYTES; LITHIUM BATTERIES; REVIEWS; SEPARATION; SEPARATORS;

LITHIUM;

EID: 84862968292     PISSN: None     EISSN: 1874088X     Source Type: Journal    
DOI: 10.2174/1874088X01105010204     Document Type: Article

References (150)

1. Howell D, Progress Report for Energy Storage Research and Development. U. S. Department of Energy 2009
2. Tarascon J-M, Armand M. Issues and challenges facing rechargeable lithium batteries. Nature 2001; 414: 359-67
3. Arico AS, Bruce P, Scrosati B, Tarascon JM, Van Schalkwijk W. Nanostructured materials for advanced energy conversion and storage devices. Nat Mater 2005; 4 (5): 366-77
4. Tollefson J. Charging up the future. Nature 2008; 456: 436-40
5. Thomas M, David WIF, Goodenough JB, Groves P. Synthesis andstructural characterization of the normal spinel LiNi2O4. Mater Res Bull 1985; 20 (10): 1137-46
6. Dahn JR, Vonsacken U, Michal CA. Structure and electrochemistryof Li1yNiO2 and a new Li2NiO2 phase with the Ni(OH)2 structure. Solid State Ionics 1990; 44 (1-2), 87-9
7. Dahn JR, Vonsacken U, Juzkow MW, Aljanaby H. RechargeableLiNiO2 carbon cells. J Electrochem Soc 1991; 138 (8): 2207-11.
8. Plichta E, Salomon M, Slane S, et al. A rechargeable Li/LixCoO2cell. J Power Sources 1987; 21: 25-31
9. Wang F, Yang J, NuLi YN, Wang JL. Highly promotedelectrochemical performance of 5 V LiCoPO4 cathode material by addition of vanadium. J Power Sources 2010; 195 (19): 6884-7
10. Ohzuku T, Yanagawa T, Kouguchi M, Ueda A. Innovativeinsertion material of LiAl1/4Ni3/4O2 (R 3 m) for lithium-ion (shuttlecock) batteries. J Power Sources 1997; 68 (1): 131-4
11. Gao Y, Yakovleva MV, Ebner WB. Novel LiNi1-xTix/2Mgx/2O2compounds as cathode materials for safer lithium-ion batteries. Electrochem Solid State Lett 1998; 1: 117-9
12. Sun YK, Myung ST, Kim MH, Prakash J. Amine K, Synthesis andcharacterization of Li [(Ni0.8Co0.1Mn0.1)0.8 (Ni0.5Mn0.5) 0.2] O2 with the microscale core-shell structure as the positive electrode material for lithium batteries. J Am Chem Soc 2005; 127 (38): 13411-8
13. Sun YK, Myung ST, Park BC, Prakash J, Belharouak I, Amine KHigh-energy cathode material for long-life and safe lithium batteries. Nat Mater 2009; 8: 320-4
14. Guyomard D, Tarascon JM. Rechargeable Li1+xMn2O4/carbon cellswith a new electrolyte- composition-potentiostatic studies and application to practical cells. J Electrochem Soc 1993; 140 (11): 3071-81
15. Tarascon JM, Wang E, Shokoohi FK, McKinnon WR, Colson SThe spinel phase of LiMn2O4 as a cathode in secondary lithium cells. J Electrochem Soc 1991; 138 (10): 2859-64
16. Tarascon JM, Guyomard D. Li metal-free rechargeable batteriesbased on Li1+XMn2O4 cathodes (0 x 1) and carbon anodes. J Electrochem Soc 1991; 138 (10): 2864-8
17. Gummow RJ, Liles DC, Thackeray MM. Lithium extraction fromorthorhombic lithium manganese oxide and the phase transformation to spinel. Mat Res Bull 1993; 28: 1249-56
18. Armstrong AR, Bruce PG. Synthesis of layered LiMnO2 as anelectrode for rechargeable lithium batteries. Nature 1996; 381 (6582): 499-500
19. Cho J, Park B. Li2+xMn0.91Cr1.09O4 cathode materials for Li-ioncells. Electrochem Solid State Lett 2000; 3 (8): 355-8
20. Davidson IJ, McMillan RS, Slegr H, et al. Electrochemistry andstructure of Li2-xCryMn2-yO4 phases. J Power Sources 1999; 81: 406-11
21. Dahn JR, Zheng T, Thomas CL. Structure and electrochemistry ofLi2CrxMn2-xO4 for 1.0 x 1.5. J Electrochem Soc 1998; 145 (3): 851-9
22. Jang YI, Huang BY, Chiang YM, Sadowa DR. Stabilization ofLiMnO2 in the -NaFeO2 structure type by LiAlO2 addition. Electrochem Solid State Lett 1998; 1:13-6
23. Thackeray MM. Manganese oxides for lithium batteries. Prog SolidState Chem 1997; 25 (1-2): 1-71
24. Yuan AB, Tian L, Xu WM, Wang YQ. Al-doped spinelLiAl0.1Mn1.9O4 with improved high-rate cyclability in aqueous electrolyte. J Power Sources 2010; 195 (15): 5032-8
25. Amatucci G, Du Pasquier A, Blyr A, Zheng T, Tarascon JM. Theelevated temperature performance of the LiMn2O4/C system: Failure and solutions. Electrochim Acta 1999; 45 (1-2): 255-71
26. Amatucci GG, Pereira N, Zheng T, Tarascon JM. Failuremechanism and improvement of the elevated temperature cycling of LiMn2O4 compounds through the use of the LiAlxMn2-xO4-zFz solid solution. J Electrochem Soc 2001; 148 (2): A171-82
27. Amatucci GG, Blyr A, Sigala C, Alfonse P, Tarascon JM. Surfacetreatments of Li1+xMn2-xO4 spinels for improved elevated temperature performance. Solid State Ionics 1997; 104 (1-2): 13-25
28. Wang EI, Mass M. Methode of Treating Lithium Manganese OxideSpinel. US5783328, July 21, 1998
29. Padhi AK, Nanjundaswamy KS, Goodenough JB. Phospho-olivinesas positive-electrode materials for rechargeable lithium batteries. J Electrochem Soc 1997; 144 (4): 1188-94.
30. Goodenough JB, Padhi AK, Nanjundaswamy KS, Masquelier CCathode materials for secondary (rechargeable) lithium batteries. US5910382, June 8, 1999
31. Herle PS, Ellis B, Coombs N, Nazar LF. Nano-network electronicconduction in iron and nickel olivine phosphates. Nat Mater 2004;3 (3): 147-52
32. Wang YG, Wang YR, Hosono E, Wang KX, Zhou HS. The designof a LiFePO4/Carbon nanocomposite with a core-shell structure and its synthesis by an in situ polymerization restriction method. Angew Chem Int Ed 2008; 47: 7461-5
33. Ravet N, Abouimrane A, Armand M. From our readers. Nat Mater2003; 2: 702
34. Sun YK, Oh SM, Myung ST, Amine K, Scrosati B,. 15thInternational Meeting on Lithium Batteries; July 2010; Montréal, Québec, Canada; 1010
35. Chung SY, Bloking JT, Chiang YM. Electronically conductivephospho-olivines as lithium storage electrodes. Nat Mater 2002; 1(2): 123-8
36. Guo YG, Hu JS, Wan LJ. Nanostructured materials forelectrochemical energy conversion and storage devices. Adv Mater 2008; 20 (15): 2878-87
37. Wu SH, Chen MS,. 15th International Meeting on LithiumBatteries; July 2010; Montréal, Québec, Canada; 1010
38. Chang ZR, Lv HJ, Tang H, Yuan XZ, Wang HJ. Synthesis andperformance of high tap density LiFePO4/C cathode materials doped with copper ions. J Alloys Compd 2010; 501 (1): 14-7
39. Nishimura S, Kobayashi G, Ohoyama K, Kanno R, Yashima M, Yamada A,. Experimental visualization of lithium diffusion in LixFePO4. Nat Mater 2008; 7 (9): 707-11
40. Ravet N, Chouinard Y, Magnan JF, Besner S, Gauthier M, Armand M. Electroactivity of natural and synthetic triphylite. J Power Sources 2001; 97-8: 503-7
41. Delacourt C, Poizot P, Levasseur S, Masquelier C. Size effects oncarbon-free LiFePO4 powders. Electrochem Solid State Lett 2006;9 (7): A352-5
42. Kim DH, Kim J. Synthesis of LiFePO4 nanoparticles in polyolmedium and their electrochemical properties. Electrochem Solid State Lett 2006; 9 (9): A439-42
43. Kang B, Ceder G. Battery materials for ultrafast charging anddischarging. Nature 2009; 458: 190-3
44. Recham N, Chotard JN, Dupont L, et al. A 3.6 V lithium-basedfluorosulphate insertion positive electrode for lithium-ion batteries. Nat Mater 2010; 9 (1): 68-74
45. Kolosnitsyn VS, Kuzmina EV, Karaseva EV,. 15th InternationalMeeting on Lithium Batteries; July 2010; Montréal, Québec, Canada; 1010
46. Ji XL, Lee KT, Nazar LF. A highly ordered nanostructured carbon-sulphur cathode for lithium- sulphur batteries. Nat Mater 2009; 8: 500-6
47. Liang CD, Dudney NJ, Howe JY. Hierarchically structuredsulfur/Carbon nanocomposite material for high-energy lithium battery. Chem Mater 2009; 21: 4724-30
48. Hayashi A, Ohtsubo R, Ohtomo T, Mizuno F, Tatsumisago M. All-solid-state rechargeable lithium batteries with Li2S as a positive electrode material. J Power Sources 2008; 183 (1): 422-6
49. Zhou YN, Wu CL, Zhang H, Wu XJ, Fu ZW. Electrochemicalreactivity of Co-Li2S nanocomposite for lithium-ion batteries. Electrochim Acta 2007; 52 (9): 3130-6
50. Obrovac MN, Dahn JR. Electrochemically active lithia/metal andlithium sulfide/metal composites. Electrochem Solid State Lett 2002; 5 (4): A70-3
51. Yang Y, McDowell MT, Jackson A, Cha JJ, Hong SS, Cui Y. Newnanostructured Li2S/silicon rechargeable battery with high specific energy. Nano Lett 2010;10: 1486-91
52. Chu MY. Rechargeable Positive Electrodes. US5686201,November 11, 1997
53. Visco SJ, Katz BD, Nimon YS, Jonghe LCD. Protected activemetal electrode and battery cell structures with non-aqueous interplayer architecture. US2008/0038641A1, February 14, 2008.
54. Skotheim TA, Sheehan CJ, Mikhaylik YV, Affinito J. Lithiumanodes for electrochemical cells. US7247408B2, June 24, 2007.
55. Visco SJ, Nimon YS, Katz BD. Ionically conductive compositesfor protection of active metal anode. US2008/0057387A1, March 6, 2008
56. Bates JB, Protective lithium ion conducting ceramic coating forlithium metal anodes and associate method. US5314765, May 24, 1994
57. Visco SJ, Katz BD, Nimon YS, Jonghe LCD. Protected activemetal electrode and battery cell structures with non-aqueous interplayer architecture. US2008/0038641A1, February 14, 2008.
58. Visco SJ, Katz BD, Nimon YS, Jones PC. Protected active metalelectrode and battery cell structures with non-aqueous interplayer architecture. US7282295B2, October 16, 2007
59. Visco SJ, Nimon YS, Li/air non-aqueous batteries US2007/0117007A1, May 24, 2007
60. Yurity VM, Chariclea SK, Igor K, Cathie B. Separation ofelectrolytes. US2010/0129699A1, May 27, 2010
61. Shodai T, Okada S, Tobishima S, Yamabi I. Study of Li3-xMxN(M=Co, Ni or Cu) system for use as anode in lithium rechargeable cells. Solid State Ionics 1996; 86-88: 785-9
62. Besenhard JO, Yang J, Winter M. Will advanced lithium-alloyanodes have a chance in lithium-ion batteries? J Power Sources 1997; 68 (1): 87-90
63. Winter M, Besenhard JO, Spahr ME, Novak P. Insertion electrodematerials for rechargeable lithium batteries. Adv Mater 1998; 10(10): 725-63
64. Dahn JR, Zheng T, Liu YH, Xue JS. Mechanisms for lithiuminsertion in carbonaceous materials. Science 1995; 270 (5236): 590-3
65. Liu YH, Xue JS, Zheng T, Dahn JR. Mechanism of lithiuminsertion in hard carbons prepared by pyrolysis of epoxy resins. Carbon 1996; 34 (2): 193-200
66. Zhang M, Lei DN, Yin XM, et al. Magnetite/graphene composites:Microwave irradiation synthesis and enhanced cycling and rate performances for lithium ion batteries. J Mater Chem 2010; 20(26):5538-43
67. Winter M, Besenhard JO. Electrochemical lithiation of tin and tin-based intermetallics and composites. Electrochem Acta 1999; 45: 31-50
68. Anani A, Crouch-Baker S, Huggins RA. Kinetic andthermodynamic parameters of several binary lithium alloy negative electrode materials at ambient temperature. J Electrochem Soc 1987; 134: 3098-102
69. Boukamp BA, Lesh GC, Huggins RA. All-solid lithium electrodeswith mixed-conductor matrix. J Electrochem Soc 1981; 128 (4): 725-9
70. Wang JQ, Raistrick ID, Huggins RA. Behavior of some binarylithium alloys as negative electrodes in organic solvent-based electrolytes. J Electrochem Soc 1986; 133 (3): 457-60
71. Zhang SC, Fang Y, Xing YL, Jiang T, Sun MM,. 15th InternationalMeeting on Lithium Batteries; July 2010; Montréal, Québec, Canada; 1010
72. Mao O, Dunlap RA, Dahn JR. Mechanically alloyed Sn-Fe(-C)powders as anode materials for Liion batteries-I. The Sn2Fe-C system. J Electrochem Soc 1999, 146 (2), 405-13
73. Mao O, Dahn JR. Mechanically alloyed Sn-Fe(-C) powders asanode materials for Li-ion batteries-II. The SnFe system. J Electrochem Soc 1999; 146 (2): 414-22
74. Mao O, Dahn JR. Mechanically alloyed Sn-Fe(-C) powders asanode materials for Li-ion batteries-III. Sn2Fe: SnFe3C active/inactive composites. J Electrochem Soc 1999; 146 (2): 423-7
75. Beaulieu LY, Larcher D, Dunlap RA, Dahn JR. Reaction of Li withgrain-boundary atoms in nanostructured compounds. J Electrochem Soc 2000; 147 (9): 3206-12
76. Kepler KD, Vaughey JT, Thackeray MM. LixCu6Sn5 (0 13): Anintermetallic insertion electrode for rechargeable lithium batteries. Electrochem Solid State Lett 1999; 2 (7): 307-9
77. Idota Y, Kubota T, Matsufuji A, Maekawa Y, Miyasaka T. Tin-based amorphous oxide: A high-capacity lithium-ion-storage material. Science 1997; 276 (5317): 1395-7
78. Courtney IA, Dahn JR. Electrochemical and in situ x-raydiffraction studies of the reaction of lithium with tin oxide composites. J Electrochem Soc 1997; 144 (6): 2045-52
79. Park MS, Kim JH, Kang YM,. 15th International Meeting onLithium Batteries; July 2010; Montréal, Québec, Canada; 1010.
80. http://www.sony.net/SonyInfo/News/Press/200502/05-006E/.
81. Todd ADW, Mar RE, Dahn JR. Tin-transition metal-carbonsystems for lithium-ion battery negative electrodes. J Electrochem Soc 2007; 154 (6): A597-604.
82. Ferguson PP, Todd ADW, Dahn JR. Comparison of mechanicallyalloyed and sputtered tin-cobalt- carbon as an anode material for lithium-ion batteries. Electrochem Commun 2008; 10 (1): 25-31.
83. Ferguson PP, Dahn JR. Effect of annealing on Sn30Co30C40prepared by mechanical attriting. Electrochem Solid State Lett 2008; 11 (11): A187-9
84. Ferguson PP, Martine ML, George AE, Dahn JR. Studies of tin-transition metal-carbon and tin- cobalt-transition metal-carbon negative electrode materials prepared by mechanical attrition. J Power Sources 2009; 194 (2): 794-800
85. Lazzari M, Scrosati B. Rechargeable lithium batteries with non-metal electrodes. US4464447, August 7, 1984
86. Idota Y. Nonaqueous Secondary battery. US5478671, December26, 1995
87. Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon JM. Nano-sized transition-metaloxides as negative-electrode materials for lithium-ion batteries. Nature 2000; 407 (6803): 496-9
88. Kavan L, Gratzel M. Facile synthesis of nanocrystalline Li4Ti5O12(spinel) exhibiting fast Li insertion. Electrochem Solid State Lett 2002; 5 (2): A39-42
89. Ohzuku T, Ueda A, Yamamoto N. Zero-strain insertion material ofLi [Li1/3Ti5/3]O4 for rechargeable lithium cells. J Electrochem Soc 1995; 142 (5): 1431-5
90. Wen CJ, Huggins RA. Chemical diffusion in intermediate phases inthe lithium-silicon system. J Solid State Chem 1981; 37 (3): 271-8.
91. Loveridge M, Lain M, Liu FM, Coowar F, Macklin B, Green M15th International Meeting on Lithium Batteries; July 2010; Montréal, Québec, Canada; 1010
92. Green M, Fielder E, Scrosati B, Wachtler M, Moreno JSStructured silicon anodes for lithium battery applications. Electrochem Solid State Lett 2003; 6 (5): A75-9
93. Li H, Huang XJ, Chen LQ, Wu ZG, Liang Y. A high capacitynano-Si composite anode material for lithium rechargeable batteries. Electrochem Solid State Lett 1999; 2 (11): 547-9
94. Graetz J, Ahn CC, Yazami R, Fultz B. Highly reversible lithiumstorage in nanostructured silicon. Electrochem Solid State Lett 2003; 6 (9): A194-7
95. Kasavajjula U, Wang CS, Appleby AJ. Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells. J Power Sources 2007; 163 (2): 1003-39
96. Park MH, Kim MG, Joo J, et al. Silicon nanotube battery anodesNano Lett 2009; 9 (11): 3844-7
97. Cui LF, Yang Y, Hsu CM, Cui Y. Carbon-silicon core-shellnanowires as high capacity electrode for lithium ion batteries. Nano Lett 2009; 9 (9): 3370-4
98. Chan CK, Ruffo R, Hong SS, Huggins RA, Cui Y. Structural andelectrochemical study of the reaction of lithium with silicon nanowires. J Power Sources 2009; 189 (1): 34-9
99. Chan CK, Ruffo R, Hong SS, Cui Y. Surface chemistry andmorphology of the solid electrolyte interphase on silicon nanowire lithium-ion battery anodes. J Power Sources 2009; 189 (2): 1132-40
100. Cui LF, Ruffo R, Chan CK, Peng HL, Cui Y. Crystalline-amorphous core-shell silicon nanowires for high capacity and high current battery electrodes. Nano Lett 2009; 9 (1): 491-5
101. Chan CK, Peng HL, Liu G, et al. High-performance lithium batteryanodes using silicon nanowires. Nat Nanotechnol 2008; 3 (1): 31-5.
102. Ruffo R, Hong SS, Chan CK, Huggins RA, Cui Y. Impedanceanalysis of silicon nanowire lithium ion battery anodes. J Phys Chem C 2009; 113 (26): 11390-8
103. Magasinski A, Dixon P, Hertzberg B, Kvit A, Ayala J, Yushin GHigh-performance lithium-ion anodes using a hierarchical bottom- up approach. Nat Mater 2010; 9 (4): 353-8
104. Magasinski A, Hertzberg B, Dixon P, Yushin G,. 15th InternationalMeeting on Lithium Batteries; July 2010; Montréal, Québec, Canada; 1010
105. Tarascon JM, Guyomard D. New electrolyte compositions stableover the 0-V to 5-V voltage range and compatible with the Li1+xMn2O4 Carbon Li-ion cells. Solid State Ionics 1994; 69 (3-4): 293-305
106. Ding MS, Xu K, Zhang SS, Amine K, Henriksen GL, Jow TRChange of conductivity with salt content, solvent composition, and temperature for electrolytes of LiPF6 in ethylene carbonate-ethyl methyl carbonate. J Electrochem Soc 2001; 148 (10): A1196-204
107. Guyomard D, Tarascon JM. Li matal-free rechargeable LiMn2O4/Carbon cells-Their understanding and optimization. JElectrochem Soc 1992; 139 (4): 937-48
108. Guyomard D, Tarascon JM. High-voltage stable liquid electrolytesfor Li1+XMn2O4 /Carbon rocking- chair lithium batteries. J Power Sources 1995; 54 (1): 92-8
109. Oh B, Rempel J, Ofer D, Sriramulu S, Barnett B. 15th InternationalMeeting on Lithium Batteries; July 2010; Montréal, Québec, Canada; 1010
110. Liu ZQ, Huang FQ, Yang JH, Wang BF, Sun JK. New lithium ionconductor, thio-LISICON lithium zirconium sulfide system. Solid State Ionics 2008; 179: 1714-6
111. Sakaebe H, Matsumoto H. N-methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl) imide (PP13-TFSI)-novel electrolyte base for Li battery. Electrochem Commun 2003; 5: 594-8
112. Nakagawa H, Izuchi S, Kuwana K, Nukuda T, Aihara Y. Liquidand polymer gel electrolytes for lithium batteries composed of room-temperature molten salt doped by lithium salt. J Electrochem Soc 2003; 150: A695-700
113. Ishikawa M, Yamagata M. 15th International Meeting on LithiumBatteries; July 2010; Montréal, Québec, Canada 1010
114. Holzapfel M, Jost C, Novak P. Stable cycling of graphite in anionic liquid based electrolyte. Chem Comm 2004; 18: 2098-9.
115. Carlin RT, Fuller J, Hedenskoog M. Reversible lithium-graphiteanodes in room-temperature chloroaluminate melts. J Electrochem Soc 1994; 141: L21-2
116. Fuller J, Osteryoung RA, Carlin RT. Rechargeable lithium andsodium anodes in chloroaluminate molten-salts containing thionyl chloride. J Electrochem Soc 1995; 142: 3632-6
117. Fuller J, Carlin RT, Osteryoung RA. The room temperaturei liquid1-ethyl-3-methylimidazolium tetrafluoroborate: Electrochemical couples and physical properties. J Electrochem Soc 1997; 144: 3881-6
118. Katayama Y, Yukumoto M, Miura T. Electrochemical intercalationof lithium into graphite in room- temperature molten salt containing ethylene carbonate. Electrochem Solid-State Lett 2003; 6: A96-7
119. Holzapfel M, Jostb C, Novak P. Stable cycling of graphite in anionic liquid based electrolyte. Chem Commun 2004; 2098-9.
120. Appetecchi GB, Kim GT, Montanina M, et al. Ternary polymerelectrolytes containing pyrrolidinium-based polymeric ionic liquids for lithium batteries. J Power Sources 2010; 195 (11): 3668-75
121. Lewandowski A, Swiderska-Mocek A. Ionic liquids as electrolytesfor Li-ion batteries-An overview of electrochemical studies. J Power Sources 2009; 194 (2): 601-9
122. Stallworth PE, Fontanella JJ, Wintersgill MC, et al. NMR, DSCand high pressure electrical conductivity studies of liquid and hybrid electrolytes. J Power Sources 1999; 81: 739-47
123. Angell CA, Liu C, Sanchez E. Rubbery solid electrolytes withdominant cationic transport and high ambient conductivity. Nature 1993; 362 (6416): 137-9
124. Croce F, Appetecchi GB, Persi L, Scrosati B. Nanocompositepolymer electrolytes for lithium batteries. Nature 1998; 394 (6692): 456-8
125. MacFarlane DR, Huang JH, Forsyth M. Lithium-doped plasticcrystal electrolytes exhibiting fast ion conduction for secondary batteries. Nature 1999; 402 (6763): 792-4
126. Zhang JW, Huang XB, Wei H, Fu JW, Huang YW, Tang XZNovel PEO-based solid composite polymer electrolytes with inorganic-organic hybrid polyphosphazene microspheres as fillers. J Appl Electrochem 2010; 40 (8): 1475-81
127. Alpen UV, Bell MF, Wichelhaus W. Ionic conductivity ofLi14Zn(GeO4)4 (LISICON). Electrochim Acta 1978; 23: 1395-7.
128. Hong HYP. Crystal structure and ionic conductivity ofLi14Zn(GeO4)4 and other new Li+ superionic conductors. Mat Res Bull 1978; 13: 117-24
129. Murayama M, Sonoyama N, Yamada A, Kanno R. Material designof new lithium ionic conductor, thio-LISICON, in the Li2S-P2S5 system. Solid State Ionics 2004; 170 (3-4): 173-80
130. Kanno R, Hata T, Kawamoto Y, Irie M. Synthesis of a new lithiumionic conductor, thio-LISICON- lithium germanium sulfide system. Solid State Ionics 2000; 130 (1-2): 97-104
131. Hayashi A, Kitaura H, Ohtomo T, Hama S. Tatsumisago M, 15thInternational Meeting on Lithium Batteries; July 2010; Montréal, Québec, Canada; 1010. 214 The Open Materials Science Journal, 2011, Volume 5
132. Minami K, Mizuno F, Hayashi A, Tatsumisago M. Lithium ion conductivity of the Li2S-P2S5 glass- based electrolytes prepared bythe melt quenching method. Solid State Ionics 2007; 178 (11-12): 837-41
133. Trevey J, Jang JS, Jung YS, Stoldt CR, Lee SH. Glass-ceramic Li2S-P2S5 electrolytes prepared by a single step ball billing processand their application for all-solid-state lithium-ion batteries. Electrochem Commun 2009; 11 (9): 1830-3
134. Mizuno F, Hama S, Hayashi A, Tadanaga K, Minami T, Tatsumisago M. All solid-state lithium secondary batteries usinghigh lithium ion conducting Li2S-P2S5 glass-ceramics. Chem Lett 2002; 12: 1244-5
135. Hashimoto Y, Machida N, Shigematsu T. Preparation of Li4.4GexSi1-x alloys by mechanical milling process and theirproperties as anode materials in all-solid-state lithium batteries. Solid State Ionics 2004; 175 (1-4): 177-80
136. Takada K, Inada T, Kajiyama A, et al. Solid state batteries with sulfide-based solid electrolytes. Solid State Ionics 2004; 172 (1-4):25-30
137. Zhang SS. A review on the separators of liquid electrolyte Li-ion batteries. J Power Sources 2007; 164 (1): 351-64
138. Kim SS, Lim GBA, Alwattari AA, Wang YF, Lloyd DR. Microporous membrane formation via thermally-induced phase-separation. 5. Effect of diluent mobility and crystallization on the structure of isotactic polypropylene membranes. J Membr Sci 1991; 64 (1-2): 41-53
139. Vadalia HC, Lee HK, Myerson AS, Levon K. Thermally-induced phase-separation in ternary crystallizable polymer-solutions. JMembr Sci 1994; 89 (1-2): 37-50
140. Matsuyama H, Yuasa M, Kitamura Y, Teramoto M, Lloyd DR. Structure control of anisotropic and asymmetric polypropyleneTao et almembrane prepared by thermally induced phase separation. J Membr Sci 2000; 179 (1-2): 91-100
141. Venugopal G, Moore J, Howard J, Pendalwar S. Characterization of microporous separators for lithium-ion batteries. J PowerSources 1999; 77 (1): 34-41
142. Arora P, Zhang ZM. Battery separators. Chem Rev 2004; 104 (10): 4419-62
143. http://www.celgard.com/.
144. Chung YS, Yoo SH, Kim CK. Enhancement of meltdown temperature of the polyethylene lithiumion battery separator viasurface coating with polymers having high thermal resistance. Ind Eng Chem Res 2009; 48 (9): 4346-51
145. Yoo SH, Kim CK. Enhancement of the meltdown temperature of a lithium ion battery separator via a nanocomposite coating. Ind EngChem Res 2009; 48 (22): 9936-41
146. Cho TH, Tanaka M, Onishi H, et al. Silica-composite nonwoven separators for lithium-ion battery: Development andcharacterization. J Electrochem Soc 2008; 155 (9): A699-703.
147. Prosini PP, Villano P, Carewska M. A novel intrinsically porousseparator for self-standing lithiumion batteries. Electrochim Acta 2002; 48 (3): 227-33
148. Augustin S, Hennige V, Horpel G, Hying C. Ceramic but flexible: new ceramic membrane foils for fuel cells and batteriesDesalination 2002; 146 (1-3): 23-8
149. Hennige V, Hying C, Hörpel G. Pyrogenic oxidic powder, production thereof and use thereof in a separator forelectrochemical cell. US7759009B2, July 20, 2010
150. Kim M, Shon JY, Nho YC, Lee TW, Park JH. Positive effects of ebeam irradiation in inorganic particle based separators for lithiumion battery. J Electrochem Soc 2010; 157 (1): A31-4.