A theoretical study of cyclohexyne addition to carbonyl-Cα bonds: Allowed and forbidden electrocyclic and nonpericyclic ring-openings of strained cyclobutenes

Journal of Organic Chemistry

Volumn 77, Issue 11, 2012, Pages 4939-4948

  Sader, C Avery ^a   Houk, K N ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

[2 + 2] CYCLOADDITION; ALKOXIDES; ATOMIC CHARGE; C-C BONDS; COMPUTATIONAL RESULTS; CYCLIC KETONES; CYCLOBUTENE; ENOLATES; GASPHASE; GEOMETRICAL PARAMETERS; POTASSIUM ALKOXIDE; PRODUCT FORMS; RING OPENING; THEORETICAL STUDY; TRANSITION STRUCTURES;

BUTENES; DENSITY FUNCTIONAL THEORY; KETONES; POTASSIUM;

CHEMICAL BONDS;

ALCOHOL; ALKOXIDE; CARBONYL DERIVATIVE; CHEMICAL COMPOUND; CYCLOBUTENE ALKOXIDE; CYCLOBUTENE DERIVATIVE; CYCLOHEXANE; POTASSIUM ALKOXIDE; POTASSIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL MODIFICATION; CHEMICAL REACTION; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; ELECTROLYSIS; RING OPENING; THEORETICAL STUDY; THERMODYNAMICS;

CYCLOBUTANES; CYCLOHEXANES; KETONES; MODELS, THEORETICAL; MOLECULAR STRUCTURE; OXIDES; STEREOISOMERISM; THERMODYNAMICS;

EID: 84861800046     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo300314z     Document Type: Article

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