Determination of the extent of reduction of dense UO 2 cathodes from direct electrochemical reduction studies in molten chloride medium

Journal of Nuclear Materials

Volumn 427, Issue 1-3, 2012, Pages 200-208

  Sri Maha Vishnu, D ^a   Sanil, N ^a   Murugesan, N ^a   Shakila, L ^a   Ramesh, C ^a   Mohandas, K S ^a   Nagarajan, K ^a  

^a INDIRA GANDHI CENTRE FOR ATOMIC RESEARCH   (India)

Author keywords

[No Author keywords available]

Indexed keywords

AMPEROMETRIC; ELECTRO REDUCTION; ELECTROCHEMICAL REDUCTIONS; HYDROGEN SENSOR; METALLISATION; MOLTEN CHLORIDES; POLYMER ELECTROLYTE; SINTERED PELLETS;

CALCIUM CHLORIDE; CHLORINE COMPOUNDS; ELECTROLYTES; ELECTROLYTIC REDUCTION; HYDROGEN; URANIUM;

PELLETIZING;

EID: 84861552852     PISSN: 00223115     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jnucmat.2012.04.035     Document Type: Article

References (37)

1. G.Z. Chen, D.J. Fray, and T.W. Farthing Nature 407 2000 361 364
2. P.K. Tripathy, M. Gauthier, and D.J. Fray Metall. Mater. Trans. B 38B 2007 893 900
3. K.S. Mohandas, L. Shakila, N. Sanil, D. Sri Maha Vishnu, K. Nagarajan, Galvanostatic studies on the electro-deoxidation of solid titanium dioxide in molten calcium chloride, in: Fray International Symposium, Cancun, Mexico, 27 November-01 December, 2011.
4. G.Z. Chen, E. Gordo, and D.J. Fray Metall. Mater. Trans. B 35B 2004 223 233
5. X.Y. Yan, and D.J. Fray J. Appl. Electrochem. 39 2009 1349 1360
6. S.M. Jeong, H.Y. Yoo, J.-M. Hur, and C.S. Seo J. Alloys. Compd. 452 2008 27 31
7. D.S. Vishnu, N. Sanil, L. Shakila, K.S. Mohandas, K. Nagarajan, Galvanostatic electrodeoxidation of niobium pentoxide in molten calcium chloride medium, in: Proceedings of DAE-BRNS Third International Symposium on Materials Chemistry, Bhabha Atomic Research Centre, Trombay, Mumbai, December 7-11, 2010.
8. K.S. Mohandas, and D.J. Fray Metall. Mater. Trans. B 40B 2009 685 699
9. S.M. Jeong, J.Y. Jung, C.S. Seo, and S.W. Park J. Alloys. Compd. 440 2007 210 215
10. G. Li, D. Wang, and Z. Chen J. Mater. Sci. Technol. 25 6 2009 767 771
11. K. Yasuda, T. Nohira, R. Hagiwara, and Y.H. Ogata Electrochim. Acta 53 2007 106 110
12. M. Erdogan, and I. Karakaya Metall. Mater. Trans. B 41B 2010 798 804
13. K. Gourishankar, Redey, M. Williamson, Light metals, TMS (2002) 1075-1082.
14. S.D. Herrmann, S.X. Li, M.F. Simpson, and S. Phongikaroon Sep. Sci. Technol. 41 2006 1965 1983
15. S.M. Jeong, S.B. Park, S.S. Hong, C.S. Seo, and S.W. Park J. Radioanal. Nucl. Chem. 268 2006 349 356
16. Biju Joseph, N. Sanil, K.S. Mohandas, K. Nagarajan, Studies on the direct electrochemical reduction of solid uranium oxide in molten lithium chloride medium, NUCAR 2009, Mumbai, January 7-10, 2009.
17. Y. Sakamura, M. Kurata, and T. Inoue J. Electrochem. Soc. 153 3 2006 D31 D39
18. E.Y. Choi, J.M. Hur, I.K. Choi, S.G. Kwon, D.S. Kang, S.S. Hong, H.S. Shin, M.A. Yoo, and S.M. Jeong J. Nucl. Mater. 418 2011 87 92
19. J.M. Hur, C.S. Seo, I.S. Kim, S.S. Hong, D.S. Kang, S.W. Park, WM'03 Conference, Tucson, AZ, February 23-27, 2003.
20. M. Kurata, T. Inoue, J. Serp, M. Ougier, and J.P. Glatz J. Nucl. Mater. 328 2004 97 102
21. B.H. Park, I.W. Lee, and C.S. Seo Chem. Eng. Sci. 63 2008 3485 3492
22. J.M. Hur, I.K. Choi, S.H. Cho, S.M. Jeong, and C.S. Seo J. Alloys. Compd. 452 2008 23 26
23. S.M. Jeong, B.H. Park, J.M. Hur, C.S. Seo, H. Lee, and K.C. Song Nucl. Engg. Tech. 42 2 2010 183 192
24. S.M. Jeong, H.S. Shin, S.S. Hong, J.M. Hur, J.B. Do, and H.S. Lee Electrochim. Acta 55 2010 1749 1755
25. S. Herrmann, S. Li, and M. Simpson J. Nucl. Sci. Technol. 44 3 2007 361 367
26. M. Iizuka, T. Inoue, M. Ougier, and J.P. Glatz J. Nucl. Sci. Technol. 44 2007 801 813
27. M. Kurata, N. Yahagi, S. Kitawaki, A. Nakayoshi, and M. Fukushima Nucl. Technol. 164 2008 433 441
28. K.S. Mohandas, L. Shakila, N. Sanil, D. Sri Maha Vishnu, K. Nagarajan, Studies on the electrochemical deoxidation of uranium oxide in molten calcium chloride, in: Fray International Symposium, Cancun, Mexico, 27 November-01 December, 2011.
29. T. Koyama, T. Hijikata, T. Usami, T. Inoue, S. Kitawaki, T. Shinozaki, M. Fukushima, and M. Myochin J. Nucl. Sci. Technol. 44 3 2007 382 392
30. T. Usami, M. Kurata, T. Inoue, H.E. Sims, S.A. Beetham, and J.A. Jenkins J. Nucl. Mater. 300 2002 15 26
31. G.F. Brunzie, T.R. Johnson, and R.K. Steunenberg Anal. Chem. 33 8 1961 1005 1006
32. C. Ramesh, N. Murugesan, S. Velmurugan, A.A.M. Prince, V. Ganesan, S.V. Narasimhan, Indian Patent No. 204092.
33. C. Ramesh, N. Murugesan, A.A.M. Prince, S. Velmurugan, S.V. Narasimhan, and V. Ganesan Corros. Sci. 43 2001 1865 1875
34. C. Ramesh, N. Murugesan, M.V. Krishnaiah, V. Ganesan, and G. Periaswami J. Solid State Electrochem. 12 2008 1109 1116
35. N. Murugesan, D. Sri Maha Vishnu, N. Sanil, C. Ramesh, K. Nagarajan, V. Ganesan, A novel technique for estimation of uranium using proton exchange membrane based hydrogen sensor, Submitted to Anal. Chim. Acta.
36. J.M. Hur, S.M. Jeong, and H. Lee Electrochem. Commun. 12 2010 706 709
37. Y. Deng, D.H. Wang, W. Xiao, X.B. Jin, X.H. Hu, and G.Z. Chen J. Phy. Chem. B 109 29 2005 14043 14051