An unusal case of facile non-degenerate P-C bond making and breaking

Chemistry - An Asian Journal

Volumn 7, Issue 7, 2012, Pages 1708-1712

  Nesterov, Vitaly ^a   Özbolat Schön, Aysel ^a   Schnakenburg, Gregor ^a   Shi, Lili ^b   Cangönül, Asli ^b   Van Gastel, Maurice ^b   Neese, Frank ^b   Streubel, Rainer ^a  

^a UNIVERSITY OF BONN   (Germany)

^b MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

Author keywords

density functional calculations; EPR spectroscopy; one electron oxidation; radicals; tritylium

Indexed keywords

ATROPISOMERS; CARBON ATOMS; DFT CALCULATION; DIRADICALS; EPR SPECTROSCOPY; IN-SITU; LOW TEMPERATURES; MOLECULAR ENTITIES; ONE-ELECTRON OXIDATION; P-C BOND CLEAVAGE; RADICALS; RELATIVE ENERGIES; RELATIVE ORIENTATION; SINGLE CRYSTAL X-RAY ANALYSIS; TOLUENE SOLUTION; TRITYLIUM;

DENSITY FUNCTIONAL THEORY; ISOMERS; OXIDATION; TOLUENE;

REACTION INTERMEDIATES;

FREE RADICAL; LITHIUM; PHOSPHINE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ELECTRON; ELECTRON SPIN RESONANCE; ISOMERISM; OXIDATION REDUCTION REACTION; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONS; FREE RADICALS; ISOMERISM; LITHIUM; MODELS, MOLECULAR; OXIDATION-REDUCTION; PHOSPHINES;

EID: 84861180102     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.201200161     Document Type: Article

References (33)

1. S. Marque, P. Tordo, Top. Curr. Chem. 2005, 250, 43-76
2. D. Leca, L. Fensterbank, E. Lacôte, M. Malacria, Chem. Soc. Rev. 2005, 34, 858-865.
3. J. Conu, T. Chivers, in Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds, (Ed.:, R. Hicks,), Wiley, Chichester, 2010, pp. 381-406
4. J. W. Grate, G. C. Frye, in Sensors Update, Vol. 2 (Eds:, H. Baltes, W. Göpel, J. Hesse,), Wiley-VCH, Weinheim, 1996, pp. 10-20.
5. M. J. S. Gynane, A. Hudson, M. F. Lappert, P. P. Power, H. Goldwhite, J. Chem. Soc. Chem. Commun. 1976, 623-624
6. M. J. S. Gynane, A. Hudson, M. F. Lappert, P. P. Power, H. Goldwhite, J. Chem. Soc. Dalton Trans. 1980, 2428-2433
7. S. L. Hinchley, C. A. Morrison, D. W. H. Rankin, C. L. B. Macdonald, R. J. Wiacek, A. H. Cowley, M. F. Lappert, G. Gundersen, J. A. C. Clyburne, P. P. Power, J. Chem. Soc. Chem. Commun. 2000, 2045-2046
8. J.-P. Bezombes, K. B. Borisenko, P. B. Hitchcock, M. F. Lappert, J. E. Nycz, D. W. H. Rankin, H. E. Robertson, Dalton Trans. 2004, 1980-1988
9. O. Back, M. A. Celik, G. Frenking, M. Melaimi, B. Donadieu, G. Bertrand, J. Am. Chem. Soc. 2010, 132, 10262-10263
10. O. Back, B. Donnadieu, M. von Hopffgarten, S. Klein, R. Tonner, G. Frenking, G. Bertrand, Chem. Sci. 2011, 2, 858-861
11. S. Ishida, F. Hirakawa, T. Iwamoto, J. Am. Chem. Soc. 2011, 133, 12968-12971.
12. S. E. Vaillard, C. Mück-Lichtenfeld, S. Grimme, A. Studer, Angew. Chem. 2007, 119, 6653-6656
13. Angew. Chem. Int. Ed. 2007, 46, 6533-6536
14. A. Bruch, A. Ambrosius, R. Fröhlich, A. Studer, D. B. Guthrie, H. Zhang, D. P. Curran, J. Am. Chem. Soc. 2010, 132, 11452-11454.
15. B. M. Cossairt, C. Cummins, New J. Chem. 2010, 34, 1533-1536.
16. B. Cetinkaya, A. Hudson, M. F. Lappert, H. Goldwhite, J. Chem. Soc. Chem. Commun. 1982, 609-610
17. J. Geier, H. Rüegger, M. Wörle, H. Grützmacher, Angew. Chem. 2003, 115, 4081-4085
18. Angew. Chem. Int. Ed. 2003, 42, 3951-3954.
19. R. E. Bulo, H. Jansen, A. W. Ehlers, F. F. J. de Kanter, M. Schakel, M. Lutz, A. L. Spek, K. Lammertsma, Angew. Chem. 2004, 116, 732-735
20. Angew. Chem. Int. Ed. 2004, 43, 714-717.
21. B. Ndiaye, S. Bhat, A. Jouaiti, T. Berclaz, G. Bernardinelli, M. Geoffroy, J. Phys. Chem. A 2006, 110, 9736-9742
22. A. H. Cowley, R. A. Kemp, J. C. Wilburn, J. Am. Chem. Soc. 1982, 104, 332-334.
23. A. Özbolat-Schön, M. Bode, G. Schnakenburg, A. Anoop, M. van Gastel, F. Neese, R. Streubel, Angew. Chem. 2010, 122, 7047-7051
24. Angew. Chem. Int. Ed. 2010, 49, 6894-6898.
25. A. Özbolat, G. von Frantzius, J. Marinas Pérez, M. Nieger, R. Streubel, Angew. Chem. 2007, 119, 9488-9491
26. Angew. Chem. Int. Ed. 2007, 46, 9327-9330
27. M. Bode, J. Daniels, R. Streubel, Organometallics 2009, 28, 4636-4638.
28. A. Özbolat, G. von Frantzius, W. Hoffbauer, R. Streubel, Dalton Trans. 2008, 2674-2676.
29. N. G. Connelly, W. E. Geiger, Chem. Rev. 1996, 96, 877-910
30. F. Neese, ORCA-An ab initio, DFT and semiempirical SCF-MO package, version 2.8r2556, Bonn, Germany, University of Bonn, 2010.
31. 2P:, S. L. Hinchley, C. A. Morrison, D. W. H. Rankin, C. L. B. Macdonald, R. J. Wiacek, A. Voigt, A. H. Cowley, M. F. Lappert, G. Gundersen, J. A. C. Clyburne, P. P. Power, J. Am. Chem. Soc. 2001, 123, 9045-9053
32. in oxaphosphirane complexes:, J. M. Pérez, M. Klein, A. Kyri, G. Schnakenburg, R. Streubel, Organometallics 2011, 30, 5636-5640.
33. H. Kurreck, B. Kirste, W. Lubitz, Electron Nuclear Double Resonance Spectroscopy of Radicals in Solution, VCH Pulblishers, Deerfield Beach, Florida, 1988.