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Volumn 49, Issue 38, 2010, Pages 6894-6898

Insights into the chemistry of transient P-chlorophosphanyl complexes

Author keywords

Epr spectroscopy; Phosphanyl complexes; Phosphaquinomethane phosphinidenoid complexes tritylium salts

Indexed keywords

CROSS-COUPLINGS; DFT CALCULATION; EPR SPECTROSCOPY; ESR SPECTROSCOPY; ONE-ELECTRON OXIDATION; PHOSPHANYL COMPLEXES; PHOSPHAQUINOMETHANE PHOSPHINIDENOID COMPLEXES TRITYLIUM SALTS;

EID: 77956562903     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201002885     Document Type: Article
Times cited : (30)

References (43)
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    • Reduction of dihalo(organo)phosphanes might yield F-functionalized phosphanyl radicals as transient species, but only subsequently formed products have been unambigously identified to date; see for example
    • Reduction of dihalo(organo)phosphanes might yield F-functionalized phosphanyl radicals as transient species, but only subsequently formed products have been unambigously identified to date; see for example: J. Geier, H. Rüegger, M. Wörle, H. Grützmacher, Angew. Chem. 2003, 115, 4081-4085;
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    • and references therein.
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    • C. Albrecht, M. Rode, J. M. Pérez, G. Schnakenburg, R. Streubel, unpublished results
    • C. Albrecht, M. Rode, J. M. Pérez, G. Schnakenburg, R. Streubel, unpublished results.
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    • 37Q isotopomers, thus indicating a phosphorus-chlorine bond.
    • 37Q isotopomers, thus indicating a phosphorus-chlorine bond.
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    • 3- based on the crystal structures. All the calculations were performed using the ORCA Program package (F. Neese, University of Ronn, 2010) and employ the BP functional and a TZVP basis set within a spin-unrestricted Kohn-Sham formalism.
    • 3- based on the crystal structures. All the calculations were performed using the ORCA Program package (F. Neese, University of Ronn, 2010) and employ the BP functional and a TZVP basis set within a spin-unrestricted Kohn-Sham formalism.
  • 41
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    • The term spin-density distribution refers to the spin density as a function of three-dimensional space, as depicted in Figure 5. The term (Mulliken) spin population refers to its coefficients; for example, in case of 3a, the unpaired electron resides up to 87 % at a P(3p) orbital.
    • The term spin-density distribution refers to the spin density as a function of three-dimensional space, as depicted in Figure 5. The term (Mulliken) spin population refers to its coefficients; for example, in case of 3a, the unpaired electron resides up to 87 % at a P(3p) orbital.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.