Relationship between copper species in solution and leaching from alkaline copper quat (ACQ) treated wood

Holzforschung

Volumn 66, Issue 4, 2012, Pages 505-514

  Pankras, Sedric ^a   Cooper, Paul A ^a   Wylie, Stephen ^b  

^a UNIVERSITY OF TORONTO   (Canada)

^b RYERSON UNIVERSITY   (Canada)

Author keywords

ACQ; Alkaline copper quat; Copper amine; Copper complexes; Copper leaching; Copper speciation; MINTEQA2; Monoethanolamine (Mea); Wood preservative

Indexed keywords

ACQ; ALKALINE COPPER QUAT; COPPER COMPLEXES; COPPER LEACHING; MINTEQA2; MONOETHANOLAMINE; WOOD PRESERVATIVES;

COMPLEXATION; COPPER; LEACHING; PH EFFECTS; PROTECTIVE COATINGS; WOOD PRESERVATION;

COPPER COMPOUNDS;

PINUS ECHINATA;

EID: 84861059897     PISSN: 00183830     EISSN: 1437434X     Source Type: Journal    
DOI: 10.1515/HF.2011.179     Document Type: Article

References (48)

1. American Wood Protection Association (AWPA) Standard P5-06. Standards for waterborne preservatives. AWPA, Birmingham, AL, 2006a.
2. American Wood Protection Association (AWPA) Standard A7-04. Standard wet ashing procedure for preparing wood for chemical analysis. AWPA, Birmingham, AL, 2006b.
3. Barnes, H.M., Lindsey, G.B., Hill, J.M. (2009) Effect of copper xyligen treatment on bending properties of wood. Holzforschung 63:254-256.
4. Caruso, B.S., Cox, T.J., Runkel, R.L., Velleux, M.L., Bencala, K.E., Nordstrom, D.K., Julien, P.Y., Butler, B.A., Alpers, C.N., Marion, A., Smith, K.S. (2008) Metals fate and transport modeling in streams and watersheds: state of the science and USEPA workshop review. Hydrol. Process. 22:4011-4021.
5. Cooper, P.A. (1991) Cation exchange adsorption of copper on wood. Wood Protect. 1:9-14.
6. Cooper, P.A. (1998) Diffusion of copper in wood cell walls following vacuum treatment. Wood Fiber Sci. 30:382-395.
7. Crabtree, R.H. The organometallic chemistry of the transition metals, 2nd edition. Wiley Interscience, New York, 1994.
8. Davis, C.W., Patel, B.N. (1968) Complexes of the cupric ion with mono-, di- and tri-ethanolamine. J. Chem. Soc. A. 1824-1828.
9. Djurdjevic, P., Bjerrum, J. (1983) Metal amine formation in solution. XXIV. The copper (II)-and some other metal (II) - mono and diethanolamine systems. Acta Chem. Scand. Ser. A. 37:881-890.
10. Doyle, A.K., Ruddick, J.N.R. (1994) The microdistribution of alkylammonium compounds in ponderosa pine sapwood. Holzforschung 48:106-112.
11. Fisher, J.F., Hall, J.L. (1967) Polarographic study of complexes of copper (II) ion with ammonia and various ethyl, ethanol, and ethylethanolamines. Anal. Chem. 39:1550-1556.
12. Flannery, R.L., Ke, B., Grieb, M.W., Trivich, D. (1955) Polarographic study of copper (II) complexes with ethanolamine and some derivatives. J. Am. Chem. Soc. 77:2996-2998.
13. Hancock, R.D. (1981) The chelate effect in complexes with ethanolamine. Inorg. Chim. Acta. 49:145-148.
14. Humar, M., Pohleven, F., Sentjurc, M., Veber, M., Razpontnik, P., Pogni, R., Petric, M. (2003) Performance of waterborne Cu(II) octanoate-ethanolamine wood preservatives. Holzforschung 57:127-134.
15. Humar, M., Kalan, P., Sentjurc, M., Pohleven, F. (2005) Influence of carboxylic acids on fixation of copper in wood impregnated with copper amine preservatives. Wood Sci. Technol. 39:685-693.
16. Jiang, X., Ruddick, J.N.R. A comparison of the leaching resistance of copper 2 ethanolamine and copper ethylenediamine treated Scots pine. Doc. no. IRG-WP-00-30233. International Research Group on Wood Preservation (IRG), Stockholm, Sweden, 2000.
17. Jin, L., Preston, A.F. Depletion of preservatives from treated wood: results from laboratory, fungus cellar and field tests. Doc. no. IRG-WP 93-50001. International Research Group on Wood Preservation (IRG), Stockholm, Sweden, 1993.
18. Kamdem, D.P., Zhang, J. Contribution of wood components on the absorption of copper amine. Doc. no. IRG-WP-00-30216. International Research Group on Wood Preservation (IRG), Stockholm, Sweden, 2000.
19. Laux, N.T. Modeling monomethylmercury and tributyltin speciation with EPA's Geochemical speciation model MINTEQA2. Document: EPA/600/R-05/063. Environmental Protection Agency (EPA), Ecosystem Research Division, Athens, Georgia, 2005.
20. Lee, M.J., Cooper, P. (2010) Effect of amine ligand, copper/amine ratio, and pH on copper adsorption into wood. Holzforschung 64:659-665.
21. Lee, M.J., Cooper, P. (2011) Effects of ionic strength, monoethanolamine, copper, and pH on adsorption of alkyl dimethyl benzyl ammonium chloride in wood. Holzforschung 65:421-427.
22. Loubinoux, B., Malek, H. (1992) Interaction of quaternary ammonium salts with wood. 1. Fixation of benzalkonium bromide and chloride. Holzforschung 46:537-539.
23. Lucas, N., Ruddick, J.N.R. Determination of the amine to copper ratio remaining in wood after water leaching. Doc. no. IRG/WP 02-30285. International Research Group on Wood Preservation (IRG), Stockholm, Sweden, 2002.
24. Martell, A.E., Hancock, R.D. Metal Complexes in Aqueous Solutions. Modern inorganic chemistry series. Plenum Press, New York and London, 1996.
25. Micera, G., Deiana, S., Dessi, A., Decock, P., Dubois, B., Kozlowski, H. (1985) Copper(II) complexation by D-glucosamine. Spectroscopic and potentiometric studies. Inorg. Chim. Acta. 107:45-48.
26. Miyauchi, T., Mori, M. (2007) Improved quantitative determination of benzalkonium chloride in treated wood by liquid chromatography. Holzforschung 61:337-341.
27. NIST (National Institute of Standards and Technology) Standard Reference Database 46. NIST Critically selected stability constants of metal complexes. NIST, Gaithersburg, MD, 2004.
28. Paleshenko, V.I., Osadchi, V.I., Kirnichni, V.V. (1994) Mathematical modeling of metal speciation in natural waters. In: Hydrological, chemical and biological processes of transformation and transport of contaminants in aquatic environments. Proceedings of the Rostov on Don Symposium, May 1993. International Association of Hydrological Sciences (IAHS) publication number 219. IAHS Press, Wallingford, Oxfordshire.
29. Perrin, D.D. Stability Constants of Metal-Ion Complexes, Part B. Organic ligands. Pergamon Press, Oxford and New York, 1979.
30. Robinson, S.C., Laks, P.E. (2010) The effects of subthreshold loadings of tebuconazole, DDAC, and boric acid on wood decay by Postia placenta . Holzforschung 64:537-543.
31. Ruddick, J.N.R. (1996) The fixation chemistry of ammoniacal copper wood preservatives. Proc. Am. Wood Preserv. Assoc. 92:32-49.
32. Schultz, T.P., Nicholas, D.D. (2010) A proposed accelerated field stake test for rapid assessment of wood preservative systems. Holzforschung 64:673-679.
33. Sillen, L.G., Martell, A. Stability Constants of Metal-Ion Complexes. Chemical Society, London, 1971.
34. Smith, R.M., Martell, A. Critical Stability Constants, Volume 4: Inorganic complexes. Plenum Press, New York, 1976.
35. Srinivasan, K., Subramanya, R.S. (1971) Polarographic and redox potential studies on copper (I) and copper (II) and their complexes. Part II. Copper (I and II)-mono, di- and triethanolamine complexes. J. Electroanal. Chem. 31:245-256.
36. Sturrock, P.E. (1963) A polarographic study of the copper (II) complexes of mono-, di-, and triethanolamine. Anal. Chem. 35:1092.
37. Tascioglu, C., Cooper, P.A., Ung, Y.T. (2005) Rate and extent of adsorption of ACQ preservative components in wood. Holzforschung 59:574-580.
38. Tascioglu, C., Cooper, P., Ung, Y.T. (2008) Effect of fixation temperature and environment on copper speciation. Holzforschung 62:289-293.
39. Tascioglu, C., Tsunoda, K. (2010) Biological performance of copper azole-treated wood and wood-based composites. Holzforschung 64:399-406.
40. Tauler, R., Casassas, E., Rode, B.M. (1986) The complex formation of Cu (II) with mono- and-di ethanolamine in aqueous solution. Inorg. Chim. Acta. 114:203-209.
41. Ung, Y.T., Cooper, P.A. (2005) Copper stabilization in ACQ-D treated wood: Retention, temperature and species effects. Holz. Roh. Werkst. 63:186-191.
42. Unsworth, E.R., Warnken, K.W., Zhang, H., Davison, W., Black, F., Buffle, J., Cao, J., Cleven, R., Galceren, J., Gunkel, P., Kallis, E., Kistler, D., van Leeuwen, H.P., Martin, M., Noel, S., Nur, Y., Odzak, N., Puy, J., Weaber, T., Toepperwien, S., Town, R.M., Weng, L., Xue, H. (2006) Model predictions of metal speciation in freshwaters compared to measurements in situ techniques. Environ. Sci. Technol. 40:1942-1949.
43. Waldron, L., Cooper, P.A., Ung, T.Y. (2005) Prediction of long-term leaching potential of preservative-treated wood by diffusion modeling. Holzforschung 59:581-588.
44. Xie, C., Ruddck, J.N.R., Retting, S.J., Herring, F.G. (1995) Fixation of ammoniacal copper preservatives: reaction of vanillin a lignin model compound with ammoniacal copper sulphate solution. Holzforschung 49:483-490.
45. Yu, L., Cao, J., Zhao, G. (2010) Tensile stress relaxation of wood impregnated with different ACQ formulations at various temperatures. Holzforschung 64:111-117.
46. Zhang, J., Kamdem, D.P. (2000a) Interaction of copper amine with southern yellow pinewood: Retention and Migration. Wood Fiber Sci. 32:332-339.
47. Zhang, J., Kamdem, D.P. (2000b) FTIR Characterization of copper ethanolamine-wood interaction for wood preservation. Holzforschung 54:119-122.
48. Zhang, J., Kamdem, D.P. (2000c) Electron paramagnetic resonance spectroscopic study of copper amine treated southern pine in wood preservation. Holzforschung 54:343-348.