Effect of amine ligand, copper/amine ratio, and pH on copper adsorption into wood

Holzforschung

Volumn 64, Issue 5, 2010, Pages 659-665

  Lee, Myung Jae ^a   Cooper, Paul ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

ammonia; cation exchange capacity; chemical adsorption capacity; chemisorption; copper amine; diethanolamine; ethylenediamine, monoethanolamine; triethanolamine; wood preservation

Indexed keywords

CATION EXCHANGE CAPACITY; CHEMICAL ADSORPTION CAPACITY; DIETHANOLAMINE; ETHYLENE DIAMINE; TRIETHANOLAMINES;

ADSORPTION; AMMONIA; CHEMISORPTION; COPPER; DELIGNIFICATION; ION EXCHANGERS; LIGANDS; ORGANIC COMPOUNDS; PHOTOELECTRIC DEVICES; POSITIVE IONS; WOOD PRESERVATION;

PH EFFECTS;

AMINES; AMMONIA; CATIONS; CHEMISORPTION; COPPER; DELIGNIFICATION; ETHYLENEDIAMINE; ION EXCHANGE; ION EXCHANGERS; LIGANDS; ORGANIC COMPOUNDS; PH; PHOTOELECTRIC EFFECTS; WOOD PRESERVATION;

PINUS RESINOSA;

EID: 77956197967     PISSN: 00183830     EISSN: 1437434X     Source Type: Journal    
DOI: 10.1515/HF.2010.077     Document Type: Article

References (30)

1. AWPA (2006) Standard A7-04, Standard for wet ashing procedures for preparing wood for chemical analysis. American Wood Protection Association, Birmingham, AL
2. AWPA (2006) Standard P5-06, Standard for waterborne preservatives. American Wood Protection Association, Birmingham, AL.
3. Aksu, S., Doyle, F.M. (2002) Electrochemistry of copper in aqueous ethylenediamine solutions. J. Electrochem. Soc. 149:B340-B347.
4. Bjerrum, J. (1957) Metal amine formation in aqueous solution: theory of the reversible step reactions. P. Haase, Copenhagen.
5. Casassas, E., Gustems, L.o.L., Tauler, R. (1989) Spetrophotometric study of complex formation in copper(II) mono-, di-, and tri-ethanolamine systems. J. Am. Chem. Soc. 569-573.
6. Cui, W., Girods, P., Jacqueson, A., Kamdem, D.P. (2005) Effect of the addition of ammonia in the retention and leaching of copper-amine-treated southern pine cubes. Forest Prod. J. 55:92-94.
7. Davies, C.W., Patel, B.N. (1968) Complexes of the cupric ion with mono-, di, and tri-ethanolamine. J. Chem. Soc. A. 1824-1828.
8. Fisher, J.F., Hall, J.L. (1962) A polarographic study of the copper (II) complexes of mono-, di-, and triethanolamine. Anal. Chem. 34:1094-1098.
9. Hancock, R.D. (1981) The chelate effect in complexes with etha-nolamine. Inorg. Chim. Acta 49:145-148.
10. Hughes, A.S., Murphy, R.J., Gibson, J.F., Cornfield, J.A. (1994) Electron paramagnetic resonance (EPR) spectroscopic analysis of copper based preservatives in Pinus sylvestris. Holzforschung 48:91-98.
11. Humar, M., Zlindra, D., Pohleven, F. (2007) Influence of wood species, treatment method and biocides concentration on leaching of copper-ethanolamine preservatives. Building Environ. 42: 578-583.
12. Inada, Y., Ozutsumi, K., Funahashi, S., Soyama, S., Kawashima, T., Tanaka, M. (1993) Structure of copper (II) ethylenediamine complexes in aqueous and neat ethylenediamine solutions and solvent-exchange kinetics of the copper (II) ion in ethylenediamine as studied by EXAFS and NMR methods. Inorg. Chem. 32: 3010-3014.
13. Johnson, A.R., McQueen, T.M., Rodolfa, K.T. (2005) Species distribution diagrams in the copper-ammonia system: an updated and expanded demonstration illustrating complex equilibria. J. Chem. Edu. 82:408-414.
14. Lee, M.J., Cooper, P.A. (2010) Copper monoethanolamine adsorption in wood and its relationship with cation exchange capacity (CEC). Holzforschung, 64:.
15. Marko, I.E., Giles, P.R., Tsukazaki, M., Brown, S.M, Urch, C.J. (1996) Copper-catalyzed oxidation of alcohols to aldehydes and ketones: an efficient, aerobic alternative. Science 274:20442045.
16. Michite, R.I.C., Neale, S.M. (1959) Catalytic action of copper in the alkaline autoxidation of cellulose at low alkali concentration. Nature 183:534-535.
17. Nevell, T.P., Zeronian, S.H. (1985) Cellulose Chemistry and its Applications. Wiley, Chichester.
18. Pankras, S., Cooper, P.A., Wylie, S. (2009) Distribution of copper complexes in alkaline copper quat (ACQ) wood preservatives: effect of ionic strength, solution pH and copper to monoetha-nolamine ratio. Proc. Can. Wood Preserv. Assoc. 30:243-261.
19. Ruddick, J.N.R. (2003) Basic copper wood preservatives, preservative depletion: factors which influence loss. Proc. Can. Wood Preserv. Assoc. 24:26-59.
20. Ruddick, J.N.R., Xie, C., Herring, F.G. (2001) Fixation of amine copper preservatives: Part 1. reaction of vanillin, a lignin model compound with monoethanolamine copper sulphate solution. Holzforschung 55:585-589.
21. Staccioli, G., Sturaro, A., Rella, R. (2000) Cation exchange capacity tests on some lignocellulosic materials highlight some aspects of the use of copper as wood preservative. Holzforschung 54: 133-136.
22. Stumm, W., Morgan, J. (1995) Aquatic Chemistry. 3rd edn. John Wiley & Sons, Chichester.
23. Tascioglu, C., Cooper, P.A., Ung, T. (2008) Effects of fixation temperature and environment on copper speciation in ACQ treated red pine. Holzforschung 62:289-293.
24. Tauler, R., Casassas, E. (1985) The complex formation of Cu(II) with triethanolamine in aqueous solution. Inorg. Chim. Acta 105:165-170.
25. Tauler, R., Casassas, E. (1986) The complex formation of Cu (II) with mono- and di-ethanolamine in aqueous solution. Inorg. Chim. Acta 114:203-209.
26. Tsai, W., Liu, Y.H., Peng, S.M., Liu, S.T. (2005) Structural characterization and catalytic activities of copper complexes with pyridine-amine-phosphine-oxide ligand. J. Organomet. Chem. 690:415-421.
27. Velusamy, S., Srinivasan, A., Punniyamurthy, T. (2006) Cupper(II) catalyzed selective oxidation of primary alcohols to aldehydes with atmospheric oxygen. Tetrahedron Lett. 47:923-926.
28. Wang, J., Ban, H., Teng, X., Wang, H., Ladwig, K. (2006) Impacts of pH and ammonia on the leaching of Cu(II) and Cd(II) from coal fly ash. Chemosphere 64:1892-1898.
29. Xie, C., Ruddick, J.N.R., Rettig, S.J., Herring, F.G. (1995) Fixation of ammoniacal copper preservatives: reaction of vanillin, a lignin model compound with ammoniacal copper sulphate solution. Holzforschung 49:483-490.
30. Zhang, J., Kamdem, D.P. (2000) Electron paramagnetic resonance spectroscopic (EPR) study of copper amine treated southern pine in wood preservation. Holzforschung 54:343-348.