Adsorption property of cesium onto modified macroporous silica-calix[4]arene-crown based supramolecular recognition materials

Industrial and Engineering Chemistry Research

Volumn 51, Issue 17, 2012, Pages 6196-6204

  Zhang, Anyun ^a   Chai, Zhifang ^a,b  

^a ZHEJIANG UNIVERSITY   (China)

^b INSTITUTE OF HIGH ENERGY PHYSICS   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION ABILITY; ADSORPTION BEHAVIOR; ADSORPTION PROPERTIES; CHROMATOGRAPHIC SEPARATIONS; HEAT GENERATORS; HIGH SELECTIVITY; LIQUID WASTES; MACROPOROUS; PACKED COLUMN; TRI-N-BUTYL PHOSPHATE;

ADSORPTION; GADOLINIUM; LIQUID CHROMATOGRAPHY; PALLADIUM COMPOUNDS; RUBIDIUM; SILICA; SUPRAMOLECULAR CHEMISTRY; ZIRCONIUM;

CESIUM;

EID: 84860477049     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie202540d     Document Type: Conference Paper

References (37)

1. Madic, C. Overview of the Hydrometallurgical and Pyrometallurgical Process Studied World-Wide for the Partitioning of High Active Nuclear Wastes. International Symposium NUCEF 2001, Oct 31-Nov 2, 2001, Japan Atomic Energy Research Institute; Conf 2002-004; Japan Atomic Energy Research Institute: Toaki, Ibaraki, Japan, 2002; pp 27-37.
2. Asfari, Z.; Wenger, S.; Vicens, J. Calixcrowns and Related Molecules J. Inclusion Phenom. Mol. Recognit. Chem. 1994, 19, 137
3. Ludwing, R.; Dzung, N. T. K. Calixarene-Based Molecules for Cation Recognition Sensors 2002, 2, 397
4. Delmau, L. H.; Lefranc, T. J.; Bonnesen, P. V.; Bryan, J. C.; Presley, D. J.; Moyer, B. A. Fundamental Studies Regarding Synergism Between Calix[4]arene-Bis(tert-Octylbenzo-Crown-6) and Alcohol Modifiers in the Solvent Extraction of Cesium Nitrate Solvent Extr. Ion Exch. 2005, 23, 23
5. Baron, P.; Lecomte, M.; Boullis, B.; Simon, N.; Warin, D. Separation of the Long Lived Radionuclides: Current Status and Future R&D Program in France. Proceedings of Global 2003, New Orleans, LA, USA; 2003; pp 565-574.
6. + Selective Optical Sensors J. Chem. Soc., Perkin Trans.2 2001, 585
7. Sachleben, R. A.; Urvoas, A.; Bryan, J. C.; Haverlock, T. J.; Hay, B. H.; Moyer, B. A. Dideoxygenated Calix[4]arene Crown-6 Ethers Enhanced Selectivity for Caesium over Potassium and Rubidium Chem. Commun. 1999, 17, 1751
8. Simon, N.; Tournois, B.; Eymard, S.; Volle, G.; Rivalier, P.; Leybros, J.; Lanoe, J. Y.; Tronche, N. R.; Ferlay, G.; Dozol, J. F. Cs Selective Extraction from High Level Liquid Waste With Crown Calixarene: Where Are Today? International Conference Atalante 2004, Advances for Future Nuclear Fuel Cycles, Nimes, France, June 21-25, 2004; 2004; pp 1-5.
9. Simon, N.; Eymard, S.; Tournois, B.; Dozol, J. F. Caesium Extraction from Acidic High Level Liquid Wastes with Functionalized Calixarenes. International Conference Atalante 2000, Scientific Research on the Back-End of the Fuel Cycle for 21st Century, Avignon, France, Oct 24-26, 2000; 2000; pp 1-8.
10. Walker, D. D.; Norato, M.; Campbell, S. G.; Crowder, M. L.; Fink, S. D.; Fondeur, F. F.; Geeting, M. W.; Kessinger, G. F.; Pierce, R. A. Cesium Removal from Savannah River Site Radioactive Waste Using the Caustic Side Solvent Extraction (CCSX) Process. WSRC-MS-2003-00317, 2003, pp 1-14.
11. Moyer, B. A.; Bonnesen, P. V.; Bryan, J. C.; Engle, N. L.; Levitskaia, T. G.; Sachleben, R. A.; Bartsch, R. A.; Talanov, V. S.; Gibson, H. W.; Jason, J. W. (Chemical and Analytical Science Division, Oak Ridge National Laboratory, Oak Ridge, TN, USA). Next Generation Extractants for Cesium Separation from High-Level Waste: From Fundamental Concepts To Site Implementation. DE-AC05-00OR22725, 2001, pp 3-10.
12. Riddle, C. L.; Baker, J. D.; Law, J. D.; McGrath, C. A.; Meikrantz, D. H.; Mincher, B. J.; Peterman, D. R.; Todd, T. A. Fission Product Extraction (FPEX): Development of a Novel Solvent for the Simultaneous Separation of Strontium and Cesium from Acidic Solutions Solvent Extr. Ion Exch. 2005, 23, 449
13. Mincher, B. J.; Mezyk, S. P.; Bauer, W. F.; Elias, G.; Riddle, C.; Peterman, D. R. FPEX γ-Radiolysis in the Presence of Nitric Acid Solvent Extr. Ion Exch. 2005, 25, 593
14. Bonnesen, P. V.; Delmau, L. H.; Moyer, B. A.; Lumetta, G. J. Development of Effective Solvent Modifiers for the Solvent Extraction of Cesium from Alkaline High-Level Tank Waste Solvent Extr. Ion Exch. 2003, 21, 141
15. Bazelarire, E.; Gobunova, M. G.; Bonnesen, P. V.; Moyer, B. A.; Delmau, L. H. pH-Switchable Cesium Nitrate Extraction with Calix[4]arene Mono and Bis(benzo-Crown-6) Ethers Bearing Amino Functionalities Solvent Extr. Ion Exch. 2004, 22, 637
16. Bonnesen, P. V.; Delmau, L. H.; Moyer, B. A.; Leonard, R. A. A Robust Alkaline-Side CSEX Solvent Suitable for Removing Cesium from Savannah River High Level Waste Solvent Extr. Ion Exch. 2000, 18, 1079
17. Horwitz, E. P.; Chiarizia, R.; Dietz, M. L. A Novel Strontium-Selective Extraction Chromatographic Resin Solvent Extr. Ion Exch. 1992, 10, 313
18. Chiarizia, R.; Horwitz, E. P.; Dietz, M. L. Acid Dependency of the Extraction of Selected Metal Ions by a Strontium-Selective Extraction Chromatographic Resin: Calculated vs. Experimental Curves Solvent Extr. Ion Exch. 1992, 10, 337
19. Dietz, M. L.; Horwitz, E. P.; Chiarizia, R.; Diamona, H. Novel Extraction Chromatographic Materials for the Separation and Preconcentration of Radionuclides. Proceedings of the International Solvent Extraction Conference (ISEC'93). University of York, England, Sept 9-15, 1993; 1993; Vol. 3, p 1587.
20. + and K Chem. Commun. 1996, 19, 2277
21. Zhang, A.; Hu, Q.; Chai, Z. SPEC: A New Process for Strontium and Cesium Partitioning Utilizing Two Macroporous Silica-Based Supramolecular Recognition Agents Impregnated Polymeric Composites Sep. Sci. Technol. 2009, 44, 2146
22. Zhang, A.; Wei, Y. Z.; Hoshi, H.; Koma, Y.; Kamiya, M. Chromatographic Separation of Cesium and Strontium from High Level Liquid Waste Using Silica-Based Calixarene-Crown Extraction Resins. Proceedings of Global 2005, Japan, Oct 9-13, 2005; 2005; pp 25-27.
23. Zhang, A.; Wang, W.; Chai, Z.; Kumagai, M. Separation of Strontium Ions From a Simulated Highly Active Liquid Waste Using a Composite of Silica-Crown Ether in a Polymer J. Sep. Sci. 2008, 31, 3148
24. Zhang, A.; Kuraoka, E.; Kumagai, M. Development of the Chromatographic Partitioning of Cesium and Strontium Utilizing Two Macroporous Silica-Based Calix[4]arene-Crown and Amide Impregnated Polymeric Composites: PREC Partitioning Process J. Chromatogr., A 2007, 1157, 85
25. Zhang, A.; Xiao, C.; Xue, W.; Chai, Z. Chromatographic Separation of Cesium by a Macroporous Silica-Based Supramolecular Recognition Agent Impregnated Material Sep. Purif. Technol. 2009, 66, 541
26. Zhang, A.; Hu, Q.; Chai, Z. Chromatographic Partitioning of Cesium by a Macroporous Silica-Calix[4]arene-Crown Supramolecular Recognition Composite AIChE J. 2010, 56, 2632
27. Zhang, A.; Hu, Q.; Chai, Z. Synthesis of a Novel Macroporous Silica-Calix[4]arene-Crown Polymeric Composite and Its Adsorption for Alkali Metal and Alkaline Earths Ind. Eng. Chem. Res. 2010, 49, 2047
28. Zhang, A.; Xiao, C.; Hu, Q.; Chai, Z. Synthesis of a Novel Macroporous Silica-Calix[4]arene-Crown Supramolecular Recognition Material and Its Adsorption for Cesium and Some Typical Metals in Highly Active Liquid Waste Solvent Extr. Ion Exch. 2010, 28, 526
29. Zhang, A.; Hu, Q. Chromatography Partitioning of Cesium by a Modified Macroporous Silica-Based Supramolecular Recognition Material Chem. Eng. J. 2010, 159, 58
30. Zhang, A.; Chen, C.; Wang, W. Adsorption Behavior of Sr(II) and Some Typical Co-Existent Metals Contained in High Level Liquid Waste onto a Modified Macroporous Silica-Based Polymeric DtBuCH18C6 Composite Solvent Extr. Ion Exch. 2008, 26, 624
31. Zhang, A.; Wang, W.; Chai, Z.; Kuraoka, E. Modification of a Novel Macroporous Silica-Based Crown Ether Impregnated Polymeric Composite with 1-Dodecanol and Its Adsorption for Some Fission and Non-Fission Products Contained in High Level Liquid Waste Eur. Polym. J. 2008, 44, 3899
32. Zhang, A.; Chen, C.; Chai, Z.; Kumagai, M. SPEC Process III. Synthesis of a Macroporous Silica-Based Crown Ether Impregnated Polymeric Composite Modified with 1-Octanol and Its Adsorption Capacity for Sr(II) Ions and Some Typical Co-Existent Metal Ions Adsorpt. Sci. Technol. 2008, 26, 705
33. Zhang, A.; Xiao, C.; Chai, Z. SPEC process II. Adsorption of Strontium and Some Typical Co-Existent Elements Contained in High Level Liquid Waste onto a Macroporous Silica-Based Crown Ether Impregnated Functional Composite J. Radioanal. Nucl. Chem. 2009, 280, 181
34. Dietz, M. L.; Bond, A. H.; Clapper, M.; Finch, J. W. Isomer Effects in the Extraction of Metal Ions from Acidic Nitrate Media by Dicyclohexano-18- Crown-6 Radiochim. Acta 1999, 85, 119
35. Kriz, J.; Dybal, J.; Makrlik, E.; Budka, J. Interaction of Hydronium Ion with Dibenzo-18-Crown-6: NMR, IR, and Theroretical Study J. Phys. Chem. A 2008, 112, 10236
36. Dybal, J.; Makrlik, E.; Vanura, P.; Budka, J. Protonation of 25,27-Bis(1-Octyloxy) Calix[4]arene-Crown-6 in the 1,3- Alternate Conformation Monatsh. Chem. 2008, 139, 1175
37. Michael, M. N. The Ionic Hydrogen Bond. 2. Intramolecular and Partial Bonds. Protonation of Polyethers, Crown Ethers, and Diketones J. Am. Chem. Soc. 1983, 105, 4906