Fundamental studies regarding synergism between calix[4]arene-bis(tert-octylbenzo-crown-6) and alcohol modifiers in the solvent extraction of cesium nitrate

Solvent Extraction and Ion Exchange

Volumn 23, Issue 1, 2005, Pages 23-57

  Delmau, Lætitia H ^a   Lefranc, Thomas J ^a   Bonnesen, Peter V ^a   Bryan, Jeffrey C ^a   Presley, Derek J ^a   Moyer, Bruce A ^a  

^a OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; ANIONIC POLYMERIZATION; CESIUM; CRYSTALLOGRAPHY; MASS SPECTROMETRY; PHASE EQUILIBRIA;

LIPOPHILIC ALCOHOLS; PHASE MODIFIERS; POLAR SOLVATING MOLECULES;

SOLVENT EXTRACTION;

SOLVENT;

EID: 13644283002     PISSN: 07366299     EISSN: None     Source Type: Journal    
DOI: 10.1081/SEI-200044379     Document Type: Article

References (50)

1. Marcus, Y.; Kertes, A.S. Ion Exchange and Solvent Extraction of Metal Complexes; Wiley Interscience: New York, 1969.
2. Sekine, T.; Hasegawa, Y. Solvent Extraction Chemistry: Fundamentals and Applications; Marcel Dekker: New York, 1977.
3. Rydberg, J.; Musikas, C.; Choppin, G.R. Principles and Practices of Solvent Extraction; Marcel Dekker: New York, 1992.
4. Sachleben, R.A.; Deng, Y.; Moyer, B.A. Ring-size and substituent effects in the solvent extraction of alkali metal nitrates by crown ethers in 1,2-dichloroethane and 1-octanol. Solvent Extr. Ion Exch 1996, 14 (6), 995-1015.
5. Levitskaia, T.G.; Bonnesen, P.V.; Chambliss, C.K.; Moyer, B.A. Synergistic pseudohydroxide, extraction: synergism and anion selectivity in sodium extraction using a crown ether and a series of weak lipophilic acids. Anal. Chem. 2003, 75 (3), 405-412.
6. Duchemin, C.R.; Engle, N.L.; Bonnesen, P.V.; Haverlock, T.J.; Delmau, L.H.; Moyer, B.A. Solvatochromic solvent polarity measurements of alcohol solvent modifiers and correlation with cesium extraction strength. Solvent Extr. Ion Exch. 2001, 19 (6), 1037-1058.
7. + host. Chem. Commun. 2001, 17, 1620-1621.
8. Bryan, J.C.; Delmau, L.H.; Hay, B.P.; Nicholas, J.B.; Rogers, L.M.; Rogers, R.D.; Moyer, B.A. Cesium recognition by supramolecular assemblies of 2-benzylphenol and 2-benzylphenolate. Struct. Chem. 1999, 10 (3), 187-203.
9. Delmau, L.H.; Bryan, J.C.; Hay, B.P.; Engle, N.L.; Sachleben, R.A.; Moyer, B.A. Benzyl phenol derivatives: extraction properties of calixarene fragments. In Calixarene Molecules for Separations; Lumetta, G.J., Rogers, R.D., Gopalan, A.S., Eds.; ACS Symposium Series; American Chemical Society: Washington, D.C., 2000; Vol. 757, Chap. 7, 86-106.
10. Bonnesen, P.V.; Delmau, L.H.; Moyer, B.A.; Lumetta, G.J. Development of effective solvent modifiers for the solvent extraction of cesium from alkaline high-level tank waste. Solvent Extr. Ion Exch. 2003, 21 (2), 141-170.
11. Bonnesen, P.V.; Delmau, L.H.; Moyer, B.A.; Leonard, R.A. A robust alkaline-side CSEX solvent suitable for removing cesium from Savannah River high level waste. Solvent Extr. Ion Exch. 2000, 18 (6), 1079-1108.
12. Leonard, R.A.; Conner, C.; Liberatore, M.W.; Sedlet, J.; Aase, S.B.; Vandegrift, G.F.; Delmau, L.H.; Bonnesen, P.V.; Moyer, B.A. Development of a solvent extraction process for cesium removal from SRS tank waste. Sep. Sci. Technol. 2001, 36, 743-766.
13. Bonnesen, P.V.; Haverlock, T.J.; Engle, N.L.; Sachleben, R.A.; Moyer, B.A. Development of process chemistry for the removal of cesium from acidic nuclear waste by calix[4]arene-crown-6 ethers. In Calixarene Molecules for Separations; Lumetta, G.J., Rogers, R.D., Gopalan, A.S., Eds.; ACS Symposium Series, American Chemical Society: Washington, D.C., 2000; Vol. 757, Chap. 3, 26-44.
14. Moyer, B.A.; Sachleben, R.A.; Bonnesen, P.V.; Presley, D.J. Calixarene Crown Ether Solvent Composition and Use Thereof for Extraction of Cesium from Alkaline Waste Solutions. U.S. Patent 6,174,503, 16 January 2001.
15. Bonnesen, P.V.; Moyer, B.A.; Sachleben, R.A. Fluoro-alcohol Phase Modifiers and Process for Cesium Solvent Extraction. U.S. Patent 6,566,561, 20 May 2003.
16. Baes, C.F., Jr. Modeling solvent extraction systems with SXFIT. Solvent Extr. Ion Exch. 2001, 19, 193-213.
17. Ritcey, G.M.; Ashbrook, A.W. Solvent Extraction, Principles and Applications to Process Metallurgy; Elsevier: New York, 1980.
18. Ritcey, G.M.; Ashbrook, A.W. Solvent Extraction, Principles and Applications to Process Metallurgy; Elsevier: New York, 1984.
19. Szymanowski, J. Physicochemical modification of extractants. Crit. Rev. Anal. Chem. 1995, 25, 143-194.
20. Sastre, A.; Szymanowski, J. Physicochemical discussion of the effect of modifiers on the extraction properties of hydroxyoximes. Solvent Extr. Ion Exch., submitted.
21. Shmidt, V.S. Amine Extraction; Keter Press: Jerusalem, 1971.
22. Kertes, A.S. The Chemistry of the Formation and Elimination of a Third Phase in Organophosphorus and Amine Extraction Systems. In Solvent Extraction Chemistry of Metals; McKay, H.A. C., Healy, T.V., Jenkins, I.L., Naylor, A., Eds.; Macmillan: London, 1965; 377-399.
23. Verstegen, J.M. P. J. The third phase in amine systems. J. Inorg. Nucl. Chem. 1965, 27, 201-207.
24. Lipovskii, A.A.; Dem'yanova, T.A. Nature of the interaction of tridecylammonium salts with aliphatic alcohol molecules. Radiokhimiya 1966, 8 (1), 112-114.
25. Muhammed, M.A. The role of octanol in the extraction of hydrochloric acid by trilaurylamine dissolved in benzene. J. Radioanal. Chem. 1976 30, 411-417.
26. Chiarizia, R.; Jensen, M.P.; Borkowski, M.; Ferraro, J.R.; Thiyagarajan, P.; Littrell, K.C. Third phase formation revisited: The U(VI), HNO3-TBP, n-dodecane system. Solvent Extr. Ion Exch. 2003, 21 (1), 1-27.
27. Asfari, Z.; Wenger, S.; Vicens, J. Calixcrowns and related molecules. J. Incl. Phenom. Mol. Recogn. Chem. 1994, 19 (1-4), 137-148.
28. Dozol, J.-F.; Simon, N.; Lamare, V.; Rouquette, H.; Eymard, S.; Tournois, B.; De Marc, D.; Macias, R.M. A solution for cesium removal from high salinity acidic or alkaline liquid waste: the crown calix[4]arenes. Sep. Sci. Technol. 1999, 34 (6-7), 877-909.
29. 17 October 2001; Vol. 66, No. 201, 52752-52756U.S. Department of Energy, Department of Energy Record of Decision: Savannah River Site Salt Processing Alternatives, Federal Register.
30. Moyer, B.A.; Alexandratos, S.D.; Bonnesen, P.V.; Brown, G.M.; Caton, J.E., Jr.; Delmau, L.H.; Duchemin, C.R.; Haverlock, T.J.; Levitskaia, T.G.; Maskarinec, M.P.; Sloop, F.V., Jr.; Stine, C.L. Caustic-side Solvent Extraction Chemical and Physical Properties: Progress in FY 2000 and FY 2001; February Oak Ridge National Laboratory: Oak Ridge, TN, 2002Report ORNL/TM-2001/285.
31. Delmau, L.H.; Birdwell, , Jr.; Bonnesen, P.V.; Foote, L.J.; Haverlock, T.J.; Klatt, L.N.; Lee, D.D.; Leonard, R.A.; Levitskaia, T.G.; Maskarinec, M.P.; Moyer, B.A.; Sloop, F.V., Jr.; Tomkins, B.A. Caustic-side Solvent Extraction: Chemical And Physical Properties of the Optimized Solvent; OctoberOak Ridge National Laboratory: Oak Ridge, Tennessee, 2002ORNL/TM-2002/190.
32. Bonnesen, P.V.; Delmau, L.H.; Haverlock, T.J.; Moyer, B.A. Alkaline-side Extraction of Cesium from Savannah River Tank Waste using a Calixarene-Crown Ether Extractant; DecemberOak Ridge National Laboratory: Oak Ridge, TN, 1998; Report ORNL/TM-13704.
33. Harms, K. XCAD4; Universität Marburg: Germany, 1995.
34. SHELXTL (Version 5, IRIX); Siemens Analytical X-ray Instruments, Inc.: Madison, Wisconsin, 1995.
35. Spek, A.L. PLATON: A Multi-Purpose Crystallographic Tool; Universiteit Utrecht: The Netherlands, 1996.
36. Jeffrey, G.A. An Introduction to Hydrogen Bonding; Truhlar, D.G., Ed.; Oxford University Press: Oxford, 1997.
37. Delmau, L.H.; Van Berkel, G.J.; Bonnesen, P.V.; Moyer, B.A. Improved Performance of the Alkaline-Side Csex Process for Cesium Extraction from Alkaline High-Level Waste Obtained by Characterization of the Effect of Surfactant Impurities; Oak Ridge National Laboratory: Oak Ridge, TN, 1999; Report ORNL/TM-1999/209.
38. Delmau, L.H.; Baes, C.F., Jr.; Bostick, D.A.; Haverlock, T.J.; Moyer, B.A. Solvent extraction system modeling using the program SXFIT. Leaching and Solution Purification. Hydrometallurgy 2003-Fifth International Conference in Honor of Professor Ian Ritchie, Vol. 1, Proceedings of the 2003 International Symposium on Hydrometallurgy, Vancouver, Canada, August 24-27, 2003;
39. Young, C.A., Alfantazi, A.M., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A., Eds.; TMS (The Minerals, Metals, and Materials Society): Warrendale, PA, 2003; 969-981.
40. Baes, C.F., Jr.; McDowell, W.J.; Bryan, S.A. The interpretation of equilibrium data from synergistic solvent extraction systems. Solvent Extr. Ion Exch. 1987, 5 (1), 1-2.
41. Baes, C.F., Jr.; Moyer, B.A.; Case, G.N.; Case, F.I. SXLSQA, a computer program for including both complex formation and activity effects in the interpretation of solvent extraction data. Sep. Sci. Technol. 1990 25 (13-15), 1675-1688.
42. Baes, C.F., Jr. SXLSQI: A Program for Modeling Solvent Extraction Systems; DecemberOak Ridge National Laboratory: Oak Ridge, TN, 1998; Oak Ridge National Laboratory Report ORNL/TM-13604.
43. Hormadaly, J.; Marcus, Y. Anion solvation properties of protic solvents. 1. Spectroscopic study. J. Phys. Chem. 1979, 83 (22), 2843-2848.
44. Reichardt, C. Solvents and Solvent Effects in Organic Chemistry., 2nd Ed.; VCH: Weinheim (Federal Republic of Germany), 1990.
45. Marcus, Y.; Pross, E.; Hormadaly, J. Anion solvation properties of protic solvents. 2. Salt distribution study. J. Phys. Chem. 1980, 84, 2708-2715.
46. Haverlock, T.J.; Bonnesen, P.V.; Sachleben, R.A.; Moyer, B.A. Analysis of equilibria in the extraction of cesium nitrate by calix[4]arene-bis(t-octylbenzocrown-6) in 1,2-dichloroethane. J. Inclusion Phenom. Mol. Recognit. Chem. 2000, 36, 21-37.
47. Barton, A.F.M. Handbook of Solubility Parameters and other Cohesion Parameters, 2nd ed.; CRC Press: Boca Raton, 1983.
48. Millero, F.J. Water and Aqueous Solutions; Horne, R.A., Ed.; Wiley-Interscience: New York, 1972.
49. Pitzer, K.S. Activity Coefficients in Electrolyte Solutions, 2nd Ed.; Pitzer, K.S., Ed.; CRC Press: Boca Raton, 1991.
50. Bure; CLange, C. Comparison of dissociation of ions in an electrospray source, or a collision cell in tandem mass spectrometry. Current Org Chem. 2003, 7 (15), 1613-1624.