Synthesis of a novel macroporous silica-calix[4]arene-crown polymeric composite and its adsorption for alkali metals and alkaline-earth metals

Industrial and Engineering Chemistry Research

Volumn 49, Issue 5, 2010, Pages 2047-2054

  Zhang, Anyun ^a   Hu, Qihui ^a   Chai, Zhifang ^a,b  

^a ZHEJIANG UNIVERSITY   (China)

^b INSTITUTE OF HIGH ENERGY PHYSICS   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION ABILITY; CALIX[4]ARENES; CONTACT TIME; EXTRACTION CHROMATOGRAPHY; HEAT GENERATORS; INTERMOLECULAR INTERACTIONS; LIQUID WASTES; MACROPOROUS; MACROPOROUS SILICA; MEAN DIAMETER; NO ADSORPTION; POLYMERIC COMPOSITES; POLYMERIC PARTICLES; THERMODYNAMIC PARAMETER;

ADSORPTION; BARIUM; CESIUM; COMPLEXATION; LIQUID CHROMATOGRAPHY; METAL RECOVERY; METALS; REINFORCED PLASTICS; RUBIDIUM; SILICA; SODIUM; SYNTHESIS (CHEMICAL);

POLYMERS;

EID: 77749289732     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie901622y     Document Type: Article

References (36)

1. Madic, C. Overview of the Hydrometallurgical and Pyrometallurgical Processes Studied World-Wide for the Partitioning of High Active Nuclear Wastes. In Proceedings of the International Symposium NUCEF 2001; Japan Atomic Energy Research Institute: Tokai, Japan, October 31-November 2, 2001, in JAERI Conference 2002-004, March, 2002; pp 27-37.
2. Herbst, R. S.; Law, J. D.; Todd, T. A.; Romanovskiy, V. N.; Babain, V. A.; Esimantovskiy, V. M.; Smirnov, I. V.; Zaitsev, B. N. Universal Solvent Extraction (UNEX) Flowsheet Testing for the Removal of Cesium, Strontium, and Actinides Elements from Radioactive, Acidic Dissolved Waste. Solvent Extr. Ion Exch. 2002, 20, 429.
3. Romanovskiy, V. N.; Smirnov, I. V.; Babain, V. A.; Todd, T. A.; Law, J. D.; Herbst, R. S.; Brewer, K. N. The Universal Solvent Extraction (UNEX) Process. I. Development of the UNEX Process Solvent for the Separation of Cesium, Strontium, and the Actinides from Acidic Radioactive Waste. Solvent Extr. Ion Exch. 2001, 19, 1.
4. Law, J. D.; Herbst, R. S.; Todd, T. A.; Romanovskiy, V. N.; Babain, V. A.; Esimantovskiy, V. M.; Smirnov, I. V.; Zaitsev, B. N.; Zaitsev, B. N. The Universal Solvent Extraction (UNEX) Process. II Flowsheet Development and Demonstration of the UNEX Process for the Separation of Cesium, Strontium, and Actinides from Actual Acidic Radioactive Waste. Solvent Extr. Ion Exch. 2001, 19, 23.
5. Simon N.; Eymard S.; Tournois B.; Dozol J. F. Cs Selective Extraction from High Level Liquid Wastes with Crown Calixarenes: Where Are We Today. Presented at the Atalante-2004 International Conference, Nîmes, France, Jun 21-24, 2004.
6. Riddle, C. L.; Baker, J. D.; Law, J. D.; McGrath, C. A.; Meikrantz, D. H.; Mincher, B. J.; Peterman, D. R.; Todd, T. A. Fission Product Extraction (FPEX): Development of A Novel Solvent for the Simultaneous Separation of Strontium and Cesium from Acidic Solutions. Solvent Extr. Ion Exch. 2005, 23, 449.
7. Mincher, B. J.; Mezyk, S. P.; Bauer, W. F.; Elias, G.; Riddle, C.; Peterman, D. R. FPEX γ-Radiolysis in the Presence of Nitric Acid. Solvent Extr. Ion Exch. 2005, 25, 593.
8. TRUEX/SREX Demonstration Innovation Technology Summary Reports; Report DOE/EM-0419; U.S. Department of Energy: Washington, DC, Dec 1998.
9. Horwitz, E. P.; Mark, L. D.; Fisher, D. E. SREX: A New Process for the Extraction and Recovery of Strontium from Acidic Nuclear Waste Stream. Solvent Extr. Ion Exch. 1991, 9, 1.
10. Bruce, A.; Moyer, P. V.; Bonnesen, J. C.; Bryan, N. L.; Engle, T. G.; Levitskaia, R. A.; Sachleben, R. A.; Bartsch, V. S.; Talanov, H. W.; Gibson, J. W. Next Generation Extractants for Cesium Separation from High-Level Waste: From Fundamental Concepts to Site Implementation. Presented at the American Chemical Society National Meeting, New York, Sep 7-11, 2003.
11. Walker, D. D.; Norato, M.; Campbell, S. G.; Crowder, M. L.; Fink, S. D.; Fondeur, F. F.; Geeting, M. W.; Kessinger, G. F.; Pierce, R. A. Cesium Removal from Savannah River Site RadioactiVe Waste Using the Caustic Side Solvent Extraction (CCSX) Process; Report WSRC-MS-2003-00317; Westinghouse Savannah River Company: Aiken, SC, 2003.
12. Law, J. D.; Wood, D. J.; Herbst, R. S. Development and testing of SREX flow sheet for treatment of idaho chemical processing plant sodiumbearing waste using centrifugal contactors. Sep. Sci. Technol. 1997, 32, 223.
13. Zhang, A.; Kuraoka, E.; Hoshi, H.; Kumagai, M. Synthesis of two novel macroporous silica-based impregnated polymeric composites and their application in high level activity liquid waste partitioning by extraction chromatography. J. Chromatogr. A 2004, 1061, 175.
14. Wood, D. J.; Law, J. D. Evaluation of the SREX solvent extraction process for the removal of 90 sr and hazardous metal ions from acidic nuclear waste solutions containing high concentrations of interfering alkali metal ions. Sep. Sci. Technol. 1997, 32, 241.
15. Horwitz, E. P.; Chiarizia, R.; Dietz, M. L. A novel strontiumselective extraction chromatographic resin. Solvent Extr. Ion Exch. 1992, 10, 313.
16. Chiarizia, R.; Horwitz, E. P.; Dietz, M. L. Acid dependency of the extraction of selected metal ions by a strontium-selective extraction chromatographic resin: Calculated vs. experimental curves. Solvent Extr. Ion Exch. 1992, 10, 337.
17. Zhang, A.; Wei, Y. Z.; Hoshi, H.; Kumagai, M.; Kamiya, M.; Koyama, T. Resistance properties of a macroporous silica-based N,N,N',N'- tetraoctyl-3-oxapentane-1,5-diamide-impregnated polymeric adsorption material against nitric acid, temperature and γ-irradiation. Radiat. Phys. Chem. 2005, 72, 669.
18. Zhang, A.; Wei, Y. Z.; Kumagai, M.; Koma, Y.; Koyama, T. Resistant behavior of a novel silica-based octyl(phenyl)-N,N-diisobutyl carbamoylmethylphoshine oxide extraction resin against nitric acid, temperature and γ-irradiation. Radiat. Phys. Chem. 2005, 72, 455.
19. Asfari, Z.; Wenger, S.; Vicens, J. Calixcrowns and Related Molecules. J. Iuclusion Phenom. Mol. Recognit. Chem. 1994, 19, 137.
20. Ludwing, R.; Dzung, N. T. K. Calixarene-Based Molecules for Cation Recognition. Sensors 2002, 2, 397.
21. Asfieri, C.; Dradi, E.; Pochina, A.; Ungaro, R.; Andreetti, G. D. Synthesis, X-ray Crystal and Molecular Structure of a Novel Macro-Bicyclic Ligand: Crowned p-t-Butyl-calix[4]arene. J. Chem. Soc., Chem. Commun. 1983, (19), 1075.
22. Asfieri Z.; Bohmer V.; Harrowfield J.; Vicens J.; Saadioui M. Calixarenes 2001: Molecular Dynamics of Cation Complexation and Extraction; Kluwer Academic Publishers: Dordrecht, The Netherlands, 2001.
23. Dietz, M. L.; Bond, A. H.; Clapper, M.; Finch, J. W. Isomer Effects in the Extraction of Metal Ions from Acidic Nitrate Media by Dicyclohexano-18- crown-6. Radiochim. Acta 1999, 85, 119.
24. Sachleben, R. A.; Urvoas, A.; Bryan, J. C.; Haverlock, T. J.; Hay, B. H.; Moyer, B. A. Dideoxygenated Calix[4]arene Crown-6 Ethers Enhanced Selectivity for Caesium over Potassium and Rubidium. Chem. Commun. 1999, (17), 1751.
25. Wei, Y. Z.; Zhang, A.; Kumagai, M.; Watanabe, M.; Hayashi, N. Development of the MAREC Process for HLLW Partitioning Using a Novel Silica-Based CMPO Extraction Resin. J. Nucl. Sci. Technol. 2004, 41, 315.
26. Zhang, A.; Wei, Y. Z.; Kumagai, M.; Koma, Y. A New Partitioning Process for High Level Liquid Waste by Extraction Chromatography Using Impregnated Adsorbents. Presented at the 2003 ANS/ENS International Winter Meeting, New Orleans, LA, Nov 16-20, 2003.
27. Zhang, A.; Kuraoka, E.; Kumagai, M.; Koma, Y.; Koyama, T. Synthesis and application of macroporous silica-based octyl(phenyl)-N, Ndiisobutylcarbamoylmethyl phosphine oxide functional polymeric composite in chromatographic partitioning of high level liquid waste. J. Radioanal. Nucl. Chem. 2006, 269, 119.
28. Zhang, A.; Hu, Q.; Chai, Z. SPEC: A New Process for Strontium and Cesium Partitioning Utilizing Two Macroporous Silica-Based Supramolecular Recognition Agents Impregnated Polymeric Composites. Sep. Sci. Technol. 2009, 44, 2146.
29. Zhang A.; Wei Y. Z.; Hoshi H.; Koma Y.; Kamiya M. Chromatographic Separation of Cesium and Strontium from High Level Liquid Waste Using Silica-Based Calixarene-Crown Extraction Resins. Presented at Global 2005, Tsukuba, Japan, Oct 9-13, 2005.
30. Zhang, A.; Wei, Y. Z.; Hoshi, H.; Koma, Y.; Kamiya, M. Partitioning of Cesium from A Simulated High Level Liquid Waste by Extraction Chromatography Utilizing A Macroporous Silica-Based Supermolecular Calix[4]arene-Crown Impregnated Polymeric Composite. Solvent Extr. Ion Exch. 2007, 25, 389.
31. Zhang, A.; Kuraoka, E.; Kumagai, M. Development of the Chromatographic Partitioning of Cesium and Strontium Utilizing Two Macroporous Silica-Based Calix[4]arene-Crown and Amide Impregnated Polymeric Composites: PREC Partitioning Process. J. Chromatogr. A 2007, 1157, 85.
32. Zhang, A.; Wang, W.; Chai, Z.; Kumagai, M. Separation of Strontium Ions from A Simulated Highly Active Liquid Waste Using A Composite of Silica-Crown Ether in A Polymer. J. Sep. Sci. 2008, 31, 3148.
33. Zhang, A.; Wei, Y.-Z.; Kumagai, M. Synthesis of a novel silicabased macroporous polymeric adsorption material containing 4,4′,(5′)- di(tertbutylcyclohexano)-18-crown-6 functional group and its adsorption mechanism for strontium. React. Funct. Polym. 2004, 61, 191.
34. Kriz, J.; Dybal, J.; Makrlik, E.; Budka, J. Interaction of Hydronium Ion with Dibenzo-18-crown-6: NMR, IR, and Theroretical Study. J. Phys. Chem. A 2008, 112, 10236.
35. Kriz, J.; Dybal, J.; Makrlik, E.; Budka, J. Protonation of 25,27-bis(1-octyloxy)calix[4]arene-crown-6 in the 1,3-alternate conformation. Monatsh. Chem. 2008, 139, 1175.
36. Michael, M. N. The Ionic Hydrogen Bond. 2. Intramolecular and Partial Bonds. Protonation of Polyethers, Crown Ethers, and Diketones. J. Am. Chem. Soc. 1983, 105, 4906.