Straightforward synthesis of nonconjugated cyclohex-3-enone and conjugated 4-methylenecyclohex-2-enone derivatives

Synthesis

Volumn 44, Issue 9, 2012, Pages 1293-1303

  Kuttner, Julian R ^a   Warratz, Svenja ^a   Hilt, Gerhard ^a  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

alkynes; catalysis; cobalt; Diels Alder reaction; dienes; nonconjugation

Indexed keywords

ALKYNES; BIDENTATE PHOSPHINES; CARBON-CARBON DOUBLE BONDS; DEPROTECTION; DIELS-ALDER REACTION; DIENES; ISOMERISATION; MILD REACTION CONDITIONS; NONCONJUGATED; NONCONJUGATION; REGIO-SELECTIVE; SILYL ENOL ETHERS;

ACETYLENE; CATALYSIS; COBALT; ETHERS; LIGANDS; OLEFINS; PHOSPHORUS COMPOUNDS;

ORGANIC POLYMERS;

1,3 BUTADIENE DERIVATIVE; 2 (TRIMETHYLSILYLOXY)BUTA 1,3 DIENE; 2 CYCLOHEXENONE; 3 (2 METHALLYL) 4 PHENYLCYCLOHEX 3 ENONE; 3 (CYCLOHEX 1 ENYL)CYCLOHEX 3 ENONE; 3 [2 (3 OXOBUTYL)PROP 2 ENYL] 4 PHENYLCYCLOHEX 3 ENONE; 3 ALLYL 4 PHENYLCYCLOHEX 3 ENONE; 3 BUTYL 4 (2,6 DIMETHYLCYCLOHEX 1 ENYL)CYCLOHEX 3 ENONE; 3 BUTYLCYCLOHEX 3 ENONE; 3 METHYL 4 PHENYLCYCLOHEX 3 ENONE; 3 PHENYLCYCLOHEX 3 ENONE; 3,4 BIS (METHOXYMETHYL)CYCLOHEX 3 ENONE; 3,4 DIETHYLCYCLOHEX 3 ENONE; 3,4 DIPROPYLCYCLOHEX 3 ENONE; 4 (2 METHALLYL) 4 PHENYLCYCLOHEX 3 ENONE; 4 (PROP 1 EN 2 YL)CYCLOHEX 3 ENONE; 4 ALLYL 3 PHENYLCYCLOHEX 3 ENONE; 4 BUTYL 3 (2,6 DIMETHYLCYCLOHEX 1 ENYL)CYCLOHEX 3 ENONE; 4 BUTYLCYCLOHEX 3 ENONE; 4 METHYL 3 PHENYLCYCLOHEX 3 ENONE; 4 METHYLENECYCLOHEX 2 ENONE DERIVATIVE; 4 PHENYLCYCLOHEX 3 ENONE; ALKYNE DERIVATIVE; COBALT; CYCLOHEX 3 ENONE; IMINE; METHYL 2 (5 OXOCYCLOHEX 1 ENYL)ACETATE; PHOSPHINE DERIVATIVE; PYRIDINE; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; CONTROLLED STUDY; CYCLOADDITION; DEPROTECTION REACTION; DIELS ALDER REACTION; ELIMINATION REACTION; HYDROLYSIS; ISOMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SYNTHESIS;

EID: 84859853689     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0031-1289752     Document Type: Article

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