Sulfur tolerant PdAu and PdAuPt alloy hydrogen separation membranes

Journal of Membrane Science

Volumn 405-406, Issue , 2012, Pages 11-19

  Coulter, Kent E ^a   Way, J Douglas ^b   Gade, Sabina K ^b   Chaudhari, Saurabh ^b   Alptekin, Gökhan O ^c   DeVoss, Sarah J ^c   Paglieri, Stephen N ^c   Pledger, Bill ^d  

^a SOUTHWEST RESEARCH INSTITUTE   (United States)

^b Department of Metallurgical and Materials Engineering   (United States)

^c TDA RESEARCH INC   (United States)

^d IdaTech LLC   (United States)

Author keywords

Hydrogen; PdAu; PdAuPt; Sulfur tolerant

Indexed keywords

HYDROGEN GAS; HYDROGEN PERMEABILITY; HYDROGEN SEPARATION MEMBRANES; MIXED GAS; MIXTURE GAS; PDAU; PDAUPT; PURE GAS; SULFIDE FORMATION; SYN-GAS; U.S. DEPARTMENT OF ENERGY; WATER-GAS SHIFTS;

ALLOYS; CARBON DIOXIDE; COLD ROLLING; DESULFURIZATION; GAS MIXTURES; GAS PERMEABILITY; HYDROGEN; METAL CLADDING; PLATINUM; SULFUR; SURFACE PROPERTIES; SYNTHESIS GAS; WATER GAS SHIFT;

GAS PERMEABLE MEMBRANES;

ALLOY; GOLD; HYDROGEN; PALLADIUM; PLATINUM;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL COMPOSITION; GAS; MATERIALS TESTING; MEMBRANE PERMEABILITY; PRIORITY JOURNAL; SURFACE PROPERTY;

EID: 84859441560     PISSN: 03767388     EISSN: 18733123     Source Type: Journal    
DOI: 10.1016/j.memsci.2012.02.018     Document Type: Article

References (68)

1. Ockwig N.W., Nenoff T.M. Membranes for hydrogen separation. Chem. Rev. 2007, 107:4078-4110.
2. Ayturk M.E., Mardilovich I.P., Engwall E.E., Ma Y.H. Synthesis of composite Pd-porous stainless steel (pss) membranes with a Pd/Ag intermetallic diffusion barrier. J. Membr. Sci. 2006, 285:385-394.
3. Hara S., Sakaki K., Itoh N., Kimura H.-M., Asami K., Inoue A. An amorphous alloy membrane without noble metals for gaseous hydrogen separation. J. Membr. Sci. 2000, 164:289-294.
4. Paglieri S.N., Wermer J.R., Buxbaum R.E., Ciocco M.V., Howard B.H., Morreale B.D. Development of membranes for hydrogen separation: Pd-coated v-10pd. Energy Mater. 2008, 3:169-176.
5. Li F., Fan L.-S. Clean coal conversion processes - progress and challenges. Energy Environ. Sci. 2008, 1:248-267.
6. Anderson D.H., Evenson C.R.I., Harkins T.H., Jack D.S., Mackay R., Mundschau M.V. Hydrogen separation using dense composite membranes. Inorganic Membranes for Energy and Environmental Applications 2009, 155-171. Springer, New York. A.C. Bose (Ed.).
7. D. Gray, J. Plunkett, S. Salerno, C. White, G. Tomlinson, Current and Future Technologies for Gasification-based Power Generation, volume 2: A Pathway Study Focused on Carbon Capture Advanced Power Systems R&D Using Bituminous Coal, Report No. DOE/NETL-2009/1389, NETL, 2010.
8. Lewis F.A. The Palladium Hydrogen System 1967, Academic Press, London.
9. Timofeev N.I., Berseneva F.N., Makarov V.M. New palladium-based membrane alloys for separation of gas mixtures to generate ultrapure hydrogen. Int. J. Hydrogen Energy 1994, 19:895-898.
10. D.L. McKinley, Method for Hydrogen Separation and Purification, US Patent 3,439,474 (1969).
11. R.C. Benn, S.M. Opalka, T.H. Vanderspurt, Durable Pd-based Alloy and Hydrogen Generation Membrane Thereof, U.S. Patent 7,655,183 (2010).
12. Y. Yamamoto, R. Goto, Palladium Alloy Permeable Wall for the Separation and Purification of Hydrogen, US Patent 3,155,467 (1964).
13. Burkhanov G.S., Gorina N.B., Kolchugina N.B., Roshan N.R., Slovetsky D.I., Chistov E.M. Palladium-based alloy membranes for separation of high purity hydrogen from hydrogen-containing gas mixtures. Platinum Met. Rev. 2011, 55:3-12.
14. Sholl D.S., Ma Y.H. Dense metal membranes for the production of high-purity hydrogen. MRS Bull. 2006, 31:770-773.
15. Sonwane C.G., Jennifer W., Yi Hua M. Achieving optimum hydrogen permeability in PdAg and PdAu alloys. J. Chem. Phys. 2006, 125. 184714-1-184714-10.
16. Kamakoti P., Morreale B.D., Ciocco M.V., Howard B.H., Killmeyer R.P., Cugini A.V., Sholl D.S. Prediction of hydrogen flux through sulfur-tolerant binary alloy membranes. Science 2005, 307:569-573.
17. Gade S.K., DeVoss S.J., Coulter K.E., Paglieri S.N., Alptekin G.O., Way J.D. Palladium-gold membranes in mixed gas streams with hydrogen sulfide: effect of alloy content and fabrication technique. J. Membr. Sci. 2011, 378:35-41.
18. 2S adsorption on niobium- and copper-doped palladium surfaces. J. Phys. Chem. B: Condens. Matter Mater. Surf. Interfaces Biophys. 2010, 114:12851-12858.
19. 4S. Ind. Eng. Chem. Res. 2007, 46:6313-6319.
20. Iyoha O., Enick R., Killmeyer R., Morreale B. The influence of hydrogen sulfide-to-hydrogen partial pressure ratio on the sulfidization of Pd and 70mol% Pd-Cu membranes. J. Membr. Sci. 2007, 305:77-92.
21. Morreale B.D., Ciocco M.V., Howard B.H., Killmeyer R., Cugini A.V., Enick R.M. Effect of hydrogen-sulfide on the hydrogen permeance of palladium-copper alloys at elevated temperatures. J. Membr. Sci. 2004, 241:219-224.
22. Barbier J., Lamy-Pitara E., Marecot P., Boitiaux J.P., Cosyns J., Verna F. Role of sulfur in catalytic hydrogenation reactions. Advances in Catalysis 1990, 279-318. Academic Press. H. Pines, D.D. Eley, B.W. Paul (Eds.).
23. Morreale B., Ciferno J., Howard B., Marano M.C.J., Iyoha O., Enick R. Gasification and associated degradation mechanisms applicable to dense metal hydrogen membranes. Inorganic Membranes for Energy and Environmental Applications 2009, 173-201. Springer, New York. A.C. Bose (Ed.).
24. D.M. Driscoll, Brian, Netl Test Protocol - Testing of Hydrogen Separation Membranes, Report No. DOE/NETL 2008/1335, 2008.
25. Shu J., Grandjean B.P.A., Van Neste A., Kaliaguine S. Catalytic palladium-based membrane reactors: a review. Can. J. Chem. Eng. 1991, 69:1036-1060.
26. Coulter K.E., Way J.D., Gade S.K., Chaudhari S., Sholl D.S., Semidey-Flecha L. Predicting, fabricating, and permeability testing of free-standing ternary palladium-copper-gold membranes for hydrogen separation. J. Phys. Chem. C 2010, 114:17173-17180.
27. Grashoff G.J., Pilkington C.E., Corti C.W. The purification of hydrogen: a review of the technology emphasising the current status of palladium membrane diffusion. Platinum Met. Rev. 1983, 27:157-169.
28. Semidey-Flecha L., Ling C., Sholl D.S. Detailed first-principles models of hydrogen permeation through PdCu-based ternary alloys. J. Membr. Sci. 2010, 362:384-392.
29. 2S on the performance of Pd and Pd/Au composite membrane. J. Membr. Sci. 2010, 362:535-544.
30. 2S from natural gas streams. J. Membr. Sci. 1994, 94:111-119.
31. Goto R. Hyperpure hydrogen from palladium alloy membrane permeation (1). Chem. Econ. Eng. Rev. 1970, 2:44-50.
32. 4Pt alloy membranes. Energy Mater. 2008, 3:177-185.
33. Berseneva F.N., Timofeev N.I., Zakharov A.B. Alloys of palladium with metals of the platinum group as hydrogen-permeable membrane components at high temperatures of gas separation. Int. J. Hydrogen Energy 1993, 18:15-18.
34. Uemiya S. State-of-the-art of supported metal membranes for gas separation. Sep. Purif. Methods 1999, 28:51-85.
35. Paglieri S.N. Palladium membranes. Nonporous Inorganic Membranes 2006, 77-105. Wiley-VCH, Weinheim, Germany. A.F. Sammells, M.V. Mundschau (Eds.).
36. R. Bredesen, H. Klette, Method of Manufacturing Thin Metal Membranes, WO Patent 97/40914 (1997).
37. Frost C.B., Robinson M. The application of ultra-thin palladium alloy metal foils in gas-phase hydrogen separation or purification. JOM 2007, 59:63-64.
38. W. Juda, C.W. Krueger, R.T. Bombard, Method of Fabricating Thinned Free-Standing Metallic Hydrogen-Selective Palladium-Bearing Membranes and Novel Pin-Hole-Free Membranes Formed Thereby, US Patent 6,103,028 (2000).
39. Kim D.-W., Park Y.J., Woo B.-I., Kang S.-M., Park J.-S. Study on the perm-selectivity of thin Pd-Cu-Ni ternary alloy membrane for hydrogen purification and separation. Jpn. J. Appl. Phys. 2010, 49:018003.
40. R.W. Baker, J. Louie, P.H. Pfromm, J.G. Wijmans, Ultrathin Composite Metal Membranes, US Patent 4,857,080 (1989).
41. P.H. Thornton, Palladium and Palladium/Copper Thin Flat Membranes, US Patent 6,171,712 (2001).
42. Mejdell A.L., Klette H., Ramachandran A., Borg A., Bredesen R., Mejdell A.L. Hydrogen permeation of thin, free-standing Pd/Ag23% membranes before and after heat treatment in air. J. Membr. Sci. 2008, 307:96-104.
43. Ryi S.K., Park J.S., Kim S.H., Cho S.H., Kim D.W., Um K.Y. Characterization of Pd-Cu-Ni ternary alloy membrane prepared by magnetron sputtering and Cu-reflow on porous nickel support for hydrogen separation. Sep. Purif. Technol. 2006, 50:82-91.
44. T. Uemura, K. Yoshida, O. Nobuyuki, H. Takeshi, Hydrogen-Permeable Structure and Method of Manufacturing the Same, U.S. Patent 6,641,647 (2003).
45. Tucho W., Venvik H., Walmsley J., Stange M., Ramachandran A., Mathiesen R., Borg A., Bredesen R., Holmestad R. Microstructural studies of self-supported (1.5-10μm) Pd/23wt%Ag hydrogen separation membranes subjected to different heat treatments. J. Mater. Sci. 2009, 44:4429-4442.
46. Ramachandran A., Tucho W.M., Mejdell A.L., Stange M., Venvik H.J., Walmsley J.C., Holmestad R., Bredesen R., Borg A. Surface characterization of Pd/Ag23wt% membranes after different thermal treatments. Appl. Surf. Sci. 2010, 256:6121-6132.
47. Gade S.K., Thoen P.M., Way J.D. Unsupported palladium alloy foil membranes fabricated by electroless plating. J. Membr. Sci. 2008, 316:112-118.
48. Tosti S., Bettinali L., Castelli S., Sarto F., Scaglione S., Violante V. Sputtered, electroless, and rolled palladium-ceramic membranes. J. Membr. Sci. 2002, 196:241-249.
49. Mukaida M., Takahashi N., Hisamatsu K., Ishitsuka M., Hara S., Suda H., Haraya K. Preparation for defect-free self-supported Pd membranes by an electroless plating method. J. Membr. Sci. 2010, 365:378-381.
50. Lanning B.R., Ishteiwy O., Way J.D., Edlund D., Coulter K. Un-supported palladium alloy membranes for the production of hydrogen. Inorganic Membranes for Energy and Environmental Applications 2009, 203-219. Springer, New York. A.C. Bose (Ed.).
51. Arstad B., Venvik H., Klette H., Walmsley J.C., Tucho W.M., Holmestad R., Holmen A., Bredesen R. Studies of self-supported 1.6mm Pd/23wt.% Ag membranes during and after hydrogen production in a catalytic membrane reactor. Catal. Today 2006, 118:63-72.
52. S.K. Gade, Palladium-Gold Membranes for Hydrogen Separations: Development, Characterization, and Optimization, Ph.D. thesis, Colorado School of Mines, Golden, Colorado, 2009.
53. 2 plasma for hydrogen loading in Pd. Intermetallics 2003, 11:1345-1354.
54. Lemier C., Weissmüller J. Grain boundary segregation, stress and stretch: effects on hydrogen absorption in nanocrystalline palladium. Acta Mater. 2007, 55:1241-1254.
55. Uchikawa H., Okazaki T., Sato K. New technique of activating palladium surface for absorption of hydrogen or deuterium. Jpn. J. Appl. Phys. 1993, 32:5095-5096.
56. Roa F., Way J.D. The effect of air exposure on palladium-copper composite membranes. Appl. Surf. Sci. 2005, 240:85-104.
57. Knapton A.G. Palladium alloys for hydrogen diffusion membranes: a review of high permeability materials. Platinum Met. Rev. 1977, 21:44.
58. N.R. Bochvar, Y.P. Liberov, Au-H-Pd Phase Diagram, ASM Alloy Phase Diagrams Center, in: P. Villars (editor-in-chief), in: H. Okamoto, K. Cenzual (section editors), ASM, International, Materials Park, OH, 2006. http://www1.asminternational.org/AsmEnterprise/APD.
59. Mundschau M.V., Xie X., Evenson Iv C.R., Sammells A.F. Dense inorganic membranes for production of hydrogen from methane and coal with carbon dioxide sequestration. Catal. Today 2006, 118:12-23.
60. 2S. J. Membr. Sci. 2005, 254:49-62.
61. 2 permeation system. J. Vac. Sci. Technol. A 2010, 28:147-151.
62. Hou K., Fowles M., Hughes R. The effect of hydrogen removal during methane steam reforming in membrane reactors in the presence of hydrogen sulphide. Catal. Today 2000, 56:13-20.
63. 2S at 350°C. J. Membr. Sci. 2010, 349:380-384.
64. Kajiwara M., Uemiya S., Kojima T. Stability and hydrogen permeation behavior of supported platinum membranes in presence of hydrogen sulfide. Int. J. Hydrogen Energy 1999, 24:839-844.
65. Edlund D.J., Pledger W.A. Thermolysis of hydrogen sulfide in a metal-membrane reactor. J. Membr. Sci. 1993, 77:255-264.
66. 2S in a double-pipe packed bed membrane reactor: numerical simulation studies. Chem. Eng. J. 2008, 143:273-281.
67. 2S on hydrogen permeation of Pd60Cu40/V-15Ni composite membrane. J. Alloys Compd. 2007, 446:575-578.
68. 2S on the performance and long-term stability of Pd/Cu membranes. Ind. Eng. Chem. Res. 2009, 48:4030-4039.