Inhibition of hydrogen transport through Pd and Pd47Cu53 membranes by H2S at 350 °C

Journal of Membrane Science

Volumn 349, Issue 1-2, 2010, Pages 380-384

  O'Brien, Casey P ^a,b   Howard, Bret H ^a   Miller, James B ^a,b   Morreale, Bryan D ^a   Gellman, Andrew J ^a,b  

^a NATIONAL ENERGY TECHNOLOGY LABORATORY   (United States)

^b CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

Hydrogen sulfide; Palladium sulfide; Palladium copper membrane; Sulfur poisoning

Indexed keywords

COPPER-MEMBRANE; CORROSION LAYERS; CORROSION PRODUCTS; DECAY PATTERNS; HYDROGEN ATOMS; HYDROGEN DISSOCIATION; HYDROGEN FLUXES; HYDROGEN TRANSPORT; LOW PERMEABILITY; SEM; SLOW GROWTH; SULFUR POISONING; XPS DEPTH PROFILING;

CORROSION; DEPTH PROFILING; GAS PERMEABLE MEMBRANES; HYDROGEN; HYDROGEN SULFIDE; SCANNING ELECTRON MICROSCOPY; SULFUR; SULFUR DETERMINATION; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS;

PALLADIUM;

ALLOY; HYDROGEN SULFIDE; PALLADIUM; PALLADIUM COPPER; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION; CONTROLLED STUDY; CORROSION; DISSOCIATION; FOIL; MEMBRANE PERMEABILITY; PRIORITY JOURNAL; PROTON TRANSPORT; SCANNING ELECTRON MICROSCOPY; SURFACE PROPERTY; TRANSPORT KINETICS; X RAY DIFFRACTION;

EID: 74649083111     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2009.11.070     Document Type: Article

References (35)

1. Elkina I.B., and Meldon J.H. Hydrogen transport in palladium membranes. Desalination 147 (2002) 445-448
2. Mundschau M.V., Xie X., Evenson C.R., and Sammells A.F. Dense inorganic membranes for production of hydrogen from methane and coal with carbon dioxide sequestration. Catal. Today 118 (2006) 12-23
3. Thoen P.M., Roa F., and Way J.D. High flux palladium-copper composite membrane for hydrogen separations. Desalination 193 (2006) 224-229
4. 2 transport rate control in body-centered cubic PdCu membranes. J. Phys. Chem. B 111 (2007) 10952-10958
5. Flanagan T.B., Wang D., and Shanahan K.L. Diffusion of H through Pd membranes: effects of non-ideality. J. Membr. Sci. 306 (2007) 66-74
6. Amandusson H., Ekedahl L.-G., and Dannetun H. Hydrogen permeation through surface modified Pd and PdAg membranes. J. Membr. Sci. 193 (2001) 35-47
7. Liu S.-Y., Kao Y.-H., Oliver Su Y., and Perng T.-P. Analysis of hydrogen and deuterium absorption kinetics in Pd nanofilms. J. Alloys Compd. 311 (2000) 283-287
8. Li H., Xu H., and Li W. Study of n value and α/β palladium hydride phase transition within the ultra-thin palladium composite membrane. J. Membr. Sci. 324 (2008) 44-49
9. Peden C.H.F., Kay B.D., and Goodman D.W. Kinetics of hydrogen absorption by chemically modified Pd(110). Surf. Sci. 175 (1986) 215-225
10. Gallucci F., Chiaravalloti F., Tosti S., Drioli E., and Basile A. The effect of mixture gas on hydrogen permeation through a palladium membrane: experimental study and theoretical approach. Int. J. Hydrogen Energy 32 (2007) 1837-1845
11. 2 dissociative adsorption on Mg, Ti, Ni, Pd and La surfaces. Surf. Sci. 566-568 (2004) 703-707
12. 4S. Ind. Eng. Chem. Res. 46 (2007) 6313-6319
13. 2S on Palladium and Palladium-Copper Alloy Membranes, Chemical Engineering, vol. Doctor of Philosophy (2006), University of Pittsburgh
14. Edlund D.J., and Pledger W.A. Thermolysis of hydrogen sulfide in a metal-membrane reactor. J. Membr. Sci. 77 (1993) 255-264
15. D.L. McKinley, Metal alloy for hydrogen separation and purification, USA, 1967.
16. Kamakoti P., Morreale B.D., Ciocco M.V., Howard B.H., Killmeyer R.P., Cugini A.V., and Sholl D.S. Prediction of hydrogen flux through sulfur-tolerant binary alloy membranes. Science 307 (2005) 569-573
17. 2S in multi-tubular Pd and 80wt% Pd-20 wt% Cu membrane reactors at 1173 K. J. Membr. Sci. 306 (2007) 103-115
18. Iyoha O., Enick R., Killmeyer R., and Morreale B. The influence of hydrogen sulfide-to-hydrogen partial pressure ratio on the sulfidization of Pd and 70 mol% Pd-Cu membranes. J. Membr. Sci. 305 (2007) 77-92
19. 2S. J. Membr. Sci. 254 (2005) 49-62
20. D.J. Edlund, Hydrogen-permeable metal membrane and method for producing the same, US Patent 6,152,995 (2000).
21. Howard B.H., Killmeyer R.P., Rothenberger K.S., Cugini A.V., Morreale B.D., Enick R.M., and Bustamante F. Hydrogen permeance of palladium-copper alloy membranes over a wide range of temperatures and pressures. J. Membr. Sci. 241 (2004) 207-218
22. 40/V-15Ni composite membrane. J. Alloys Compd. (2007) 446-447
23. Roa F., Way J.D., McCormick R.L., Paglieri S.N., and Preparation. Characterization of Pd-Cu composite membranes for hydrogen separation. Chem. Eng. J. 93 (2003) 11-22
24. Nam S., Seong Y., Lee J.W., and Lee K. Preparation of highly stable palladium alloy composite membranes for hydrogen separation. Desalination 236 (2009) 51-55
25. D.L. McKinley, Method for hydrogen separation and purification, USA, 1969.
26. 2 flux of composite Pd-Cu membranes. Desalination 147 (2002) 411-416
27. Zhang X., Wang W., Liu J., Sheng S., Xiong G., and Yang W. Hydrogen transport through thin palladium-copper alloy composite membranes at low temperatures. Thin Solid Films 516 (2008) 1849-1856
28. 2S. J. Membr. Sci. 309 (2008) 246-250
29. Morreale B.D., Ciocco M.V., Howard B.H., Killmeyer R.P., Cugini A.V., and Enick R.M. Effect of hydrogen-sulfide on the hydrogen permeance of palladium-copper alloys at elevated temperatures. J. Membr. Sci. 241 (2004) 219-224
30. Yuan L., Goldbach A., and Xu H. Real-time monitoring of metal deposition and segregation phenomena during preparation of PdCu membranes. J. Membr. Sci. 322 (2008) 39-45
31. Opalka S.M., Huang W., Wang D., Flanagan T.B., Lovvik O.M., Emerson S.C., She Y., and Vanderspurt T.H. Hydrogen interactions with the PdCu ordered B2 alloy. J. Alloys Compd. 446-447 (2007)
32. Yang J.Y., Nishimura C., and Komaki M. Effect of overlayer composition on hydrogen permeation of Pd-Cu alloy coated V-15Ni composite membrane. J. Membr. Sci. 282 (2006) 337-341
33. Kamakoti P., and Sholl D.S. A comparison of hydrogen diffusivities in Pd and CuPd alloys using density functional theory. J. Membr. Sci. 225 (2003) 145-154
34. Kamakoti P., and Sholl D.S. Ab initio based lattice gas modeling of interstitial hydrogen diffusion in CuPd alloys. Phys. Rev. B 71 (2005)
35. Ngameni R., Decaux C., Solas D., Grigoriev S., and Millet P. Time and frequency domain analysis of hydrogen permeation across PdCu metallic membranes for hydrogen purification. Int. J. Hydrogen Energy (2009) 10.1016/j.ijhydene.2009.1008.1100